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31.
In this paper, the electroluminescence quenching mechanism
in a 5,6,11,12-tetraphenylnaphthacene (Rubrene) doped host--guest
system is studied by utilizing a specially designed organic
light-emitting diode with an emission layer consisting of a few
periodic host/guest structures. Tris-(8-hydroxyquinoline) aluminium
(Alq3) and Rubrene are used as the host and the guest,
respectively. The thickness variation of the guest layer in each
period enables the study of the effect of molecule aggregation, and
the thickness variation of the host layer suggests a long range
quenching mechanism of dipole--dipole interaction. The long range
quenching mechanism is a F?rster process, and the F?rster
radius of Rubrene is between 3 and 10~nm. 相似文献
32.
快速准确地识别污染气体种类是光谱法环境监测技术对分类器的基本要求。分段线性分类器简单、计算量小,可以较好的逼近非线性分界面。文章根据最大化分类间隔的思想,结合分段线性分类器和线性支持向量机,设计了单边分段线性分类器优化算法。对某气体模拟剂光谱的分类实验表明,经过优化算法训练的分段线性分类器可以用较少的超平面逼近非线性分界面,而且得到更高的识别准确率。 相似文献
33.
实验中共制备了五种有机量子阱结构电致发光器件,分别对这五种量子阱结构器件的电致发光特性进行了研究,分析了量子阱结构的周期数和势垒层的厚度对器件电学性能的影响.实验结果表明适当周期数的量子阱结构器件的亮度和电流效率比传统的三层结构器件的要大,主要原因是量子阱结构对电子和空穴的限制作用,这种限制作用提高了电子和空穴在发光层中形成激子和复合的概率,从而提高了发光的亮度和效率.当改变阱结构器件中势阱层的厚度时,也会对器件的亮度和效率产生影响,采用适当的势阱层厚度能够提高器件的亮度和效率.
关键词:
量子阱结构
电致发光
电流效率
光谱 相似文献
34.
We investigate the effects of (N,N’-diphenyl)-N,N’-bis(1-naphthyl)-1,1’-biphenyl-4,4’-diamine (NPB) buffer layers on charge collection in inverted ZnO/MEH-PPV hybrid devices. The insertion of a 3-nm NPB thin layer enhances the efficiency of charge collection by improving charge transport and reducing the interface energy barrier, resulting in better device performances. S-shaped light J–V curve appears when the thickness of the NPB layer reaches 25 nm, which is induced by the inefficient charge extraction from MEH-PPV to Ag. Capacitance–voltage measurements are performed to further investigate the influence of the NPB layer on charge collection from both simulations and experiments. 相似文献
35.
36.
Solar cells based on the poly(N-vinylcarbazole):porphyrin: tris(8-hydroxyquinolinato) aluminium blend system 下载免费PDF全文
Organic solar cells based on poly(N-vinylcarbazole)(PVK):porphyrin:tris(8-hydroxyquinolinato) aluminium(Alq3) blend p-n junction systems have been fabricated in this work.The roles of the different components in the blend system and of the amount of porphyrin have been investigated.The 5,10,15,20-tetraphenylporphyrin(TPP) and 5,10,15,20-tetra(o-chloro)phenylporphyrinato-copper(CuTClPP) are used in the solar cells.The results show that TPP is better than CuTClPP in enhancing the performance of PVK:Alq3 solar cells.When the weight ratio of PVK:TPP:Alq3 is 1:1.5:1,the best performance of solar cell is obtained.The open circuit voltage(V oc) is 0.87 V,and the short circuit current(J sc) is 17.5 μA·cm 2.In the ternary bulk hereojunction system,the device may be regarded as a cascade of three devices of PVK:TPP,TPP:Alq3 and PVK:Alq3.PVK,TPP and Alq3 can improve the hole mobility,light absorption intensity and electron mobility of the ternary bulk hereojunction system,respectively. 相似文献
37.
38.
Performance improvement cells using bathocuproine of MEH-PPV:PCBM solar and bathophenanthroline as the buffer layers 下载免费PDF全文
In this work, bathocuproine (BCP) and bathophenanthroline (Bphen), commonly used in small-molecule organic solar cells (OSCs), are adopted as the buffer layers to improve the performance of the polymer solar cells (PSCs) based on poly(2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene) (MEH-PPV): [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) bulk heterojunction. By inserting BCP or Bphen between the active layer and the top cathode, all the performance parameters are dramatically improved. The power conversion efficiency is increased by about 70% and 120% with 5-am BCP and 12-nm Bphen layers, respectively, when compared with that of the devices without any buffer layer. The performance enhancement is attributed to BCP or Bphen (i) increasing the optical field, and hence the absorption in the active layer, (ii) effectively blocking the excitons generated in MEH-PPV from quenching at organic/aluminum (Al) interface due to the large band-gap of BCP or Bphen, which results in a significant reduction in series resistance (Rs), and (iii) preventing damage to the active layer during the metal deposition. Compared with the traditional device using LiF as the buffer layer, the BCP-based devices show a comparable efficiency, while the Bphen-based devices show a much larger efficiency. This is due to the higher electron mobility in Bphen than that in BCP, which facilitates the electron transport and extraction through the buffer layer to the cathode. 相似文献
39.
采用密度泛函理论B3LYP方法研究了CF_2自由基与HNCO的反应机理,并在B3LYP/6-311++G**水平上对反应物、中间体、过渡态进行了全几何参数优化.为了得到更精确的能量值,又用CCSD(T)/6-311++G**方法计算了在B3LYP/6-311++G**水平优化后的各个驻点的相对能量.根据统计热力学及用Winger校正的Eyring过渡态理论,利用自编程序,计算不同温度下低势垒反应的平衡常数和速率常数.计算结果表明单重态的CF_2自由基与HNCO的反应有四条反应通道,三重态的CF_2自由基与HNCO的反应有两条反应通道.其中单重态反应通道CF_2+HNCO→1IM1→1TS1→1IM2→1TS2→1IM3→CF_2NH+CO(P1)为主反应通道.三重态反应通道CF_2+HNCO→~36IM1→~36TS1→~36IM2→HCF_2+NCO(~3P5)为主反应通道. 相似文献
40.
采用密度泛函理论B3LYP方法研究了单重态GeH2与HNCO的反应机理.在B3LYP/6-311++G**水平上对反应物、中间体、过渡态进行了全几何参数优化,通过频率分析和内禀反应坐标(IRC)确定中间体和过渡态,用QCISD(T)/6-311++G**方法计算了各个驻点的单点能.计算表明单重态的锗烯与异氰酸的反应有抽提氧、插入N-H键、抽提亚氨基的反应路径.采用经Winger校正的Eyring过渡态理论分别计算了1个大气压、不同温度下反应势垒较低通道的热力学及动力学性质,结果表明插入N-H键反应(GeH2+HNCO→IM7→TS6→P2)通道在温度400 K~1400 K内,有较高的平衡常数和反应速率常数,为主反应通道,主产物为GeH3NCO. 相似文献