SUPPORT VECTOR MACHINE FOR STRUCTURAL RELIABILITY ANALYSIS

Support vector machine (SVM) was introduced to analyze the reliability of the implicit performance function, which is difficult to implement by the classical methods such as the first order reliability method (FORM) and the Monte Carlo simulation (MCS). As a classification method where the underlying structural risk minimization inference rule is employed, SVM possesses excellent learning capacity with a small amount of information and good capability of generalization over the complete data. Hence, two approaches, i.e., SVM-based FORM and SVM-based MCS, were presented for the structural reliability analysis of the implicit limit state function. Compared to the conventional response surface method (RSM) and the artificial neural network (ANN), which are widely used to replace the implicit state function for alleviating the computation cost, the more important advantages of SVM are that it can approximate the implicit function with higher precision and better generalization under the small amount of information and avoid the "curse of dimensionality". The SVM-based reliability approaches can approximate the actual performance function over the complete sampling data with the decreased number of the implicit performance function analysis (usually finite element analysis), and the computational precision can satisfy the engineering requirement, which are demonstrated by illustrations.     

MOF-1和Tb@MOF-1荧光探针的设计、合成及对痕量Cr2O72-、S2O82-离子的识别

采用5-（（4-吡啶基）甲氧基）-异烟酸（H₂PLIA）、1,3,5-三（1-咪唑基）-苯（TIB）合成了金属有机骨架[Cd （PLIA）（TIB）]_n （MOF-1）。MOF-1是具有理想一维孔道的二维结构化合物,其一维孔道由柔性三角形PLIA^2-配体和刚性三角形TIB配体间隔形成。利用MOF-1易掺杂的优势,采用后修饰合成策略制备了Tb@MOF-1。对MOF-1和Tb@MOF-1进行了基本表征及荧光探针性能研究。2种探针材料具有相同的结构。MOF-1和Tb@MOF-1分别对水溶液中的Cr₂O₇^2-和S₂O₈^2-离子具有较强荧光识别能力,均有响应时间快,稳定性、选择性、灵敏度高的特点。研究了MOF-1和Tb@MOF-1对Cr₂O₇^2-和S₂O₈^2-的荧光识别机理,其不同可能与Tb³⁺离子掺杂有关。     

云母/莫来石可加工微晶玻璃的制备与析晶

通过调整SiO2-MgO-Al2O3-K2O-F基础玻璃的组成和热处理条件,制备了云母/莫来石复合可加工微晶玻璃.应用扫描电子显微镜和X射线衍射技术研究了可加工微晶玻璃的析晶特征.结果表明:添加3.0;ZnO(质量分数)的基础玻璃析出了锌尖晶石相,而锌尖晶石的析出抑制莫来石相的形成,没有得到云母/莫来石复合材料.当玻璃中添加3.0;的V2O5后,在试样中同时析出莫来石和云母晶体,但没有形成莫来石/云母复合的组织.含V2O5 8.0;的玻璃在等温析晶中,从表面析出莫来石和粗大枝状的云母晶体,云母间相互交错程度较低,只有在随炉升温的情况下,云母晶体以莫来石相为核心异质生长,形成均匀分布的云母/莫来石复合微晶玻璃材料.     

锶内标法在溶液法制样-X射线荧光光谱法测定天然铀产品(U3O8)中铀的可行性研究

建立了溶液法制样-X射线荧光光谱法(XRFS)测定天然铀产品(U3O8)中铀元素的含量,并从样品中锶含量水平、锶元素分析谱线的选择、锶内标化合物的选择、样品中硫含量对锶的影响等角度探讨了锶内标法的可行性.将0.60000 g干燥后的内标物碳酸锶与1.00000 g天然铀产品(U3O8)混合,用磷酸和硝酸在电炉上加热消解...     

一维钴(Ⅱ)/镍(Ⅱ)配位聚合物的合成、结构、磁性及荧光传感性质

采用水热法合成了2个新的配位聚合物[Co(L)_0.5(1,4-bib)(H₂O)₃]_n (1)和[Ni(L)_0.5(1,4-bib)(H₂O)₃]_n (2)(H₄L=1,4-二(2,6-二甲基-3,5-二羧基吡啶基)苯,1,4-bib=1,4-双(1-咪唑基)苯),通过X射线单晶及粉末衍射、元素分析、红外光谱分析和热重分析对其结构进行表征。结构分析表明配合物1和2为异质同构,均为一维结构。通过变温磁化率测量发现,配合物b>1和2中的Co(Ⅱ)/Ni(Ⅱ)离子之间存在反铁磁相互作用。此外,配合物 1可通过荧光猝灭法检测头孢克肟(CEF),配合物 2可用来检测四环素(TET),该方法灵敏度高、选择性好,其检出限分别为0.86 μmol·L^-1 (CEF)和0.49 μmol·L^-1 (TET)。     

单线态氧的检测及分析应用研究进展

综述了单线态氧（^1O2）的测定方法。介绍了单线态氧的ESR、磷光光度、分光光度、化学发光和荧光法的基本原理、方法研究进展和分析应用情况,并重点介绍了化学发光法和荧光法,同时比较了这几种方法的特点。     

Meso approaches for the creep damage behavior of nickel-base directionally solidified superalloys

IntroductionNickel-basehightemperatureresistancesuperalloysarsewidelyusedingasturbinesandjetengines.DireetionallysolidificationwasintroducedtoenhancecreepsbengthbyelindnahnggrainboundariesnormaltotheappliedstresswherevoidsarelikelytOoccurundercreepload.Inpractice,however,theappliedstressmaynotbeuniaxialnordirectedparalleltOthegrainboundaries.Singlecrystalswerethusdeveloped.CongregationoflowtempefAnremeltingelementsongrainboundaries,grainboundaryoxidation)etc.,areadditionalfactorsthatwoulddeg…     

涡轮冷却叶片气动与传热设计优化

提出了航空发动机涡轮冷却叶片叶栅气动与传热自动优化方法,利用函数解析成型方法实现了冷却叶片几何模型的参数化与自动生成,可以建立任意冷却内腔数量的叶片模型;基于N-S方程实现叶片流体域与固体域的流-热耦合分析;采用KS函数方法将多目标优化问题转化为单目标函数进行优化,以总压损失、叶片最高温度和平均温度最小为优化目标进行了自动优化,改善了叶片性能。     

On the study of the initiation of the micro crack on the smooth surface of polycrystalline

Crystallographic plasticity was applied to study the initiation of micro cracks on the smooth surface of polycrystalline under uniform applied stress. Even under the uniform external stress, due to the different crystallographic orientations of the grains in the polycrystalline, there is un-uniform stress distribution and the deformation is also not uniform. Under the fatigue loading, the roughness increases with the number of fatigue, and deformation will localize in some places, where micro cracks form.     

侧压式道气道流场特性研究

应用表面油流和压力测量技术,结合数值模拟方法研究了超燃冲压发动机侧压式进气道无支板和有支板两种典型工况的基本流动特性.结果表明:由侧壁诱发的后掠激波与底板边界层相互作用,形成一对逆向旋转的漩涡,该漩涡在下游不断发展并偏离底板,在出口截面形成一个低马赫数低总压区;支板的引入增加了压缩率,但同时导致底板与侧壁边界层严重分离,使进气道性能偏离设计工况.