纳米金-还原氧化石墨烯修饰葡萄糖氧化酶传感器的制备及其电流法检测饮料中的葡萄糖

利用纳米金(Au NPs)与还原氧化石墨烯(rGO)复合纳米材料制备了葡萄糖氧化酶生物传感器并用于饮料中葡萄糖含量的检测。将壳聚糖作为还原剂及稳定剂,通过一步法合成了Au NPs-rGO复合材料,并通过物理吸附固定葡萄糖氧化酶(GOx)来制作GOx生物传感器。该传感器在磷酸盐缓冲溶液(0.1 mol/L,p H6.0)中,-0.45 V(vs.Ag/Ag Cl)电位下电流法检测葡萄糖含量,线性检测范围为0.01~0.88 mmol/L,灵敏度为22.54μA·mmol-1·L·cm-2,检出限为1.01μmol/L,且表观米氏常数为0.497 mmol/L。该传感器用于多种饮料中葡萄糖含量的直接检测,结果满意。     

新型喹唑啉类PDE7抑制剂类似物的合成

以邻氨基苯甲酸为原料,经溴代和环合反应合成了4个新型喹唑啉类PDE7抑制剂类似物,其结构经1H NMR和ESI-MS表征。     

（Ti,Al）N薄膜光学性能的研究

研究了（Ｔｉ，Ａｌ）薄膜的光学特性，对其反射和透射光谱作了仔细分析。运用Ｈａｄｌｅｙ方程，算出一定成分（Ｔｉ，Ａｌ）Ｎ膜的折射率ｎ，消光系数ｋ随波长的变化关系。又根据透射曲线，计算出了（Ｔｉ，Ａｌ）Ｎ膜的光隙能。     

固体介质间隔层激光标准具性能的影响因素研究

针对固体介质间隔层的镀膜标准具, 以1 064 nm激光镀膜标准具为例, 首先研究了反射膜堆数对反射带宽、基底厚度以及对自由光谱区的影响:标准具的带宽随着膜层堆数增加而减小, 自由光谱区随着基板厚度的增加而减小;其次研究了基底误差对标准具中心波长定位和透过率的影响, 通过定量数值计算证明了基底误差可通过标准具的使用角度补偿;针对典型的H(LH)^m/Substrate/(HL)^mH和L(LH)^m/Substrate/(HL)^mL两个膜系结构, 研究了入射激光发散角对标准具中心波长偏移、通带半宽度、中心波长透过率和最大透过率的影响。随着激光发散角的增加, 中心波长向短波方向移动, 通带半宽度、中心波长透过率和最大透过率呈现下降的趋势, 并且第二个膜系结构的标准具性能优于第一个膜系结构的标准具。     

The thermal effect in diode-end-pumped continuous-wave 914-nm Nd:YVO4 laser

The thermal effect and the heat generation in diode-end-pumped continuous-wave 914-nm Nd:YVO₄ lasers are investigated in detail. A theoretical model of a diode end-pumped solid-state laser is constructed to analyse the influence of fractional thermal loading on the thermal effect in the Nd:YVO₄ laser based on finite element analysis. The thermal focal lengths and the end-surface deformations of laser rods in Nd:YVO₄ quasi-three-level and four-level lasers are measured and compared with the results obtained by ordinary interferometry for the demonstration of higher thermal loading in 914-nm laser. Finally the fractional thermal loading in the Nd:YVO₄ quasi-three-level laser is calculated by matching the experimental and the simulated end deformations.     

强光场中原子的电离速率

以静态场隧道电离为基础,在准静态近似的条件下,对描述强光场中原子及其各阶离子电离的电离速率进行了较为系统的总结,纠正了早期对隧道电离的电离速率公式进行讨论并且后来的计算中被广泛引用的文献「１０」中公式的错误,地部分稀有气体原子及其各了子在线偏振、圆偏振强光场中的了速度及相应的阈值光强进行了比较。     

用联合变换相关器实现灰阶图像绝对差度量光学匹配

将绝对差度量（ＡＤＭ）引入联合变换相关器（ＪＴＣ）,实现了灰阶图像光学匹配的计算机模拟实验,利用循环编码方法,通过联合变换相关器一步绝对差度量,相关后的图像通过取高阈值的分割方法来实现对目标的准确判断,针对高斯噪声干扰情况,分析了阈值选择问题,提高了灰阶目标识别抵抗器材怕畸变干扰的能力。     

关于误差方差估计渐近正态收敛速度的上,下界

考虑线性回归模型 Y_■=x_4~′β+e_■ i=1,2,…设误差序列■,i≥1满足条件:e_■ i≥1 i.i.d.,Ee_1=0,Ee_1~2=σ~2>0,∞>Var e_1~2=τ~2>0。记■_n~2=1/(n-r){sum from j=1 to n e■-sum from k=1 to r (sum from j=1 to n a_(akj)■_j)~2} δ(n)=τ~(-2)E(■_1~2-σ~2)~2I_((|■-σ~2|≥■τ)+τ~(-3)n~(1/2)|E(■_1~2-σ~2)~3I_((|■_1~2-σ~2|<(nτ)~(1/2))+τ~(-4)n~(-1)E■_1~2-σ~2)~4I_((|■-σ~2|0使得■|P(■_n~2-σ~2)/(Var■_n~2)~(1/2))≤x)-Φ(x)|≤C(δ(n)+n~(-1/2)) ■|P(■_n~2-σ~2)/(Var■_n~2)~(1/2))≤x)-Φ(x)|+n~(-1/2)≥C_1δ(n)。     

损耗对屏蔽光伏空间孤子演化特性的影响

研究了晶体损耗对屏蔽光伏空间孤子在加偏压的光伏光折变晶体中演化特性的影响.结果表明,损耗除了造成屏蔽光伏孤子光波振幅的减小外,还造成了孤子横截面的改变.对于明孤子,当入射波光强较低时,横截面随传播距离的增长而不断增大;而当入射波光强较高时,起初横截面不断压缩,而后再膨胀,并在某一传播距离上孤子横截面恢复到入射时的尺寸.对于暗孤子,不论入射光孤子光强的高低,横截面都随传播距离的增长而不断增大.虽然在传播距离足够短时,可以不考虑损耗的影响,但距离较大时,损耗将最终导致孤子崩溃. 关键词： 非线性光学 空间光孤子 光折变效应     

STABILITY OF BRIGHT SCREENING-PHOTOVOLTAIC SPATIAL SOLITONS

We present a theoretical analysis of the stability of screening-photovoltaic (SP) spatial solitons in biased photovoltaic-photorefractive materials in the case of neglecting the loss of the material and the effect of diffusion. When an incident optical beam is a SP soliton, this beam propagates along a linear path with its shape kept unchanged. When the maximum amplitude, width and functional form of an incident optical beam are slightly different from those of a SP soliton, the beam reshapes itself and tries to evolve into a solitary wave after a short distance. That is, these SP solitons are stable against small perturbations. However, optical beams that significantly differ from SP soliton solutions tend to experience larger cycles of compression and expansion, and their maximum amplitudes oscillate with propagation distances. The larger the perturbations, the stronger the oscillation.