Numerical analysis of edge effect in laminated composite structures

In order to further study free edge effect in composite laminates, a new method is developed. This method is based on the perturbation and modified method of least square. In this paper, we emphatically discuss the solution within the boundary layer region, the socalled inner solution. As an example, we will discuss structures composed of two and four symmetric laminates. Project Supported by the Science Fund of the Chinese Academy of Science.     

S树兰烯( 烯)类似物的合成

本文报导了树兰烯(即钴钯烯)的几个类似物(6a-d和7a-d)的合成, 并讨论了有关这些化合物的形成反应的构象效应。     

An exact analytic method applied to nonhomogeneous ring- and stringer-stiffened cylindrical shells

In this paper, the nonlinear axial symmetric deformation problem of nonhomogeneous ring- and stringer-stiffened shells is first solved by the exact analytic method. An analytic expression of displacements and stress resultants is obtained and its convergence is proved. Displacements and stress resultants converge to exact solution uniformly. Finally, it is only necessary to solve a system of linear algebraic equations with two unknowns. Four numerical examples are given at the end of the paper which indicate that satisfactory results can be obtained by the exact analytic method.     

5-(2,3-二羟丙基)嘧啶的合成及其高碘酸盐氧化

近十年来,呋喃和嘧啶的并合体系之一的呋喃并[2,3-d]嘧啶的合成受到了一定的注意.对其衍生物的肌肉松弛、利尿、抗敏、镇静等作用及抗癌作用曾进行了研究.两个主要的合成途径是由取代4-羟基嘧啶与a-卤代羰基化合物缩合,或从2-氨基呋喃-3-甲腈或酮与胺或甲酰胺环化.     

14N核四极共振自旋系统自旋-晶格弛豫时间的测量

¹⁴N核四极共振自旋系统的自旋-晶格弛豫是一种双指数弛豫。本文介绍了¹⁴N核四极共振自旋系统的自旋-晶格弛豫时间的3种测量方法,利用可变多面体方法对实验数据进行拟合,获得了¹⁴N核四极共振自旋系统的自旋-晶格弛豫时间T_1s和T₁₁,对有关文献中关于核四极共振弛豫时间的测量的3个观点提出了质疑。     

二重高阶对称破缺分歧点和它们的数值确定

本文考虑带Z_××Z₂对称性的两参数非线性的二重高阶对称破缺分歧点。利用对称性,我们提出了相应的正则扩张系统来确定这类分歧点。同时指出存在两条平方音叉式分歧点的道路通过该点。     

分析结构跳跃问题的自适应参数增量迭代方法

通过对Riks切线弧长法和Crisfield圆弧长法的综合及改进,本文提出分析结构跳跃问题的自适应参数增量迭代方法,并建立相应理论基础。最后文中给出中心分布压力作用下圆底扁球壳跳跃问题的数值结果,以验证它的有效性。     

THE QUALOCATION METHOD FOR LINEAR SECOND-ORDER TWO-POINT BOUNDARY-VALUE PROBLEMS

A qualocation method for linear second-order two-point boundary-value problems is developed. The results are extended those in [2]. On the other hand i this method can also be regarded as a discrete, version of the H1-Galerkin method. From this point, our results show that the effect of numerical integration does not decrease the order of convergence.     

软土地区盾构隧道掘进引起的地表沉降预测修订

在盾构隧道施工时, 地表沉降的Peck公式预测结果往往因地质条件的不同而与实测结果差异较大. 为此研究基于宁波轨道交通1号线地表沉降实测数据, 利用最小二乘和一元线性回归法, 确定了盾构隧道地表沉降槽宽度系数K和地层损失率Vl的取值范围, 并引入了地表最大沉降修订系数α和沉降槽宽度修订系数β对Peck公式进行修订. 结果表明: 宁波软土盾构隧道地表沉降槽宽度系数K范围为0.6~0.9, 建议取0.75, 地层损失率Vl范围为1%~3%, 建议取2%; 当修订系数α取1.2, β取0.8时, 能够获得比Peck公式更好的预测效果.     

荧光碳量子点的绿色合成及高灵敏高选择性检测汞离子

本实验以苹果汁为原料,通过一步水热法合成得到了水溶性好及稳定性高的蓝色荧光碳量子点。研究发现Hg2+对碳量子点荧光有良好的猝灭作用,从而建立了一种快速检测Hg2+的新方法。实验发现在pH 7.0磷酸盐缓冲介质中碳量子点荧光猝灭强度与Hg2+浓度在5~100 nmol/L和1~50μmol/L范围内呈线性关系,检出限为2.3 nmol/L(S/N=3)。本方法可用于实际水样中Hg2+的测定。