“第二届全国微全分析系统学术会议”的第二轮通知

“全国微全分析系统学术会议”是为海峡两岸及我国的海外学者提供的微分析系统及相关领域的重要跨学科学术论坛 ,每两年召开一次。本次会议会址设在风景秀丽的杭州西湖畔 ,交流的重点将包括微流控系统中的纳米技术、纳流控分析、单细胞与单分子技术、基因组和蛋白组分析及药物筛选、临床分析中的应用、及微流控系统的大规模集成化等前沿领域。本次会议原定于 2 0 0 4年 4月 2 2日 - 2 4日在杭州市召开 ,报到时间 :4月 2 1日。因中国化学会第 2 4届学术年会安排在2 0 0 4年 4月 2 4— 2 7日在长沙市召开 ,4月 2 3日报到。其中部分时间有冲突…     

46.8MeV的 ~(12)C非弹性散射

在Glauber多重散射理论框架下,使用跃迁密度方法和三种N-N湮没势,计算了46·8MeV的反质子在~(12)C上的非弹性散射微分截面.理论曲线与实验数据符合得较好.     

超导混合态椭球的交流磁化率

本文研究了处于混合态非均匀磁化的高温超导椭球在线性响应区的交流磁化率，给出了不同离心率的非均匀磁化椭球在直流磁场和小交流磁场中的交流磁化率的解析解析阐明了样品几何形状（退磁因子）对交流磁化率的影响文中研究了处于超地椭球的交流磁化率。     

自引力场中非定态二维流体力学方程组的数值解

本艾以林家翘的线性密度波为初值,在自封闭边界的条件下,求得了自引力场中的非定态二维流体力学方程组的数值解.初始为基态5%的扰动密度,在10年的时间内会发展到与基态同量级.这表明,至少在气体盘模拟盘状星系时,星系密度波理论的准稳螺旋结构假设(Qsss 假设)需要作更进一步的考虑.     

ICP-MS测定无公害畜禽饮用水中铅、汞、砷和镉

用ICP-MS测定畜禽饮用水中铅、汞、砷、镉的含量,其最终结果与现行国家标准方法一致。     

Study of new boson W_1~± in the Minimal Higgsless Model at the LHC

The Minimal Higgsless Model predicts the existence of new vector gauge boson W1± . By the process PP → W1± qq → W±Z0qq, Z0 → l+l-, W±→ qq (l=e,μ; q is hadronized to be jets), we study the sensitivity of searching for this possible vector gauge boson in the level of generator events of signal and backgrounds, then give integrated luminosity required to discover 5σ signal as a function of W1± mass. The generator for the signal PP→W1± qq→W±Z0qq at tree level is developed with the Minimal Higgsless Model and th...     

Optimal Capacity Allocation on Heterogeneous Complex Transport Networks

We study how the node delivering capacity is allocated so that the traffic transport efficiency can be enhanced maximally. Network heterogeneity of degree distribution and processing delay of the traffic are considered. An explicit analytical solution is provided, which is based on the M/M/1 queueing theory and optimization principle, provided that the network structure and routing strategy are given. In particular, we extend the relevant conclusions in the literature [Europhys. Lett. 83 （2008） 28001]. Finally, an order parameter simulation example by comparing results with those obtained via simple capacity allocation in large Barabasi—Albert （BA） scale-free network is provided to illustrate the effectiveness of the theoretical results.     

Ratio of a strange quark mass ms to up or down quark mass mu,d predicted by a quark propagator in the framework of the chiral perturbation theory

Based on the fully dressed quark propagator and chiral perturbation theory, we study the ratio of the strange quark mass ms to up or down quark mass mu,d . The ratio is related to the determination of quark masses which are fundamental input parameters of QCD Lagrangian in the Standard Model of particle physics and can not be directly measured since the quark is confined within a hadron. An accurate determination of these QCD free parameters is extremely important for both phenomenological and theoretical applications. We begin with a brief introduction to the non-perturbation QCD theory, and then study the mass ratio in the framework of the chiral perturbation theory (χPT) with a parameterized fully dressed quark propagator which describes confining fully dressed quark propagation and is analytic everywhere in the finite complex p2-plane and has no Lehmann representation so there are no quark production thresholds in any theoretical calculations of observable data. Our prediction for the ratio ms/mu,d is consistent with other model predictions such as Lattice QCD, instanton model, QCD sum rules and the empirical values used widely in the literature. As a by-product of this study, our theoretical results, together with other predictions of physical quantities that used this quark propagator in our previous publications, clearly show that the parameterized form of the fully dressed quark propagator is an applicable and reliable approximation to the solution of the Dyson-Schwinger Equation of quark propagator in the QCD.     

一类[Os(II)(CO)3(tfa)(L)](L=O^O,O^N,N^N)配合物的结构和光谱特征

采用密度泛函理论以及B3LYP方法和单激发组态相互作用(CIS)方法分别优化了一系列[Os(II)(CO)3(tfa)(L)](tfa为三氟乙酸; L=O^O(1), O^N(2), N^N(3), 其中O^O为六氟乙酰丙酮, O^N为羟基喹啉, N^N为3-(三氟甲基)-5-(2-吡啶基)吡唑)配合物的基态和激发态结构. 利用含时密度泛函理论(TD-DFT)结合极化连续溶剂化模型(PCM)计算了配合物在CH2Cl2溶液中的吸收和发射光谱. 研究结果表明, 优化得到的几何结构参数和相应的实验值符合得非常好, 激发态几何构型相对基态变化较小, 这与实验上观察到的较小的斯托克斯频移现象一致. 配合物1-3的最低能吸收分别在342、431和329 nm, 其磷光发射分别在521、638 和488 nm. 配合物1-3的最高占据分子轨道和最低空轨道主要表现为L配体的π和π*轨道特征, 所以它们的最低能吸收归属于π-π*电荷跃迁, 并混有少量的金属到配体的电荷跃迁(MLCT)和配体之间电荷跃迁(LLCT)微扰, 且其高能吸收也表现为配体内部(IL)和配体间(LL)的电荷跃迁. 此外, 它们的磷光发射和吸收有相似的跃迁特征.     

微拟球藻脂肪热解及对全组分制备生物油的影响

以酸水解法从微拟球藻中提取的粗脂肪为原料,在管式裂解炉中考察不同热解温度下脂肪单组分的热解规律及对微拟球藻全组分各相产率及生物油性能的影响。利用热重分析仪分别考察粗脂肪及全组分的热失重特性,并求出相应的动力学参数。结果表明,脂肪热解能够提高全组分热解有机相产率并改善油品性能。随着温度的升高,粗脂肪与全组分热解后的有机相产率及油品性能的变化趋势相同,且生物油性能均在600℃时达到最佳。经热解,粗脂肪中含氧化合物含量降低,脂肪烃含量显著增加。对比全组分热解,粗脂肪热解后的油品脱氧率及氢、碳元素比例更高,因而增加全组分中脂肪的含量能够促进油品性能的进一步提高。对粗脂肪及全组分的热重数据进行计算,发现两者均满足二级化学反应机理,粗脂肪、全组分的活化能与指前因子分别为64.34 k J/mol与2.94×105min-1,48.13 k J/mol与2.96×103min-1。