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Unusual Fragmentation of Peptide and Protein in Matrix-assisted Laser Desorption/lonization Mass Spectrometry

Unusual amine - bond fragmentation on the peptide/protein backbone has been reported using matrix - assisted laser desorption/ionization time - of- flight mass spectrometry (MALDI - TOFMS)The amine - bond cleavage occurred without metastable decay, while the peptide - bond cleavage occurred with metastable decay of peptide ions in a drift region of TOF mass analyzer. It was presumed that the amine - bond cleavage occurred as a non - ergodic process independent of the ionization under MALDI conditions.     

关于2011年CUMCM-D题的一种解法与若干思考

本文系2011年全国大学生数学建模竞赛专科组高教社杯获得者针对本年度竞赛D题的一种解法与若干思考的阐述。首先系统介绍了对此题认识和解题思路,其次提供了一类基于启发式算法求解此问题的参考解法,最后对该问题提出了进一步研究的一个方向。     

《化学通报》网络版(Chemistry Online)2001年4月论文摘要

引用方法 :作者 (多位作者间以逗号隔开 ) .题目 .化学通报 ,年 ,卷 :Ｗ××× (×××为网络版目次中序号的后三位 )[Ｗ 0 1 0 32 ]中性水介质中钙、镁离子对钨酸盐缓蚀机理的影响 Ｃｏｒｒｏｓｉｏｎ ｉｎｈｉｂｉｔｉｏｎＭｅｃｈａｎｉｓｍｏｆＴｕｎｇｓｔａｔｅｉｎＮｅｕｔｒａｌＡｑｕｅｏｕｓＳｏｌｕｔｉｏｎｓ李　燕　　陆　柱 (华东理工大学防腐蚀中心　上海　 2 0 0 2 37)用极化曲线法和Ａｕｇｅｒ能谱研究了中性水介质中Ｃａ2 +、Ｍｇ2 +离子对钨酸盐缓蚀机理的影响。碳钢极化曲线表明 :在含Ｃｌ-和ＷＯ42 -的水中 ,添加Ｃａ…     

Method of array shape calibration based on time delay estimation using two auxiliary sources

As for a flexible horizontal array deployed in the sea, it is difficult to obtain each sensor's precise relative position. Therefore a method of array shape calibration is proposed. The method is described as follows. Firstly two separate auxiliary sources are deployed. Secondly tune delay of each sensor's received signal is estimated. Finally, with the aid of GPS location of the sources and the horizontal array, relative sensor positions of the horizontal array can be determined. The estimation of relative sensor positions is unbiased. Simultaneously, simulation analysis has been done to estimate its standard variance, and the optimal flare angle of the two sources has been derived. Data of 2001 Asian Sea International Experiment have been used to validate the method. After array calibration, measured source azimuth angle agrees with the real one, and measured array gain agrees with the theoretical gain. In conclusion, the theoretical and experimental results both show that the method can determine each sensor's relative position precisely.     

A SUCCESSIVE QUADRATIC PROGRAMMING ALGORITHM FOR SDP RELAXATION OF MAX-BISECTION

A successive quadratic programming algorithm for solving SDP relaxation of Max- Bisection is provided and its convergence result is given.The step-size in the algorithm is obtained by solving n easy quadratic equations without using the linear search technique.The numerical experiments show that this algorithm is rather faster than the interior-point method.