全氟和多氟烷基磺酸的研究 VIII: N-(3'-三氯硅基丙基)-3-氧杂全氟烷基磺酰胺及基衍生物的合成

3-OXaperfluoroalkanesulfonyl fluoride (1) reacted with allylamine to give the corresponding N-allylsulfonamide 2 which on treatment with sodium methoxide and methyl iodide affrded N-methyl-N-allyl-3 -oxaperfluoroalkanesulfonamide 3. 2 and 3 were converted to the corresponding substituted trichlorosilanes 4 and 5 respectively on treatment with trichlorosilane in the presence of chloroplatinic acid. Compounds 5 reacted with methanol and pyridine to give the corresponding trimethoxysilane 6. The elemental analysis, IR, ^1H NMR and 19F NMR data of these new compounds were recorded in Table 1-4. The compounds 4, 5 can be used for the treatment of glass surface to render it water-proof and solvent-proof.     

四氟乙烯齐聚体的反应: II.四氟乙烯五聚体和烯丙醇的反应及反应产物的转化

The reaction of perfluoro- (3, 4-dimethyl-3-ethylhexene-(2)) (1) with allyl alcohol under different conditions gave different products. Compound 1 reacted with sodium allyl alcoholate yielding 2-(1'-allyloxy-tetrafluoroethyl)-perfluoro(3-methyl-3-ethylpentene- (1))(2). In the presence of triethylamine, 1 reacted with allyl alcohol to give 2-allyloxy-perfluoro (3, 4-dimethy1-4-ethylhexene- (2))(3), and in the presence of acetone and K2CO3 to give compound 4. These reactions all gave allyl-3-trifluoromethyl-3- pentafluoroethyl-2,2-dihydro-pentafluorovalerate (5a) as byproduct. Compound 1 reacted with allyl alcohol in the presence of triethylamine at 20-22`C to give 2, at 30-35`C to give a mixture of 2 and 3 and at 35-40`C to give a mixture of 3 and 5a respectively. Compound 2 was transformed to compound 4 in acetone and in the psesence of K2CO3, \o\ compound 5a or 5b in the corresponding alcohol and to compound 6 on reacting with dimethylamine. Compound 2 as well as 3 was converted to perfluoro-(3-ethyl-2,3,4,5- tetramethyl-2,3-dihydrofuran) (7) by KF in sulpholane.     

四氟乙烯齐聚体的反应 III: 四氟乙烯四聚体与脂族胺以及烷氧亲核试剂的反应

3, 4-Bis (trifluoromethyl)-perfluorohexene-(3) (1) reacted with diethylamine to give the 1-N, N-diethylamino-2-pentafluoroethyl -3-trifluoromethyl-perfluoropentene-(1)(2), which was easily hydrolyzed to the corresponding N, N-diethyl-2-penta-fluoroethyl- 3-trifluoromethyl-perfluoropenteno-(2)-amide (3). When compound 1 was allowed to react with n-butyl amine at 40-50`C, the 2,3,4-tris(trifluoromethyl)-4-pentafluoroethyl-1-n-butyl-aza- cyclobutene-(2) (5) was obtained as the main product and at-30-40`C, 3,4-bis(trifluoromethyl)-4-n-butylamino-perfluorohexene-(2) (4) as the main product. The isomers 3, 4-bis(trifluoromethyl)-4-allyloxy-perfluoro-hexen-(2) (6) and 2-pentafluoroethyl-3-trifluoromethyl-3-allyloxy-perfluoropentene-(1)(7) were formed when 1 was reacted with sodium allyl alcoholate.     

中子半影成像图像反演方法研究

 给出了中子半影成像技术的原理;分析了系统分辨率的影响因子;利用MCNP软件对中子半影成像过程进行模拟;用改进的逆滤波和维纳滤波两种方法对成像主轴上一点源和偏轴两点源的编码图像进行重建,并对编码像在降低噪声和去除本底前后的反演结果进行了比较。模拟结果表明维纳滤波法能够更好地抑制统计噪声。     

正弦波纹扁球壳的非线性强迫振动

波纹壳是传感器弹性元件的一类重要形式,也是精密仪器仪表弹性元件中的一类重要形式。由于波纹壳形状复杂、参数众多、厚度薄,对其进行非线性分析非常重要同时也是十分困难的。本文考虑一种在传感器弹性元件中有重要应用价值的正弦波纹浅球壳体,将这种壳体视为结构上的圆柱正交异性扁球壳,根据Andryewa的思想,分别得到了正弦波纹壳径向、环向在拉伸、弯曲下的等价的四个各向异性参数;建立了正弦波纹扁球壳的非线性强迫振动微分方程;得到了正弦波纹扁球壳非线性强迫振动的共振周期解及幅频特性曲线。     

关于Simmons模型的几点讨论

本文介绍了Simmons模型的参数选择方法 ,并对几种Simmons模型的精度、合作程度进行了比较 ,最后推荐一种新的随机化装置 ,不仅在精度上有所提高 ,而且操作简便 ,提高了被访者的合作程度     

二维沸石及其在大分子催化转化领域的研究进展

与三维结构沸石不同,二维沸石由于其更开放的孔道结构、更大的比表面积、更易暴露的酸性位点,在大分子和扩散限制催化领域显示了特殊优势。通过各种合成和后处理方法,能够调控二维沸石及其衍生材料的孔道种类、大小与分布,从而适用于不同的催化过程。本文综述了近年来二维沸石的合成与应用进展。     

损伤围岩中爆炸应力波动的数值模拟

应用有限元方法分析了硐室损伤围岩中爆炸应力波的传播和应力分布特征，通过引入JHC本构模型和岩石损伤变量D探讨了应力波作用下岩体的损伤演化模式。研究表明:围岩初始损伤对后续爆炸应力波的波动性质、作用范围和围岩应力分布具有不同程度的影响。当初始损伤超过某临界值后会显著地影响应力波的波动范围和围岩应力分布；在一定爆炸当量下，爆炸应力存在一个有效作用范围Lp，该范围塑性区以内，爆炸应力对岩体的损伤随围岩初始损伤增大而增大；有效作用范围Lp以外，围岩初始残余非弹性变形积累和单元残余拉应力可以平衡爆炸应力波动产生的损伤叠加效应，耗散了爆炸应力作用和波动能量。分析了产生在这种现象的原因。给出了有效作用范围Lp与围岩初始等效应力p之间的经验关系。     

美国中学数学教材中的函数概念及特点分析

函数是中学数学中的重要概念，同时又是近代数学的重要基础．由于它的意义比较抽象，所以就我国目前中学数学教材来看，所采用的函数定义，基本上还是属于在函数概念的发展史上，第三次扩张的“对应关系”的函数概念．而在美国的数学教材中对函数概念的处理则另辟蹊径，采...