全文获取类型
收费全文 | 89篇 |
免费 | 14篇 |
国内免费 | 120篇 |
专业分类
化学 | 188篇 |
力学 | 2篇 |
物理学 | 33篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2021年 | 3篇 |
2020年 | 2篇 |
2019年 | 3篇 |
2018年 | 3篇 |
2017年 | 2篇 |
2016年 | 1篇 |
2015年 | 3篇 |
2014年 | 6篇 |
2013年 | 6篇 |
2012年 | 3篇 |
2011年 | 6篇 |
2010年 | 4篇 |
2009年 | 14篇 |
2008年 | 6篇 |
2007年 | 11篇 |
2006年 | 8篇 |
2005年 | 11篇 |
2004年 | 12篇 |
2003年 | 16篇 |
2002年 | 16篇 |
2001年 | 25篇 |
2000年 | 23篇 |
1999年 | 14篇 |
1998年 | 7篇 |
1997年 | 5篇 |
1996年 | 6篇 |
1994年 | 1篇 |
1992年 | 4篇 |
排序方式: 共有223条查询结果,搜索用时 15 毫秒
52.
53.
A coordination polymer of [Zn(BBP)(p-CPOA)]n(where BBP is 2,6-bis(benzimidazolyl)pyridine and p-CPOA is p-carboxylato-phenoxyacetate dianion) has been synthesized and characterized by elemental analysis, IR, TG, and the single crystal structure was determined by X-ray diffraction. The crystal crystallizes in the monoclinic system, space group of P21/n with a=1.397 3(4) nm, b=1.138 4(3) nm, c=1.575 9(5) nm, β=91.805(1)°, V=2.505 4(13) nm3, Z=4, Dc=1.513 g·cm-3, μ=1.030 mm-1 and F(000)=1 168. Zn(Ⅱ) ion is penta-coordinated and surrounded by two carboxylate O atoms from two different p-CPOA groups in a bis-monodentate mode, three N atoms from the 2,6-bis(benzimidazolyl)pyridine ligand, completing a distorted trigonal bipyramidal coordination configuration. The structure is a helix with a long pitch of 1.138 4 nm. Under direction of supramolecular recognition and attraction, the adjacent chains are formed the double-stranded chain through π-π stacking between the 2,6-bis(benzimidazolyl)pyridine ligands and hydrogen-bonding interactions. A three-dimensional supramolecular network is further constructed through these interactions between the helices. The TG shows that its chain skeleton is thermally stable up to 382 ℃. CCDC: 626650. 相似文献
54.
55.
首次采用共振光散射、荧光光谱并结合平衡透析法研究了 I- 与人血清白蛋白 ( human serum albumin,简称 HSA)或牛血清白蛋白 ( Bovine Serum Albumin,简称 BSA)结合平衡。首次观测到 I- 对 HSA和 BSA的共振光散射有增强效应 ,却导致 35 0和 70 0 nm处的荧光淬灭。平衡透析的结果表明 :I- 与 HSA或 BSA的结合平衡不适合用 Scatchard模型处理 ,却能较好地符合相平衡分配规律 ,表观相分配常数数量级为 1 0 4。Cl-很可能是通过改变溶液的离子强度影响 I- 的结合。根据不同的 p H条件下的透析结果 ,推测 I- 是与白蛋白上质子化的碱性氨基酸残基结合。 相似文献
56.
在室温下,MnSO4·H2O和1,2,4-苯三甲酸(H3BTC)反应得到化合物[Mn(H2BTC)2(H2O)4]·2H2O (1),化合物1和CuSO4·5H2O反应得到化合物[Cu(HBTC)(H2O)1.5]·H2O (2)。化合物1是一个单核分子化合物。在化合物1中,每个锰离子和两个H2BTC-离子及四个水分子配位。化合物2中,每个铜离子和三个HBTC2-及两个水分子配位,其中的一个水分子起桥联作用从而形成二维网状结构。 相似文献
57.
58.
59.
[Zn(o-bda)(phen)(H2O)]n·nH2O (C22H20N2O6Zn) (1) [where o-bda is o-phenylenediacetic acid dianion and phen is 1,10-phenanthroline] crystallizes in triclinic system, space group P1 with a=0.826 5(4) nm, b=1.042 4(5) nm, c=1.238 1(6) nm, α=76.987(9)°, β=70.987(9)°, γ=78.281(8)°, V=0.9728(8) nm3, Z=2, Dc=1.617 g·cm-3, μ=1.308 mm-1 and F(000)=488. Zn(Ⅱ) ion has a distorted trigonal bipyramid coordination geometry formed by two carboxyl O atoms from two different o-bda groups, two N atoms from the phen ligand and one terminal water molecule. Adjacent Zn(Ⅱ) ions are interlinked by o-bda groups into a infinite zigzag chain structure with a Zn…Zn distance of 0.825 6(4) nm. The adjacent zigzag chains may also be paired under direction of supramolecular recognition and attraction through both π-π stacking and hydrogen bonding interactions into molecular zippers, which further interlinked into a three-dimensional supramolecular network by these noncovalent interactions. CCDC: 600935. 相似文献
60.
The reaction of MoO2(acac)2 with 2-amino-6-methyl-pyridine (amp) in the mixed solvent of DMF (N,N-dimethylformamide) and water affords the title complex [H-amp]4- [Mo8O26(DMF)2]·2H2O which was characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction analysis with the following crystallographic data: C30H54Mo8N10O30, Mr = 1802.35, monoclinic, P21/n, a = 8.631(1), b = 24.260(3), c = 13.351(2)A,β= 104.688(3)°, V = 2704.2(7) A3, Z = 2, Dc = 2.213 g/cm3, μ =1.890 mm-1 and F(000) = 1760. The final R = 0.0281 and Wr = 0.0620 for 4935 observed reflections with I > 2σ(I). X-ray structure analysis has confirmed the existence of γ-[Mo8O26]4- anion in the molecule. Eight MoO6 distorted octahedra share edges with short terminal Mo-O bonds from 1.691(3) to 1.749(2)A, medium bonds from 1.868(2) to 1.965(2) A And long bonds from 2.059(2) to 2.450(2) A. In the terminal site there exist two DMF ligands bound to the Mo atom through O atoms with the Mo-ODMF bond length of 2.166(3) A, affording a bond strength of 0.433. A three-dimensional network structure was formed through hydrogen bonds. 相似文献