平面光学元件PMD面形检测的调整技术研究

针对相位测量偏折术(PMD)检测平面光学元件面形的光路结构,系统地分析了各部件因各自由度的不确定度变化对重建面形的影响,并且提出了一种高精度的平面元件调整方法。通过对相移算法得到的显示器坐标与通过光线追迹得出的参考面显示器坐标进行比较,能够将被测镜调节至理想测试状态,从而能准确求出被测面上各点斜率,再采用波前重建算法,实现了光学元件面形重建。实验结果显示,有效口径为Ф140mm的平面元件在去掉Zernike多项式前6项的面形数据与干涉仪的测量结果差值在RMS=5nm以内,结果远优于未经过该方法调整的结果。因此,该调整方法可行,能够有效完成对平面元件的精密调整,具有很大的应用价值。     

球状胶束中表面活性剂脱附的离子调控机制

建立耦合伞状采样的粗粒度分子动力学方法,研究球状胶束中表面活性剂分子的脱附过程,揭示表面活性剂聚集数、盐种类及浓度对表面活性剂脱附过程的影响机制。发现球状胶束半径及偏心率均随聚集数增加而增大,盐浓度的影响主要取决于抗衡离子的半径和吸附特性,半径更大、吸附更强的水杨酸根离子对胶束结构的影响更为显著;基于伞状采样方法获得了表面活性剂脱附自由能、脱附时间等关键参数,发现球状胶束中表面活性剂脱附自由能和脱附时间均随聚集数和盐浓度呈非单调变化,揭示其主要机制为离子吸附引起的静电屏蔽作用;发现自由能在表面活性剂脱附过程中起主导作用,结合胶束热力学理论发展了临界胶束浓度预测方法,获得了临界胶束浓度下胶束尺寸的分布范围。     

Multi-scale computation methods: Their applications in lithium-ion battery research and development

Based upon advances in theoretical algorithms, modeling and simulations, and computer technologies, the rational design of materials, cells, devices, and packs in the field of lithium-ion batteries is being realized incrementally and will at some point trigger a paradigm revolution by combining calculations and experiments linked by a big shared database,enabling accelerated development of the whole industrial chain. Theory and multi-scale modeling and simulation, as supplements to experimental efforts, can help greatly to close some of the current experimental and technological gaps,as well as predict path-independent properties and help to fundamentally understand path-independent performance in multiple spatial and temporal scales.     

基于SOA的宁波地铁信息系统架构设计

为有效改善宁波地铁企业信息系统中各个信息系统间信息的有效互通、数据共享、统一管理等问题, 结合宁波市轨道交通的规划、建设、运营和开发“四位一体”战略, 设计了面向智慧地铁的信息系统架构, 整个架构的内容包括基础设施、基础平台、一体化的信息系统平台、信息门户及网站、微信、移动APP等公众服务平台, 并设计配置了信息化管理体系, 进而实现异构、分散的应用系统之间的有效集成, 提升信息化系统资源协同工作和业务管理的效率.     

First principle study of LiXS_2(X=Ga,In) as cathode materials for Li ion batteries

From first principle calculations, we demonstrate that LiXS_2(X = Ga, In) compounds have potential applications as cathode materials for Li ion batteries. It is shown that Li can be extracted from the LiXS_2 lattice with relatively small volume change and the XS_4 tetrahedron structure framework remains stable upon delithiation. The theoretical capacity and average intercalation potential of the LiGaS_2(LiInS_2) cathode are 190.4(144._2) m Ah/g and 3.50 V(3.53 V). The electronic structures of the LiXS_2 are insulating with band gaps of _2.88 eV and 1.99 eV for X = Ga and In, respectively.However, Li vacancies, which are formed through delithiation, change the electronic structure substantially from insulating to metallic structure, indicating that the electrical conductivities of the LiXS_2 compounds should be good during cycling.Li ion migration energy barriers are also calculated, and the results show that Li ion diffusions in the LiXS_2 compounds can be as good as those in the currently widely used electrode materials.     

循证护理在慢性宫颈炎合并HPV感染患者治疗指导中的应用

目的探究循证护理在慢性宫颈炎合并HPV感染患者治疗指导中的应用。方法对63例慢性宫颈炎合并HPV感染患者,经循证护理,分别于6个月和12个月追踪HPV清除率。结果 63例经循证护理的慢性宫颈炎合并HPV感染患者,6个月后和12个月后的HPV清除率分别为41.3%(26/63)和58.7%(37/63);42例对照组6个月后和12个月后的HPV清除率分别为28.6%(12/42)和58.7%(17/42)。结论对慢性宫颈炎合并HPV感染患者进行循证护理,缩短了宫颈炎治愈时间并提高HPV清除率。     

碳点-荧光素荧光共振能量转移体系在阿司匹林测定中的研究与应用

研究了经L-y半胱氨酸修饰后的碳点(CDs)-荧光素(FAM)荧光共振能量转移体系,并利用该体系建立了测定阿司匹林(ASP)的新方法。结果表明:在λex=330 nm下,于p H 7.0的Tris-HCl缓冲液中,CDs与FAM反应5 min后能发生有效的荧光共振能量转移,能量供体CDs将能量转移到受体FAM,使FAM的荧光显著增强,而ASP的加入可有效猝灭FAM的荧光,且ASP浓度在1.0~150.0μg/m L范围内与体系的荧光猝灭值ΔIF呈良好的线性关系(r=0.999 6),基于此建立了测定ASP的新方法。在最佳实验条件下,方法的检出限达0.33μg/m L(3δ/k,n=11),回收率为97.1%~105.3%,相对标准偏差(RSD)不大于4.6%(n=6)。常见的无机离子以及与ASP同类型的药物对测定影响较小,方法的选择性较好。     

Radiation Induced Optical Absorption of Cubic Lead Fluoride Crystals and the Effect of Annealing

Transparent and colorless lead fluoride crystals with sizes of 20 × 20 × 20 （ram3） are irradiated with several doses of γ-rays from a ^60Co source. Their transmittance spectra before and after irradiation are measured, and a new parameter ΔT = Tb - Ta is defined to evaluate the irradiation damage. Three optical absorption bands peaking at 27Onto, 37Onto and 50Onto are found in the plots of AT versus wavelength, and their intensities increase with the irradiation dose. These optical absorption bands, except the one at 27Onto, can recover spontaneously with time. Thermal annealing treatment can enhance this recovery of the transmittance, while the optimum annealing temperature for different samples depends on the irradiation dose.     

应力对硅烯上锂吸附的影响

本文采用基于密度泛函理论的第一性原理平面波赝势方法研究了双轴应力作用下锂原子吸附硅烯的结构及其稳定性. 计算结果表明,在拉应力和一定的压应力作用下,锂吸附的硅烯体系基本保持原有的结构. 而当更大的压应力作用时,硅烯产生了向锂原子方向凸起的结构变化,所得到的体系的总能也有明显地下降. 本文通过对各种应力下的硅烯声子谱的计算,分析了在压应力作用下锂吸附的硅烯结构不稳定的原因. 关键词： 硅烯 应力 第一性原理 声子谱     

红宝石Cr~(3+)∶Al_2O_3的电子云延伸效应及压力对电子云延伸效应影响(英文)

本文以 Cr3 +自由离子的 3 d电子径向波函数为基础 ,对 Cr3 +∶Al2 O3 中的电子云延伸效应进行了理论研究 ,引入了电子云延伸效应系数 κ,得到了 Cr3 +∶Al2 O3 中 Cr3 +离子的最优化 3 d电子径向波函数 .并研究了压力对电子云延伸效应系数κ的影响