金属酞菁催化氧化β-甲基萘的研究

研究了金属酞菁催化氧化β-甲基萘制备甲基萘醌的反应,考察了催化剂种类、氧化剂种类、投料比、反应温度和时间等对反应的影响。结果表明双核磺化酞菁铜表现出良好的催化活性,在双氧水为氧化剂,醋酸为溶剂的条件下,催化剂质量分数为15%、双氧水与甲基萘的摩尔比为5∶1、反应温度为60℃、时间为7 h,目标产物的收率最高达到47.8%。     

Field Emission Enhancement of Carbon Nanotubes by Surface Modification

By employing a multi-walled carbon nanotube （MWCNT） film as the substrate, we obtain Fe tipped carbon nanorods or carbon nanoparticles grown on the outer walls of MWCNTs by combining sputtering deposition of Fe films and rf plasma enhanced chemical vapour deposition at high temperature. Scanning electron microscopy and high-resolution transmission electron microscopy are used to examine the structure of carbon nanorods and carbon nanoparticles. In addition, the formation mechanism is discussed briefly. The electron field emission tests indicate that the turn-on field （at 10μA/cm^2） of the treated MWCNT films decreases from 2.4 V/μm to O. 79 V/μm and the field emission current is relatively stable. The enhanced field enhancement factor, increasing emission densities coming from the grown nanorods and nanoparticles, and H terminated by H plasma a11 are responsible for the enhancement of the field enhancement factor.     

微量热法研究Na+,K+-ATPase酶促反应

首次用微量热方法研究了Na^ ,K^ -ATPase催化ATP水解的酶促反应，在310．15K，PH＝7．4的100mmol.L^-1Tris-HCl,100mmol.L^-1NaCl,10mmol.L^-1KCl,3mmol.L^-1MgCl2缓冲溶液环境下，用对比进度法得出了Na^ ,K^ -ATPase酶促反应的米氏常数Km值和最大反应速率Vm值，所得常数值与文献给出的相符，并用比色法得出了一致的Km和Vm值，同时初步研究了酶预稀释对酶促反应的影响。     

科技产业化实施系统预研究

科技产业化实施系统是科研成果的物化和转化的关键，其发展和完善将直接影响到科学技术转化为生产力的程度。本将采用系统动力学的方法论对科技产业化实施系统进行研究和分析。     

壳脑酸二甲酯溴化反应动力学的研究

本文用紫外分光光度法首次跟踪研究了壳脑酸二甲酯(dimethl Shellolate)与溴加成反应的规律。结果表明该反应符合二级反应规律。其中自由基反应接近2/3。极性历程占1/3强:该反应活化能为66.8kJ/mol,为室温下便可发生的反应:盐效应可以在一定程度上阻滞反应。     

激光辐照下双层钢板接触界面对传热的影响

 首次提出激光辐照下双层金属板界面会由于变形而产生脱离，从而对双层板之间的传热有明显的影响，通过实验和数值模拟验证这一提法。该工作丰富了接触热阻概念，有助于进一步加深对强激光破坏机理的研究，同时提供了一条有效的抗强激光加固的途径。     

The Discovery and Geological Feature of Kyanite-Topazite in High-Pressure Belt From Central China

For the first time, we find kyanite-topazite which is similar to the white schist from abroad, in Jiangsu, Anhui, Henan of China. Because of intercontinental obduction and collision, the kyanite-topazite is formed from the superhigh-pressure metamorphism of sedimentary rock in continental crust, at the depth of mantle. Kyanite-topazite runs parallel to blue schist, eclogite and constitutes the high-pressure metamorphic belt in Central China. Its original rocks are a set of sedimentary rock series which is mainly composed of marginal shallow marine facies to continental facies pelitic to magnesium carbonatite, both rocks exist in Precambrian Middle-Upper Proterozoic metamorphic strata.     

1,6,9,13-四氧双螺[4.2.4.2]十四烷-2,10-二酮的晶体结构测定

1,6,9,13-Tetraoxadispiro[4.2.4.2]tetradecane-2,10-dione,C_(10)H_(12)O_6,are colourless transparent crystal,and belonges to monoclinic system with space groupP2_1/n.The unit cell parameters are:a=9.051(1)(?),b=6.051(2)(?),c=10.098(1)(?),β=112.57(1)°,Z=2.A four-circle diffractmeter has been used to observe the diffrac-tion intensities.The crystal structure has been determined by direct method and its para-meters refined by the block-matrix least-squares method.The final agreement factor isR=0.065.The result shows that two saturated γ-lactone ring are connected to the dioxanering in dispiro arrangement.     

基于角点特征的机载摄像系统电子稳像算法

为了消除载体姿态变化和振动造成的视频抖动,提出了一种机载摄像系统的电子稳像算法。将图像分为若干个块,每个块中取一个点作为特征点,采用块匹配算法在局部区域进行特征点匹配,然后利用改进的随机一致性检测算法剔除误匹配的特征点,最后采用卡尔曼滤波算法对图像的运动参数进行滤波,得到稳定后的视频图像。该算法时间复杂度和空间复杂度低,便于在硬件平台上实现,实验结果表明,该算法稳像精度高,精度达到1个像素,适应性好,能较好地实现图像序列稳定。