偏晶向(111)硅片闪耀光栅的制作

硅光栅的制作可以利用湿法腐蚀体硅工艺.湿法腐蚀利用硅的各向异性,由硅的晶面形成光栅工作凹槽,利用湿法工艺可以制作在不同光谱波段内工作的闪耀光栅.设计了一种利用偏晶向(111)硅片制作闪耀光栅的方法,使用这种方法可以批量制作闪耀角度较小的光栅.利用扫描电子显微镜(SEM)进行了光栅表面形貌测试,试验结果表明,制作的硅光栅样片具有良好光学特性的反射表面和光栅槽形.硅闪耀光栅可以被用来制作微型光谱仪、滤光器等微型仪器或器件.     

Anomalous Hall effect of heavy holes in III-V semiconductor quantum wells

The anomalous Hall effect of heavy holes in semiconductor quantum wells is studied in the intrinsic transport regime, where the Berry curvature governs the Hall current properties. Based on the first--order perturbation of wave function the expression of the Hall conductivity the same as that from the semiclassical equation of motion of the Bloch particles is derived. The dependence of Hall conductivity on the system parameters is shown. The amplitude of Hall conductivity is found to be balanced by a competition between the Zeeman splitting and the spin--orbit splitting.     

黄铁矿处理重金属废水的光谱表征

将反射光谱和吸收光谱用于黄铁矿处理酸性重金属废水的研究,探讨了黄铁矿的表面反应以及黄铁矿与重金属的相互作用。漫反射红外光谱分析证实,在处理废水过程中,黄铁矿中表面羟基与重金属离子发生反应;并通过考察黄铁矿中碳酸盐,合理解释了黄铁矿处理酸性重金属废水后的溶液自然均趋于中性(pH 7)的现象。可见区的反射光谱用于表征处理过程中的黄铁矿的颗粒及比表面变化,解释了黄铁矿在重复使用时其活性反而增强的原因。吸收光谱及XPS表征表明,黄铁矿处理含Cr(Ⅵ)废水,是一个由Cr(Ⅵ)到Cr3+再到Cr(OH)₃的吸附沉淀过程。     

原位漫反射红外光谱表征钛硅分子筛TS-1催化苯乙烯氧化反应

采用高温漫反射红外光谱考察了钛硅分子筛TS-1的稳定性,发现960 cm-1吸收峰在673 K时没有变化,表明所表征的骨架钛具有一定的高温稳定性,而表征分子筛骨架振动的两个吸收峰在673 K下向低波数位移了约13 cm-1。探讨了H₂O₂吸附对TS-1分子筛骨架钛的影响,发现960 cm-1处的吸收峰在吸附H₂O₂后强度减弱,并且向高波数位移了11 cm-1;抽真空或加热,吸收峰又复原,表明骨架钛可能存在TiO结构,H₂O₂与分子筛中的TiO作用,使相应的960 cm-1吸收峰向高波数位移。原位漫反射红外光谱考察了TS-1催化苯乙烯氧化反应,谱图分析表明,苯甲醛是主要产物,TS-1催化氧化的关键是H₂O₂吸附在TS-1的骨架钛上形成活性中心。     

Equation of State for Shock Compressed Xenon in the Ionization Regime:ab Initio Study

Quantum molecular dynamic (QMD) simulations have been applied to study the thermophysical properties of liquid xenon under dynamic compressions. The equation of state (EOS) obtained from QMD calculations are corrected according to Saha equation, and contributions from atomic ionization, which are of predominance in determining the EOS at high temperature and pressure, are considered. For the pressures below 160 GPa, the necessity in accounting for the atomic ionization has been demonstrated by the Hugoniot curve, which shows excellent agreement with previous experimental measurements, and three levels of ionization have been proved to be sufficient at this stage.     

相干光正交频分复用系统中射频导频和扩展卡尔曼滤波联合的相位噪声补偿算法

针对大线宽和高阶圆形正交幅度调制(C-QAM)的相干光正交频分复用(CO-OFDM)系统,提出一种基于射频导频(RF-Pilot)和时域扩展卡尔曼滤波相结合的相位噪声补偿算法。该算法通过在接收端预设的RF-Pilot进行时域相位噪声粗补偿,并进行信道估计和均衡。再对信道均衡后的频域数据进行预判决,结合判决后的时域数据和信道均衡后的时域数据,进行扩展卡尔曼滤波,实现相位噪声的最终补偿。基于传输速率为50Gb·s~(-1)和传输距离为100km的CO-OFDM系统在C-16QAM和C-32QAM两种调制格式下进行了算法的仿真验证。仿真结果表明,该算法相较于原RF-Pilot算法,具有较好的相位噪声补偿效果,且频谱利用率并未显著降低,算法复杂度并未显著增加。激光器线宽为2.1MHz,且使用C-32QAM时,该相位噪声算法补偿的误码性能可达到前向纠错上限,从理论上证明使用该算法可提高CO-OFDM系统对激光器线宽的容忍度,线宽较宽的廉价分布式反馈激光器可作为CO-OFDM系统的发射端光源和接收端本地振荡。该算法能扩展大线宽CO-OFDM系统在长距离接入网和城域网中的应用。     

电子激励表面等离极化激元的粒子模拟

采用极化电流微分方程,对贵金属中自由电子与外电场的共振过程进行描述。将该微分方程与麦克斯韦方程相结合,运用时域有限差分(FDTD)方法,在粒子PIC模拟软件CHIPIC3D的基础上,实现了电子激励表面等离极化激元(SPPs)的模拟。通过对100 keV电子平行于银薄膜表面运动、激励起表面等离极化激元的模拟,观测并分析了SPPs的场强及模式在银薄膜表面的分布,并验证了模拟结果的正确性。     

KTX 反场箍缩装置装配基准网的创建与分析

介绍了反场箍缩KTX装置主机主要构成部件、安装精度要求以及装配方案。通过建立一个独立于装置之外且可永久保存的装配基准网,以及对坐标系控制网的测量数据分析,确保各部件的安装定位和准确测量。     

Atomic and electronic structures of montmorillonite in soft rock

Montmorillonite is a kind of clay mineral which often causes large deformation in soft-rock tunnel engineering and thus brings about safety problems in practice. To deal with these engineering safety problems, the physical and chemical properties of montmorillonite should be studied from basic viewpoints. We study the atomic and electronic structures of montmorillonite by using density-functional theory within the local-density approximation (LDA). The results of calculation show that Al--O bond lengths are longer than Si--O bond lengths. It is found that both the valence band maximum (VBM) and the conduction band minimum (CBM) of montmorillonite are at point Γ, and the calculated direct band gap of montmorillonite is 5.35~eV. We show that the chemical bonding between cations and oxygen anions in montmorillonite is mainly ionic, accompanied as well by a minor covalent component. It is pointed out that the VBM and CBM of montmorillonite consist of oxygen 2p and cation s states, respectively. Our calculated results help to understand the chemical and physical properties of montmorillonite, and are expected to be a guide for solving the problem of large deformation of soft-rock tunnels.     

侧链型聚合物DANS-PMMA脊形条波导的制备

有机聚合物的紫外漂白,经过一系列复杂的光化学反应,会使聚合物薄膜的折射率和厚度降低。在此基础上,利用金属掩模对聚合物薄膜进行选择性紫外漂白,制备出了聚合物脊形条波导。紫外漂白不需要对聚合物薄膜进行光刻和腐蚀便可获得边缘和表面比较整齐和光滑的脊形条波导,对减少波导的散射损耗十分有利。本文介绍了利用紫外漂白和金属掩模方法制备侧链型聚合物DANS（4－dimethylamino-4’nitro-stlibene)-PMMA(polymethyl methacrylate)脊形条波导的工艺过程,并对关键工艺进行了讨论。