Experimental investigation about the effect of non-axisymmetric wake impact on a low speed axial compressor

Non-axisymmetric wake impact experiments were carried out after the best exciting frequency for a low speed axial compressor had been found by axisymmetric wake impact experiments. When the number and circumferential distribution of inlet guide vanes （IGV） are logical, the wakes of non-axisymmetric IGVs can exert beneficial unsteady exciting effect on their downstream rotor flow fields and improve the compressor＇s performance. In the present paper, four non-axisymmetric wake impact plans were found working better than the axisymmetric wake impact plan. Compared with the base plan, the best non-axisymmetric plan increased the compressor＇s peak efficiency, and the total pressure rise by 1.1 and 2%, and enhanced the stall margin by 4.4%. The main reason why non-axisymmetric plans worked better than the axisymmetric plan was explained as the change of the unsteady exciting signal arising from IGV wakes. Besides the high-frequency components, the nonaxisymmetric plan generated a beneficial low-frequency square-wave exciting signal and other secondary frequency components. Compared with the axisymmetric plan, multifrequency exciting wakes arising from the non-axisymmetric plans are easier to get coupling relation with complex vortices such as clearance vortices, passage vortices and shedding vortices.     

用动力学Lie代数方法研究H2在Ni(100)面离解吸附量子动力学

用动力学Lie代数方法处理H2 在一个光滑金属表面上离解吸附量子动力学 .用一个修正LEPS势能面描述H2 与Ni( 1 0 0 )表面相互作用 ,得到了H2 初态确定的离解几率的初始动能和时间依赖的解析表示 ,并与实验和其他理论计算做了比较 .这个方法能有效地用于描述表面反应散射动力学 .     

在吡啶溶液中细菌叶绿素a分子S3-S1转换过程的实时观测

采用飞秒荧光亏蚀技术研究细菌叶绿素a在吡啶溶液中的内转换过程 .我们用 40 0和 80 0nm飞秒光作为泵浦与探测光 .该研究给出了细菌叶绿素a分子的S3 S1转换过程的实时观测 ,同时观测到随后的两个弛豫过程 .细菌叶绿素a在吡啶溶液中的内转换时间为 2 2 6fs .     

Rapid internal conversion in a symmetric molecule LD 700 studied by means of femtosecond fluorescence depletion

The rapid internal conversion dynamics at room temperature is determined by using the femtosecond time-resolved fluorescence depletion measurements of a complex solvated molecule of LD 700 (rhodamine 700) combined with steady-state absorption and fluorescence spectroscopy, as well as quantum chemical calculation. The molecule is excited by a 50fs laser pulse at 400nm which directly populated the highly excited singlet state, the rapid internal conversions (ICs) are observed, which leads to the directional changes of the emission transition moment following photoexcitation to the highly excited singlet state S₅ of LD 700.