HCFC22/HFC152aPVTx性质实验研究

引言 HCFC22/HFC152a是近年越来越受到重视的一种近共沸混合工质。采用该混合工质作为制冷剂以替代现用的CFC12具有许多优点:首先从保护臭氧层、减少温室效应的角度看,这种混合物对大气臭氧层破坏势(ODP值)和温室效应(GHP值)均比较小;第二,在HFC152a中加入适量的HCFC22可以达到对HFC152a可燃性的抑制作     

First-Principles Calculation of Static Equation of State and Elastic Constants for GaSe

The all-electron full potential augmented plane-wave plus local orbital （APW_Io） method with the local-density approximation （LDA） is used to calculate the static equation of state （EOS） and elastic constants of crystalline GaSe. After the full relaxation of atomic positions, the calculated band structure at ambient pressure is consistent with the experimental data to the extent expected to give the known limits of LDA one-electron energies. The equilibrium lattice parameters found here exhibit the usual LDA-induced contraction. However, constrained with the experimental cell volume, the interlayer separation exhibits an expansion due to the LDA underestimate of the weak interlayer bonding. The calculated values of elastic constants are in good agreement with acoustic measurements. The pressure derivatives of the lattice constants derived from the theoretical elastic constants are in very good agreement with x-ray spectra measurements. Two analytical EOSs have been determined at pressures up to 4.5 GPa. The pressure evolution of the structure indicates that the layer thickness decreases slightly under pressure.     

用TDMA法计算谐振子在强激光脉冲下的高次谐波

用含时薛定谔方程的多态展开(TDMA)方法求解含时薛定谔方程.该方法将含时波函数以基函数展开,通过求解展开系数的一阶微分方程组得到任意时刻的波函数.并将这一方法用于强激光场中谐振子的高次谐波的计算,以HCl分子为例,计算了在脉冲激光作用下高次谐波的产生和对应的激光强度、波长和脉冲宽度.     

94K低温下和室温下GaN基MSM紫外光探测器性能的比较

在采用MOCVD技术生长的GaN膜上制备出MSM紫外光探测器，分别在室温下和94K低温下，测量了探测器对不同光波长的响应、同一光波长下对不同偏压的响应、不同斩波频率下的响应。结果表明，在94K下响应有了很大的改善。当光波长从360nm增加到450nm时，响应下降了3个数量级，而常温下只下降两个数量级，但探测器的时间响应常数变长了。     

二苯并18-冠-6配合物[NH4(DB18-C-6)]2[Pd(SCN)4]的合成与结构分析

研究了二苯并18-冠-6(DB18-C-6)与(NH4)2[Pd(SCN)4]的反应,通过元素分析、红外光谱、单晶X射线衍射对生成的配合物[NH4(DB18-C-6)]2[Pd(SCN)4](1)进行了结构分析.1为三斜晶系,空间群P-1,晶体学数据:a=0.8705(3)nm,b=1.1954(4)nm,c=1.3044(4)nm,α=73.216(5)°,β=78.897(5)°,γ=81.105(6)°,V=1.2682(7)nm3,Z=1,F(000)=568,R1=0.0301,wR2=0.0431.配合物由二个[NH4(DB18-C-6)]+配阳离子和一个[Pd(SCN)4]2-配阴离子组成,二者通过N-H…N氢键形成中性配合物,配合物中不存在阳离子-π相互作用.     

Torus上一般复结构的Virasoro代数

我们讨论了torus上一般度规下,复结构的形式和相应的能量动量张量T(z),T(z);并在τ度规下,解torus上的玻色弦及其鬼的运动方程,得到了弦场和鬼场通解形式;最后我们给出了torus上一般复结构的Virasoro代数,并证明了不同复结构上的Virasoro代数相同.     

Isotope Dependence of Superheavy Nucleus Formation Cross Section

The dynamical process in the superheavy nucleus synthesis is studied on the basis of the two-dimensional Smoluchowski equation. Special attention is paid to the isotope dependence of the cross section for the superheavy nucleus formation by means of making a comparison among the reaction systems of ^54Re＋204pb, ^56Re ＋206Pb, and ^58Fe＋^208Pb. It is found by this comparison that the formation cross section is very sensitive to the conditional saddle-point height and the neutron separation energy of the compound nucleus. Reaction systems with lower height of conditional saddle-point and smaller neutron separation energy are more favourable for the synthesis of the superheavy nucleus.     

低压铸造充型动力学的高速摄影观察

利用高速摄影和影片运动分析技术,在透明模型上对低压铸造充型过程进行了实时观察和运动分析。结果表明:低压铸造充型的动力学特征可用二阶非线性微分方程描述。     

部分填充手征等离子体波导的电磁波

 把麦克斯韦方程和电磁场分解成横向和纵向分量, 导出了简明的一般性的手征等离子体填充的任意截面波导的波动方程和横向纵向场的关系式。对于部分填充手征等离子体波导, 导出了它的色散方程。这一方程的数值解给出了HE₁₁, EH₀₁和HE₂₁模式的色散图。随着手征等离子体填充面积的增大, EH₀₁模式的色散曲线向更高的频率移动。随着手征导纳的增加, 传播常数减小。