肌红蛋白与生物碱相互作用的光谱性质研究

用分子荧光光谱法和紫外可见分光光度法研究了肌红蛋白（myoglobin,Mb）与咖啡因、茶碱相互作用的光谱性质变化。据Stern-Volmer图得到猝灭常数,由紫外-可见吸收光谱判断均为静态猝灭,通过热力学常数得出其相互作用力为静电作用,依据Foerster偶极-偶极无辐射能量转移理论计算出Mb与生物碱间的距离,并用同步荧光光谱技术考察了生物碱对Mb构象的影响。     

火焰原子吸收光谱法测定大葱中的10种金属元素

采用火焰原子吸收光谱法测定不同品种和不同产地大葱中无机元素K、Ca、Na、Mg、Fe、Mn、Zn、Cu、Cr和Cd。结果表明：不同品种和不同产地大葱中所含无机元素差异较大,这为高营养育种和强化营养栽培提供了重要参考依据。该方法的加标回收率为96.74%—107.20%,相对标准偏差（RSD）在0.44%—2.67%之间,具有良好的准确度和精密度。     

Carrier suppression in quadruple frequency modulation by cascaded optical external modulators for millimeter-wave generation

The optical carrier suppression in optical quadruple frequency modulation by cascaded external modulators is investigated theoretically and experimentally. Theoretical analysis demonstrates that the optical carrier suppression ratio is related with not only the initial phase difference of electrical signals applied on the two modulators, but also the optical phase shift between the two modulators. The maximum suppression ratio can be achieved when the total phase difference is equal to nπ＋π/2 （n = 1, 2,…）, which is verified by experiments. By properly controlling the total phase shift, 40-GHz millimeter-wave is generated by using a 10-GHz radio frequency （RF） source and the modulators.     

高速离心风机叶片扩压器前缘倾角对其性能影响的实验研究

本文对一高速离心风机中扩压器与叶轮匹配时的气动性能进行了试验研究,主要研究了扩压器前缘不同倾角对其性能的影响.结果表明,扩压器倾角变化对性能有明显的影响;当负倾角在一定范围内时,扩压器的压升在小流量下略高于原始扩压器,而大流量下明显高于原始扩压器.另外,正倾角扩压器的性能曲线具有相交于一固定点的特征.因此,具有合适前缘倾角的扩压器可以改善风机性能.     

Theoretical Study on Inner Shell Electron Impact Excitation of Lithium

Cross sections for electron impact excitation of lithium from the ground state 1s^22s to the excited states 1s2s^2, 1s2p^2, 1s2snp （n = 2-5）, 1s2sns （n = 3 5）, 1s2pns （n = 3-5）, and 1s2pnp （n = 3-5） are calculated by using a full relativistic distorted wave method. The latest experimental electron energy loss spectra for inner-shell electron excitations of lithium at a given incident electron energy of 2500 eV [Chin. Phys. Lett. 25 （2008）3649] have been reproduced by the present theoretical investigation excellently. At the same time, the structures of electron energy loss spectra of lithium at low incident electron energy are also predicted theoretically, it is found that the electron energy loss spectra in the energy region of 55-57eV show two-peak structures.     

Theoretical Study on the Propagation of Acoustic Phonon Modes in Single-Wall Carbon Nanotubes by Different Potential Models

Propagation of a heat pulse in （10,0） zig-zag carbon nanotubes, modeled by the Brenner-H and Tersoff bondorder potentials, respectively, is investigated using a molecular dynamics simulation. The longitudinal acoustic mode, twisting phonon mode, and second sound waves are observed in the simulation. The time variations of speed and intensity of the above three phonon modes are in good agreement with the previous works based on the Brenner-I potential. Higher speed and weaker peak intensity are observed in the simulation of the Tersoff potential. The inherent over-binding of radicals and the non-local effects in Tersoff＇s covalent-bonding formula may play an important role in the heat pulse propagating simulation.     

激光调制气溶胶红外诱饵对成像制导导弹的干扰分析

概述了气溶胶红外诱饵的工作原理、特点、现状及其发展趋势。介绍了一种新型气溶胶红外诱饵———激光调制气溶胶红外诱饵。仿真实验表明,与传统的红外诱饵相比,激光调制气溶胶红外诱饵有效地增强了保护目标和对抗红外成像制导武器的能力,是气溶胶红外诱饵发展的一个新方向。     

在AlCl3和Nafion-H的催化作用下均三甲苯与γ-丁内酯的烷基化反应

 在无水AlCl3的催化作用下,均三甲苯与γ-丁内酯在室温下即可发生烷基化反应生成4-(2,4,6-三甲基苯基)丁酸. 实验结果表明,催化剂用量和反应时间是影响反应产物收率的重要因素,选择合适的反应条件可使γ-丁内酯几乎定量地转化为目标产物. 在固体高分子酸性树脂Nafion-H的催化作用下,4-(2,4,6-三甲基苯基)丁酸的收率随着温度的升高而升高,在200 ℃下收率达到最大值84.5%,选择性保持在90%左右. Nafion-H经过简单的溶剂洗涤和干燥处理后可重复使用,但每次重复使用后收率下降4%～5%. 对Nafion-H催化下该反应可能的机理进行了探讨.     

大视场航天遥感器的光学系统设计

设计了一个主镜为凸面的三镜无遮掩全反射光学系统。采用共轴系统设计、离轴视场使用的成像方式,避开了中心遮光,实现了大视场。其视场角为30°×2°,焦距为600mm,相对孔径为1/5 6。各个面都是二次曲面,成像质量接近衍射限。结果表明,用这种方法设计的系统在航天遥感领域具有很好的应用前景。     

PLGA/明胶共混体系的静电纺丝研究

采用静电纺丝技术制备了聚乳酸乙醇酸(PLGA)/明胶(Gt)的复合超细纤维, 考察了溶液浓度、电压及流速对纤维形貌的影响. 研究了不同明胶比例的纤维膜的微观形貌和干湿态的力学性能. 结果表明, 在溶液浓度0.12 g/mL, 电压7.5 kV, 流速0.8 mL/h条件下, 所得PLGA/Gt复合纤维直径较小, 粗细较均匀且缺陷少. 含有明胶的复合纤维直径远小于PLGA单纺纤维直径, 明胶的加入降低了膜的拉伸强度和断裂伸长率, 提高了膜的亲水性. 经PBS浸泡后, 复合膜的弹性得到加强. 明胶质量分数为5%和10%时, 纤维直径分布较窄, 当明胶的质量分数增加至15%时, 纤维的直径分布变宽.