硫化锌中Sm3+的发光中心

本工作研究了Sm3+离子在立方和六角两种结构硫化锌中的光谱。实验上,采用不同激发条件下的高分辨光谱、时间分辨光谱和激发光谱,同时配合低温退火处理实验,鉴别出硫化锌中Sm3+具有两种不同的发光中心。采用发光方法,第一次对稀土离子在硫化锌中的C3v对称发光中心进行分析。在中间耦合自由离子能级基础上利用不可约张量方法和Wigner-Eckart定理进行晶体场计算,得到的晶体场参数实验值和点电荷模型计算的晶体场参数值相符合。     

中国沉积-改造铅锌矿床

本文主要阐述了我国沉积-改造型层控铅锌矿床的地质特征,铅、硫、氢、氧稳定同位素的组成,改造热液的物理化学性质及其来源,Pb、Zn元素的活化迁移和沉淀的实验研究,矿床的成矿规律等。认为矿床的形成首先是成矿物质与含矿岩系同生沉积,又受后期地质作用影响而被改造及进一步富集成矿。整个成矿过程与岩浆活动没有明显联系。     

近红外光谱结合人工神经网络分析蔗汁的锤度和旋光度

应用中波近红外(NIR)光谱结合误差反传人工神经网络(BP-ANN)方法,建立蔗汁锤度、旋光度的定量分析模型。光谱范围为1 000～1 800 nm,采用2 mm光程透射方式获得蔗汁吸光度光谱。对蔗汁的吸光度光谱进行Savitzky-Golay求导和均值中心化处理,然后通过相关系数法结合样品特征吸收优化建模波长范围,再采用PLS降维获取主成分并输入BP-ANN建立校正模型,用验证样品对校正模型进行验证。结果显示,BP-ANN法建立的锤度和旋光度的预测相关系数(R2)分别为0.982,0.979,预测标准偏差(SEP)分别为0.159和0.137,均优于偏最小二乘(PLS)建模方法结果,可较好地用于蔗汁锤度、旋光度的快速测定。     

南岭花岗岩液态分离实验研究

用黑云母花岗岩加10％NaF和10％LiF作为初始物,在1000bar,840℃条件下实验产生了不混溶,均一的富氟锂花岗岩熔体分离成两种以上的熔体相。据电子探针分析结果至少可分出:一种是富氟铁的硅酸盐熔体,另一种是贫氟的硅酸盐熔体,第三种是氟盐类为主的熔体,结合南岭花岗岩的某些特征进行了讨论,用实验结果,有可能对花岗岩中一些难以解释的球粒结构,矿物中玻璃包体、矿化囊包体、流动构造等地质现象,给予解释。     

BeAl2O4:Cr3+晶体的生长习性

分别沿a,b,c轴三种取向用提拉法生长了BeAl₂O₄:Cr³⁺晶体,用X射线和光学方法测定了各个显露面,确定了其密勒指数,并根据PBC理论计算了各显露面的重要性,计算结果与实验结果相符。 关键词：     

SEDIMENTARY-REFORMED Pb-Zn DEPOSITS IN CHINA

This paper considers the geological characteristics and stable isotopic compositions of sed-imentary-reformed Pb-Zn deposits of China, the physical and chemical properties and sourcesof reformed fluids, and the experimental studies of migration and deposition of Pb and Zn inthem. It is suggested that after ore substances were synchronously deposited with source beds,they were reformed through later geological events, thus making the sedimentary deposits fur-ther enriched. There is no obvious genetic relation between ore formation and magmaticactivity.     

关于有限群的S-半置换子群

Let d be the smallest generator number of a finite p-group P and let Md（P） = {P1,...,Pd} be a set of maximal subgroups of P such that ∩di=1 Pi = Φ（P）. In this paper, we study the structure of a finite group G under the assumption that every member in Md（Gp） is S-semipermutable in G for each prime divisor p of ｜G｜ and a Sylow p-subgroup Gp of G.     

轴流压气机非轴对称机匣造型的研究

首次对一尖部失速型的亚音轴流压气机转子进行了非轴对称机匣造型的设计和研究.本文首先分析了压气机非轴对称机匣造型与已有的非轴对称端壁造型概念的异同点,进而对本文研究的转子给出了非轴对称机匣造型的实例,对流场进行了定常与非定常的数值模拟,着重研究了非轴对称造型机匣对转子整体性能和稳定裕度的影响,对造型面对叶顶流动的改变进行了动态的分析,总结了该类机匣设计的初步经验.通过对同转子上非轴对称机匣造型与实壁机匣,周向槽和轴向槽机匣的对比,可以得出结论:精细设计的非轴对称机匣有效利用了叶顶局部压差,以及造型面的流线化,实现了对叶顶流动的优化,在不损失压气机整体性能的条件下实现了一定程度的扩稳.其应用前景值得关注和深入的研究.     

AN EXPERIMENTAL STUDY ON LIQUID SEGREGATION OF NANLING GRANITES

Based on the characteristics of granites of the Nanling region, a procedure was specially designed to do experiment on the immiscible liquid phase. The starting materials were biotite granite + NnF + LiF. Under 1000 bar and 840℃, more than two immiscible liquid phases were produced from the homogeneous granite melt rich in F and Li. Electron microprobe data suggest that the immiscible liquid phases can be divided into (ⅰ) a silicate melt rich in F and Fe (melanocratic glass balls), (ⅱ) a silicate melt poor in F (matrix glass), and (ⅲ) a melt consisting mainly of fluorates (leucocratic glass balls). In conjunction with the chemical and mineral compositions, the structure and texture of granites in the Nanling region, the experimental results are discussed in this paper. The theory of liquid immiscibility can well account for the globular structure, glass inclusions pressent in minerals mineralized globular "inclusions", flow structure, banded structure and layer structure as are observed in Nanling g