激光偏振特性对丙酮和氧气多光子电离质谱信号的影响

在极性分子丙酮复合物CH3COCH3*H2O和非极性分子氧气的REMPI谱中,母体离子信号强度与激光偏振方向的关系是不同的.改变532 nm激光偏振方向,记录了两种分子母体离子信号强度,实验结果表明,对于氧气分子的母体离子信号强度,激光偏振方向的改变对其没有影响,而对于CH3COCH3*H2O的母体离子信号强度,随偶极矩与激光偏振方向夹角的增加,其母体离子信号强度呈余弦曲线变化,且与夹角余弦的2.1次幂成正比.理论分析显示,CH3COCH3*H2O的REMPI母体离子信号强度应与此夹角的余弦的2次幂成正比.这就说明实验结果和理论分析是相符的.     

One-colour resonant two-photon ionization spectrum of the 1-fluoronaphthalene dimer and ab initio calculation

The one-colour resonant two-photon ionization(R2PI) spectrum of the 1-fluoronaphthalene(1FN) dimer has been studied in the wavelength range of 304 to 322 nm by using a supersonic molecular beam and time-of-flight mass spectrometry.Compared with the original band 00(at 313.8 nm) of the S1 ← S0 transition of the 1FN monomer,a red-shifted band was observed in the 1FN dimer spectrum at about 315 nm with a relatively large linewidth,nearly 2 nm.Based on the consideration of inductive effect and ab initio calculations,this red-shifted band is assigned to the first electronic excited transition of the 1FN dimer.A possible geometric structure of the 1FN dimer is also obtained with calculations that the two 1FN molecules are combined through two hydrogen bonds which are formed between the hydrogen atom of a molecule and the fluorine atom of a neighbouring molecule.A time-dependent calculation was also carried out and the results are consistent with the experimental data.     

复合式补偿器的温度效应

石英晶体有着较大的温度膨胀系数,因而温度变化会引起石英晶体制作器件的使用误差.为了减小这种误差,研究了二元复合式补偿器相位延迟随温度的变化情况.结果表明,温度变化越大,波片级数越大,补偿相位受到的影响也越大;理论计算表明,补偿相位在一定的温度范围内与起偏镜转动的角度成线性关系.实验结果与理论结果相一致.该研究结果对于复合补偿器在不同环境下的正确使用有一定的参考价值.     

Optical and Electrical Properties Evolution of Diamond-Like Carbon Thin Films with Deposition Temperature

Optical and electrical properties of diamond-like carbon （DLC） films deposited by pulsed laser ablation of graphite target at different substrate temperatures are reported. By varying the deposition temperature from 400 to 25℃, the film optical transparency and electrical resistivity increase severely. Most importantly, the transparency and resistivity properties of the DLC films can be tailored to approaching diamond by adjusting the deposition temperature, which is critical to many applications. DLC films deposited at low temperatures show excellent optical transmittance and high resistivity. Over the same temperature regime an increase of the spa bonded C content is observed using visible Raman spectroscopy, which is responsible for the enhanced transparency and resistivity properties.     

基于Matlab的单轴晶体锥光干涉图样模拟

根据偏振光干涉原理,在Matlab环境中完成晶体电光调制实验中锥光干涉图样的计算模型建构和仿真模拟,其结果图样细致逼真. 在此基础上,模拟出其他情况下单轴晶体锥光干涉图样,从而使复杂的干涉现象变得直观形象,为光学实验教学提供了有效的辅助手段.     

266 nm激光作用下对溴甲苯多光子电离质谱的研究

利用266 nm激光作为光源研究了对溴甲苯分子的多光子电离解离,得到了对溴甲苯的多光子电离飞行时间质谱.实验测得了部分碎片离子占总离子信号的分支比对激光强度的依赖关系,分析了对溴甲苯分子的多光子电离解离机理,讨论了C4H+7,C6H+,C5H+5等碎片离子的可能形成过程.结果表明,碎片离子主要是经过离子离解阶梯模式产生.对实验中观测到的由激光强度变化引起的质谱峰值漂移现象作了说明.     

激光光谱技术在环境监测中的应用专题系列（Ⅲ）：激光质谱法对机动车尾气中污染物的实时监测

激光质谱法通过共振增强多光子电离把紫外光谱和飞行时间质谱结合起来,是具有高选择性、快速和高灵敏度的痕量化学污染物质分析方法。文章介绍了其原理和在机动车尾气监测上的应用。     

氟氯甲醇及其异构体的气相离解反应研究

在G3(MP2)水平上,通过对CH2ClFO的势能面(PES)上关键驻点的能量计算,共找到3种中间体,14个过渡态,20种产物通道,并对氟氯甲醇(CHClFOH)及其异构体(CH2FOCl和CH2ClOF)的气相解离机理进行了讨论。结果表明：四中心的1,2-HX(X=Cl,F)消去反应是氟氯甲醇的主要通道,但对于其同分异构体,OCl和OF键断裂又是强竞争过程。     

多晶体分析--德拜法的实验数据处理问题探讨

本文主要是探讨用均方差和最小二乘法的思想对多晶体分析——德拜法实验的数据进行有效的处理,其目的在于减少在实验数据处理过程中产生的误差。     

X波段高功率宽频带双螺旋反射阵列天线的设计

为了提升高功率微波辐射天线的带宽,提出并设计了一种X波段高功率圆极化反射阵列天线,该天线采用喇叭天线作为馈源,阵列天线单元由可旋转金属双螺旋线构成,通过旋转螺旋线可以实现360°的相位补偿,同时反射损耗极小。设计了15×15矩形栅格螺旋反射阵列天线,全波仿真结果表明:该口径为315 mm的阵列天线在中心频点9.3 GHz下,增益为28 dB,轴比为0.53 dB,口径效率为52.6%;在8.5~10.9 GHz的频带范围内增益大于26.8 dB,轴比小于1.14 dB,1 dB增益带宽和40%以上口径效率带宽均大于21%;在真空中所能承受的最大功率约为207 MW。