Polythiophene-block-poly(phenyl isocyanide) copolymers: One-pot synthesis,properties and applications

Conjugated block copolymers have gained increasing interests in recent years. Development of a novel method for facile synthesis of conjugated block copolymers with desired structures and functions is greatly desired. In this mini review, we summarized the recent advances in one-pot synthesis of conjugated block copolymers containing π-conjugated polythiophene and helical polyisocyanide segments by using a nickel(Ⅱ) complex as single catalyst. The sequential living polymerization of the two monomers proceeded in a controlled manner, affording expected block copolymers in high yields with controlled molecular weights(Mns) and narrow molecular weight distributions(Mw/Mns). By using this method, a family of block copolymers with expected structure and tunable compositions can be facilely prepared. Introducing functional groups onto the pendant, these block copolymers can exhibit interesting self-assembly property, tunable light emission and multi-responsiveness.     

蒸汽辅助溶液过程制备钙钛矿材料及钙钛矿太阳能电池

有机无机杂化钙钛矿材料被广泛应用于光电器件领域,特别是其作为太阳能电池的吸光材料,受到学术界和工业界越来越多的关注。钙钛矿太阳能电池的产业化进程正在进行中,而在进一步降低制备成本、提高电池转换效率的同时,研究出一种操作简单且可重复性高的制备钙钛矿薄膜的技术具有十分重要的意义。与其他传统的溶液处理方法不同,蒸汽辅助溶液过程(VASP)处理法避免了薄膜在生长过程中溶解以及溶剂化作用,抑制了晶核的形成,使薄膜快速重组,获得致密的高质量钙钛矿薄膜。目前报道,基于此薄膜制备的平面结构钙钛矿太阳能电池转换效率高达16.8%。本文综述了低温(150℃)VASP法制备的钙钛矿薄膜及光伏器件的相关研究进展,并对该技术的产业化前景做了展望。VASP制备过程简单、薄膜性能优异且可重复性高,为进一步制备大面积、高质量薄膜提供了可能。     

Influence of quark energy loss on extracting nuclear sea quark distribution from nuclear Drell-Yan experimental data

By means of two typical kinds of quark energy loss parametrization and the nuclear parton distributions determined only with lepton-nuclear deep inelastic scattering experimental data, a leading order analysis is performed on the proton-induced Drell-Yan differential cross section ratios of tungsten versus deuterium as a function of the quark momentum fraction in the beam proton and target nuclei. It is found that the theoretical results with quark energy loss are in good agreement with the experimental data. The quark energy loss effect produces approximately 3% to 11% suppression on the Drell-Yan differential cross section ratios R_W/D in the range 0.05≤x₂≤0.3. The application of nuclear Drell-Yan data with heavy targets is remarkably subject to difficulty in the constraint of the nuclear sea quark distribution.     

The chaotification of discrete Hopfield neural networks via impulsive control

The chaotification of discrete Hopfield neural networks is studied with impulsive control techniques. No matter whether the original systems are stable or not, chaotilication theorems for discrete Hopfield neural networks are derived, respectively. Finally, the effectiveness of the theoretical results is illustrated by some numerical examples.     

一种提高基于循环频移器的多载波光源光信噪比的方案

频率锁定多载波光源是实现太比特系统传输的关键器件之一, 目前已成为光纤通信领域的研究热点.基于循环频移技术产生的频率锁定 多载波光源因具有驱动电压低、串扰小、平坦度高的优点而受到重视, 但是其输出质量容易受到调制器固有的高阶谐波串扰的影响,特别是三阶谐波串扰. 为了减小三阶串扰的影响,本文提出了在I/Q调制器两支路上再加载另一频率为3f_m的射频信号的方案, 用其产生的一阶信号来抑制三阶串扰.通过理论分析与数值仿真,得到了载波数为24、 载波间最大功率差小于0.1 dB的多载波光源输出.与未采用三阶串扰抑制方案的结果比较, 光源输出有效光信噪比提高了2 dB. 结果表明,采用本文的改进方案,可以有效地提高多载波光源的输出平坦度和有效光信噪比.     

聚噻吩-b-聚喹喔啉共轭嵌段聚合物对Co~(2+)离子的高选择性可视化检测

探讨了聚(3-己基噻吩)-b-聚(2,3-喹喔啉)(P3HT-b-PQD)共轭嵌段聚合物对二价钴离子的高选择性可视化检测.该类结构明确的嵌段共聚物以Ni(dppp)Cl2为引发剂,通过顺序投料的一锅法活性配位聚合方法合成,其四氢呋喃溶液呈黄色,在365 nm的紫外光照射下发出橙黄色的荧光.该类嵌段聚合物可以实现对二价钴离子的可视化检测,加入二价钴离子后,其四氢呋喃溶液的颜色由黄色变为亮绿色.检测具有非常高的选择性,加入其它的金属离子不能产生溶液颜色的任何变化.此外,加入二价钴离子后,其四氢呋喃稀溶液在紫外下的发射光由橙黄色变为深绿色.其对于二价钴离子的检测限可达10-7mol/L.竞争实验表明,其它金属离子对于钴离子的识别不具有任何干扰.