Structure of Cytochromec and Its Platinum-modified Derivatives by Fourier Transform Infrared Spectroscopy

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[Cr(III)(SSA)(en)2]•2H2O配合物的合成、表征及性质研究

有机铬(III)配合物具有较高的生物利用率. 本文合成了一种新型磺基水杨酸铬(III)混配配合物[Cr(SSA)(en)₂]•2H₂O (SSA＝5-磺基水杨酸, en＝乙二胺), 通过红外、紫外、荧光光谱以及元素分析、电导率测定和X晶体衍射等方法对其结构进行了表征. 在pH 7.4, 0.05 mol•L^－1 Tris-HCl缓冲液中, 利用荧光光谱研究了配合物与人血清白蛋白的结合. 结果表明配合物可与人血清白蛋白以较强的分子间作用力结合, 条件结合常数为(2.7±0.1)×10⁴ mol•L^－1, 结合位点数为3.87. 在pH 7.4, 0.05 mol•L^－1 Tris-HCl缓冲液中, 观察了不同温度下EDTA和脱铁伴清蛋白为竞争剂的配体取代反应动力学行为, 其中37 ℃时反应速率常数分别为0.0142和0.0225 h^－1.     

Integration of GaN thin films with silicon substrates by fusion bonding and laser lift-off

GaN thin films grown on sapphire substrates by metalorganic chemical vapor deposition (MOCVD) are successfully bonded and transferred onto Si receptor substrates using fusion bonding and laser lift-off (LLO) technique. GaN/Al_2O_3 structures are joined to Si substrates by pressure bonding Ti/Au coated GaN surface onto Ti/Au coated Si receptor substrates at the temperature of 400℃. KrF excimer laser with 400-mJ/cm~2 energy density, 248-nm wavelength, and 30-ns pulse width is used to irradiate the wafer through the transparent sapphire substrates and separate GaN films from sapphire. Cross-section scanning electron microscopy (SEM) combined with energy dispersive X-ray spectrometer (EDS) measurements show that Au/Si solid solution is formed during bonding process. Atomic force microscopy (AFM) and photoluminescence (PL) measurements show that the qualities of GaN films on Si substrates degrade little after substrates transfer.     

适用于量子阱激光器的速率方程

首次在理论上用量子阱激光器增益与载流子密度的对数关系替代了原有速率方程中的线性关系，得到了改进了速率方程，分析了稳态和调制特性，从理论上得到了获得最低阈值的最佳阱数和最大调制带宽的最佳腔长。     

Synthesis and Crystal Structure of the Heteropolymate Compound Na_3H_2[Ce_3(H_2O)_(18)Bi_2W_(22)O_(76)]·23H_2O

1 INTRODUCTION As a rich remarkable class of inorganic cluster systems, polyoxometalates continue to be the focus of significant attention in the 21th century because of their various and alluring topologies as well as their unusual physicochemical prope…     

CAD／CAM技术在模具中的应用

本文介绍了模具行为中应用ＣＡＤ／ＣＡＭ技术的特点、优越性以及典型模具ＣＡＤ／ＣＡＭ软件系统的功能结构，以期推广模具ＣＡＤ／ＣＡＭ技术在我院民品的应用。     

光镊捕获金福菇孢子的拉曼光谱分析

使用光镊拉曼光谱系统俘获悬浮在生理盐水中的单个金福菇孢子,激发并收集其拉曼信号,结果显示单个金福菇孢子的拉曼光谱基本能呈现其内含物的组成和结构信息,脂类物质是其主要成分。同种栽培方式的3个不同菌株单个金福菇孢子的平均拉曼光谱信号基本一致,分别对其进行多元统计分析(PCA),无法区分其拉曼光谱信号;同一菌株不同栽培方式的单个孢子平均拉曼光谱的差异光谱表明其主要成分相同,都以脂类物质为主;而源自于脂类1743、1655、1442、1125、1080、1070、876、728cm-1等峰的信号强度基本一致,说明其脂类的含量基本相同。从单细胞拉曼光谱角度初步分析金福菇孢子,为光镊拉曼光谱技术研究食用菌孢子萌发机理提供有意义的参考。     

Fewest switches adiabatic surface hopping as applied to vibrational energy relaxation

In this contribution quantum/classical surface hopping methodology is applied to vibrational energy relaxation of a quantum oscillator in a classical heat bath. The model of a linearly damped (harmonic) oscillator is chosen which can be mapped onto the Brownian motion (Caldeira-Leggett) Hamiltonian. In the simulations Tully's fewest switches surface hopping scheme is adopted with inclusion of dephasing in the adiabatic basis using a simple decoherence algorithm. The results are compared to the predictions of a Redfield-type quantum master equation modeling using the classical heat bath force correlation function as input. Thereby a link is established between both types of quantum/classical approaches. Viewed from the latter perspective, surface hopping with dephasing may be interpreted as "on-the-fly" stochastic realization of a quantum/classical Pauli master equation.     

基于图像处理的变压器呼吸器自动检测

传统的变压器呼吸器缺少检测手段,无法实现远程监测,必须通过运行工作人员定期巡视确定其状态.本文介绍了一种基于图像处理的变压器呼吸器自动检测方法,借助于智能巡检机器人现场拍摄并传回的变压器呼吸器装置图像,利用数字图像处理技术对该图片进行颜色直方图统计分析,并进行决策判断是否需要更换变色硅胶.这种检测方法不仅对变压器呼吸器的构造没有任何要求,同时也不需要任何传感器装置,因此大大降低了变压器呼吸器的检测成本,既方便又实用.     

金属磁记忆效应的第一性原理计算与实验研究

为研究铁磁材料应力集中区域金属磁记忆信号的产生机理及其变化规律, 采用基于密度泛函理论的第一性原理平面波赝势法, 建立了磁记忆效应的磁力学模型; 计算分析了力与磁记忆自发漏磁信号的定量变化关系. 研究结果表明:力作用导致晶格畸变是磁记忆自发漏磁信号产生的根本原因; 常温下, 磁记忆信号随应力近似线性变化的规律与X70钢管水压爆破实验结果具有很好的一致性. 研究结果有助于金属磁记忆检测机理的研究. 关键词： 金属磁记忆 第一性原理 漏磁信号