聚离子液体催化碳酸乙烯酯与甲醇的酯交换反应

通过N-乙烯基咪唑鎓离子液体、 丙烯酸钠(NaAA)和交联剂二乙烯基苯(DVB)或1-乙烯基-3-三乙二醇基咪唑溴盐{[(EG)₃-DVIm]Br₂)}自由基聚合合成了一系列含羧酸根的聚离子液体. 将所合成的聚离子液体用于催化甲醇与碳酸乙烯酯(EC)酯交换反应制备碳酸二甲酯(DMC). 研究结果表明, 在甲醇和EC混合溶剂中具有最大溶胀度的聚离子液体催化剂poly[VOIm-AA-DVIm]活性最高. 在优化反应条件[120 ℃, 6 h, 1.0%(摩尔分数)催化剂用量, n(甲醇)/n(EC)=10∶1]下, DMC收率为76.6%, 选择性为90.1%, 达到了与均相催化剂1-丁基-3-甲基咪唑醋酸盐([BMIm]OAc)相当的活性.     

柏子仁化学成分与药理活性研究进展

柏子仁(arboruitae seed),为柏科植物侧柏Platycladus orientalis(L.) Franco的干燥成熟种仁.在化学成分方面,柏子仁含有脂类、氨基酸、皂苷、萜类和多糖等有效成分,具有镇静安神、抗抑郁、减少小鼠自主活动次数、改善阿尔茨海默病、加强肠推进、治疗不孕症等作用.本文对柏子仁的化学成分、药理活性和临床应用等相关研究进行综述,以指导该药物的开发利用,并为临床合理应用提供可靠的参考.     

用PCA方法模拟光子鉴别

The shower shape of n, n^-, p, p^-, K^＋, π^＋ and photons, generated by JPCIAE code for 5.5 TeV/A ^208pb＋^208pb collisions, incident on the ALICE photon spectrometer （PHOS）, is analyzed with the principal component analysis （PCA） method. The efficiency dependence of purity for the photon discrimination is simulated for the deposited energy ranges 0.5-2 GeV, 2-10 GeV, 10-50 GeV and 50-100 GeV. The result shows that in the energy range of 0.5 to 100 GeV, the efficiency of the photon identification can reach 90% with purity of 90%.     

非线性曝光对三维全息光子晶体禁带特性的影响

从理论和实验两方面研究了非线性曝光对全息方法制作光子晶体的影响.使用低折射率材料（n=152）制作了金刚石结构光子晶体,通过控制曝光量使记录介质工作在非线性曝光区域,发现光子禁带的特性得到了明显的改善.并由此提出了用低折射率材料实现全空间禁带的设想. 关键词： 光子晶体 光学全息 非线性曝光     

Carpet anti-cloak based on transformation optics

We propose a scheme for carpet anti-cloak based on the transformation optics. An anti-cloak layer is designed, which can make the external electromagnetic waves break the carpet cloak shielding. The external electromagnetic waves can be detected under the carpet cloak, while not affecting the role of carpet cloak of stealth. The Jacobian transformation tensor is calculated by numerically solving the Laplace equations with proper boundary condition. Thus, it is possible to design tile anti-cloak layer of irregular shape. The simulation results demonstrate the feasibilities and flexibilities of the structure. Design details and full-wave simulation results are provided.     

CuInS2量子点阻变效应

采用改进的热分解法制备了具有半导体效应的CuInS₂量子点,量子点尺寸均匀、大小为4.2 nm。组装的Au/CuInS₂/FTO阻变存储器件表现出典型的双极性阻变特点,其开态电压为-3.8 V,关态电压为4 V,ON/OFF开关比约为10³。对器件的I-V特性曲线线性拟合发现,器件的阻变机制在高阻态时表现为空间限制电荷（SCLC）传导机制,在低阻态时表现为欧姆传导机制。器件的阻变特性主要是由于电荷被CuInS₂薄膜中的缺陷产生的势阱捕获导致。通过调节陷阱势垒高度引起电荷在陷阱中移动,导致导电通路的产生和断裂,使器件处于高阻态和低阻态。     

Cu12Sb4S13量子点的光照增强阻变性能

采用热注入法制备了粒径为7.9 nm的Cu₁₂Sb₄S₁₃量子点（CAS QDs）,并利用旋涂法在室温下制备了结构为FTO/CAS QDs/Au（其中FTO为导电玻璃）的阻变存储器（RRAM）.在光照条件下,该三明治结构的RRAM呈现典型的双极性阻变开关特征,具有-0.38 V/0.42 V的低工作电压和10⁵的高阻变开关比,并表现出优异的数据保持性和耐久性.在持续工作1.4×10⁶ s和经过10⁴次快速读取后,器件阻变性能变化率小于0.1%.在光照和电场共同作用下,S^2-导电通道的形成与破坏和FTO/CAS QDs界面肖特基势垒高度的调制是FTO/CAS QDs/Au在高阻态与低阻态之间转变的原因.     

SPICE modeling of flux-controlled unipolar memristive devices

Unipolar memristive devices are an important kind of resistive switching devices. However, few circuit models of them have been proposed. In this paper, we propose the SPICE modeling of flux-controlled unipolar memristive devices based on the memristance versus state map. Using our model, the flux thresholds, ON and OFF resistance, and compliance current can easily be set as model parameters. We simulate the model in HSPICE using model parameters abstracted from real devices, and the simulation results show that the proposed model caters to the real device data very well, thus demonstrating that the model is correct. Using the same modeling methodology, the SPICE model of charge-controlled unipolar memristive devices could also be developed. The proposed model could be used to model resistive memory cells, logical gates as well as synapses in artificial neural networks.     

表面修饰磷钼酸铵纳米微粒的合成及摩擦学行为研究

在醇 -水体系中采用同阴离子共沉淀法合成了季铵盐修饰的 (NH4 ) 3 PMo12 O4 0 纳米微粒 ,以TEM、XRD、FTIR、TGA、DSC等多种分析手段表征了这种纳米微粒的形貌和结构 ,在四球试验机上考察了它们的摩擦学性能 .结果表明所合成的杂多化合物具有Keggin骨架结构 ,微粒粒径约 2 0nm ,在有机溶剂中可良好分散 ,作为一类新型润滑油添加剂 ,具有良好的抗磨性能