界面生长中断对GaAs (111)衬底上AlGaAs/GaAs量子阱电子自旋寿命的影响

用固源分子束外延技术(SSMBE)在GaAs(111)衬底上,采用不同的界面中断时间生长了多组AlGaAs/GaAs多量子阱样品(MQWs),通过室温发光光谱和时间分辨克尔旋转谱(TRKR)研究了界面生长中断对发光光谱半峰全宽(FWHM)和量子阱中电子自旋弛豫时间(自旋寿命)的影响,发现了自旋寿命随着界面生长中断时间的增加呈现先减小后增加的趋势,此变化趋势与荧光光谱半峰全宽表征的材料质量随中断时间的变化一致,适当的界面生长中断时间能有效的增加GaAs (111)衬底上AlGaAs/GaAs 多量子阱中电子自旋寿命。     

Chirality-asymmetry force between ɑ-quartz and copper block

The chirality-asymmetry macroscopic force mediated by light pseudoscalar particles between α -quartz and some achiral matter is studied. If this force between achiral source mass and α -quartz with some chirality is attractive, it will become repulsive when the chirality of the α -quartz crystal is changed. According to the tested limits of the coupling constant g_s g_p /\hbar c< 1.5× 10^-24 at the Compton wavelength λ = 10^-3 m, the force (F) between a 0.08× 0.08× 0.002 m³ block of α -quartz and a 0.08× 0.08× 0.01 m³ copper block with a separation being 0.5× 10^-3 \mbox{m} in between, is estimated from the published data at less than 4.64× 10^-24 N, i.e. F < 4.64× 10^-24 N.     

一般矩阵函数的变差

设Sn是n次对称群,G为Sn的子群,χ是G的次数为1的特征标.如果A是一个n阶复变矩阵,定义一般矩阵函数dχG为dχG(A)=∑σ∈Gχ(σ)∏ni=1aiσ(i).本文用lp-算子范数(1≤p≤∞)的性质证明了一般矩阵函数变差的两个不等式.     

石英粉/磷酸盐缓冲溶液体系中羟自由基荧光分光光度法定量检测研究

为了定量检测石英粉/磷酸盐缓冲溶液体系中极低浓度的羟自由基(·OH),依据对苯二甲酸(TA)在pH中性的缓冲溶液中与羟自由基反应生成唯一稳定且具有很强荧光特性的产物即2-羟基对苯二甲酸(HOTP),本文建立了滤液最大激发/发射波长EX_max/EM_max=316 nm/422 nm处的荧光强度与HOTP浓度关系的标准曲线,通过检测石英粉与缓冲溶液作用之后滤液的荧光强度,从而间接测定了体系产生的·OH累积浓度。通过重复试验并分析五个不同实验条件下体系产生的·OH累积浓度,最小检出限达到1.59×10-10 mol·L-1,相对偏差为1.20%~7.89%,标准偏差为1.09×10-9~2.17×10-9 mol·L-1,相对标准偏差为3.5%~5.8%,说明该方法具有较高的精确度和较好的重复性。该方法可用于定量检测pH中性溶液中极低浓度的·OH,与其他方法相比,具有明显的检测限低、成本低、灵敏度高、稳定性和重现性好等优势。     

吡罗红为底物的辣根过氧化物酶催化荧光反应测定葡萄糖

吡罗红在辣根过氧化物酶催化下可被过氧化氢氧化而使其荧光猝灭。在pH 7.2中性介质中,稳态催化速率由酶和底物浓度决定,催化体系服从Michaelis-Menten方程,用Lineweaver-Burk作图法求得米氏常数、最大反应速度、催化常数分别为2.4×10~(-5)mol·L-1,2.5×10~(-6)mol·L-1s-1,75.8 s-1。在最佳反应条件下,荧光F0/F的猝灭程度与过氧化氢浓度在0-3.6×10~(-7)mol·L-1范围内成线性关系,检测限为6.3×10~(-9)mol·L-1;当与葡萄糖氧化酶联用时,可定量检测葡萄糖,线性关系为0-8.0×10~(-7)mol·L-1,检测限为3.4×10~(-8)mol·L-1。方法用于分析人血清中葡萄糖含量,分析结果与苯酚-4-氨基安替比林法基本一致。     

平面交叉玻璃波导型微透镜阵列光学性能研究

介绍了平面交叉玻璃光波导型半球形微透镜阵列的制作方法.利用积分形式的光线方程式讨论了半球形微透镜的光学特性,得到了半球形微透镜的光线轨迹方程式和焦距表示式,理论结果与实验数据是一致的.     

GROWTH MODE OF Cu-RICH PARTICLES ON LASER-ABLATED YBa2Cu3O7 THIN FILMS

The microstructure of the laser-ablated YBa₂Cu₃O₇ (YBCO) thin film deposited on heated (100) SrTiO₃ substrate was examined by transmission electron microscope. The par-ticles on the film mainly consist of CuO and few CuYO₂. Most of these non-superconducting particles nucleate on or near the surface of the film and protrude about 100-400 nm in height, A large amount of a-axis YBCO grains also exist in the film, which nucleate at the substrate surface and grow perpendicularly above the c-axis YBCO film. The YBCO thin film deposited under low oxygen pressure has very different microstructure compared with YBCO thin film deposited under high oxygen pressure.     

衍射相关和Lau干涉

本文用离轴傅里叶变换系统的模型和菲涅耳衍射理论分析了衍射受限下的离焦相关器的系统特性,证明是第一模板和第二模板衍射像之间的强度相关积分。推导了衍射相关器作为测量相位物体的干涉仪的一般理论,这时要求编码板函数能衍射自成像并且相关函数为周期性函数。讨论了平行光栅作为编码板时的干涉仪的横向剪切干涉特性,给出了实验结果。本文还证明了衍射相关器是推广到任何平面物体在任何观察距离上的Lau效应装置。衍射相关干涉仪产生Lau干涉条纹,并且是直接应用Lau效应的干涉仪。 关键词：     

白光发光二级管用红色荧光粉LiSrBO3: Eu3+的制备与发光性能研究

采用高温固相法制备了LiSrBO₃:xEu³⁺ 荧光粉, 并通过XRD, 红外(FITR) 和荧光光谱(PL) 等对其表征. 结果表明, LiSrBO₃: Eu³⁺ 荧光粉可被波长为395 nm 的紫外线和466 nm 的蓝光有效激发, 且发射主波长为612 nm (Eu³⁺的电偶极跃迁⁵D₀ →⁷F₂) 的红光. 研究了Eu³⁺ 掺杂浓度对LiSrBO₃: Eu³⁺ 材料发光强度的影响, Eu³⁺ 掺杂浓度为6% 时样品的发射强度最大, 并且证实Eu³⁺ 之间的能量传递机制为电偶极子- 电偶极子相互作用. Li⁺, Na⁺, K⁺ 作为电荷补偿剂的引入全部导致LiSrBO₃: Eu³⁺ 材料发射强度增强, 其中, Li⁺ 的引入要优于Na⁺ 和K⁺. 少量Al³⁺的掺杂降低了Eu³⁺ 所处格位的对称性, 增强了Eu³⁺ 的612 nm 的电偶极发射, 改善了LiSrBO₃: Eu³⁺ 红色材料的色纯度. 关键词： 白光发光二级管 光致发光 浓度猝灭 电荷补偿剂     

Improving attosecond pulse reflection by large angle incidence for a periodic multilayer mirror in the extreme ultraviolet region

The improvement of attosecond pulse reflection by large angle incidence for a periodic multilayer mirror in the extreme ultraviolet region has been discussed. Numerical simulations of both spectral and temporal reflection characteristics of periodic multilayer mirrors under various incident angles have been analyzed and compared. It was found that the periodic multilayer mirror under a larger incidence angle can provide not only higher integrated reflectivity but also a broader reflection band with negligible dispersion, making it possible to obtain better a reflected pulse that has a higher pulse reflection efficiency and shorter pulse duration for attosecond pulse reflection. In addition, by increasing the incident angle, the promotion of attosecond pulse reflection capability has been proven for periodic multilayer mirrors with arbitrary layers.