激光动态测量技术的研究

本文报导应用激光扫描，在Φ５ｍｍ至由６０ｍｍ的外径上，实现±０．０２ｍｍ动态测量精度的研究结果。文中对研究原理及精度分析作出简明阐述。     

由酸效应系数计算pH值的新方法

基于酸效应系数αL(H)与溶液酸度的关系,建立了一种由αL(H)手工计算pH值的新方法.该方法无需解高次方程,仅需对lgαL(H)及相关pKa作加减运算、复杂体系也只需增加少量以10为底的乘方运算及常用对数运算即可.因而方法简便,计算误差可预先设置,本文控制不超过5%.     

Synthesis and Crystal Structur of (4,4′-H_2bipy)[CdBr_4]·H_2O

The title compound (4,4′-H2bipy)[CdBr4]·H2O 1 has been synthesized via hydrothermal reaction and characterized by X-ray diffraction. The crystal belongs to monoclinic,space group P21/c with a=8.260(3),b=23.926(7),c=9.774(2),β=106.777(9)o,C10H12Br4CdN2O,Mr=608.26,V=1849.4(9)3,Z=4,Dc=2.185 g/cm3,S=1.005,μ(MoKα) =9.814 mm–1,F(000)=1128,R=0.0646 and wR=0.0989. The crystal structure analysis of 1 reveals that the title compound features an isolated structure,based on discrete 4,4′-H2bipy moieties and lattice water molecules which are linked by hydrogen bonds together with tetra-hedral cadmium atoms terminally coordinated by four bromine atoms.     

阻尼板振动方程的紧致差分方法

<正>1引言考虑如下阻尼板振动方程初边值问题■其中?=(0, a)×(0, b)?R², T是时间总量,■μ(μ> 0)为阻尼系数,ρ为给定正常数, f (x, y, t)是已知函数,φ₁(x, y)和φ₂(x, y)是初值函数,ψ₁(y, t),ψ₂(y, t),ψ₃(x, t),ψ₄(x, t)和g₁(y, t), g₂(y, t), g₃(x, t), g₄(x, t)是边值函数.     

推导台体体积公式有新法

立几教材中推导台体体积公式的方法不是唯一的 ,因为用体积的割法可求出三棱台的体积 ,因此任意台体体积即可获解 .题 1　已知棱台Ａ′Ｂ′Ｃ′ ＡＢＣ中 ,设Ｓ△Ａ′Ｂ′Ｃ′=图 1　方法 1图Ｓ1 ,Ｓ△ＡＢＣ =Ｓ2 ,高为ｈ .试推导三棱台的体积公式 .解　 [方法 1]如图 1,连结ＡＣ′ ,ＡＢ′ ,ＣＢ′ .Ｖ台 =ＶＡ Ａ′Ｂ′Ｃ′ ＶＢ′ ＡＢＣ　 ＶＡ Ｂ′Ｃ′Ｃ=13Ｓ1 ｈ 13Ｓ2 ｈ　 ＶＡ Ｂ′Ｃ′Ｃ.ＶＡ Ｂ′Ｃ′ＣＶＢ′ ＡＢＣ=ＶＡ Ｂ′Ｃ′ＣＶＡ ＢＢ′Ｃ′=Ｓ△Ｂ′Ｃ′ＣＳ△ＢＢ′Ｃ=Ｂ′Ｃ′ＢＣ ,ＶＡ Ｂ′Ｃ′ＣＶＡ Ａ′…     

固溶体结构对Ca2-xSrxZn4Ti15O36∶Pr3+发光性质的影响

Ca_2-xSr_xZn₄Ti₁₅O₃₆∶Pr red long decay phosphor was synthesized by high temperature solid state reaction. Photoluminescence property and crystalline and unit cell parameters of the orthorhombic were investigated by fluorescence spectrophotometer and by powder X-ray diffraction, respectively. The emission intensity at 618 nm changes sharply when the concentration of Sr²⁺ (x) is less than 0.1 and the emission intensity reaches the maximum when x is equal to 0.007. There is an obviously broad excitation band at 270 nm when x is equal to 0.003 and it disappears gradually when x is over 0.01. The unit cell a parameter of Ca_2-xSr_xZn₄Ti₁₅O₃₆∶Pr decreases while c parameter increases with the increases of the concentration of the doped Sr²⁺. When x is over 0.1 the value of the unit cell parameters a and c become stable. TL peaks of Ca₂Zn₄Ti₁₅O₃₆∶Pr, Ca_1.993Sr_0.007Zn₄Ti₁₅O₃₆∶0.002Pr³⁺, 0.002Na⁺, are located at 62 ℃, 88 ℃, respectively, which indicates that there are deeper traps in Ca_1.993Sr_0.007Zn₄Ti₁₅O₃₆∶0.002Pr³⁺, 0.002Na⁺.     

中心教学法在分析化学教学中的应用

将中心教学法应用于高等师范院校化学系专科班的经典分析教学。提出了树结构模型 ,对教学内容进行了相应的优化重组 ,对学生的“学”也提出了对应的新方法。对照试验表明这种方法具有省时高效的特点     

红色长余辉发光材料Ca2Zn4Ti15O36∶Pr3+的合成和发光性质

分别采用高温固相法和溶胶-凝胶法合成了新型红色长余辉发光材料Ca2Zn4Ti15O36∶Pr. 高温固相法合成Ca2Zn4Ti15O36需要在1200 ℃灼烧96 h才能形成纯物相. 热重分析曲线和X射线衍射分析结果表明 溶胶-凝胶法制得的前驱体在700 ℃灼烧12 h开始形成Ca2Zn4Ti15O36物相; 在1000 ℃灼烧24 h得到Ca2Zn4Ti15O36纯物相; 最佳反应温度为1000 ℃, 激活剂Pr3+的最佳浓度为0.6mol%, 发光强度比高温固相法增强了510%.     

CaS:Cu~+,Eu~(2+)的光致发光及其在农业生产中的应用

研究了Ｃｕ＋，Ｅｕ２＋共激活的ＣａＳ的发光性质及激活剂浓度与荧光性质的关系．Ｃｕ＋和Ｅｕ２＋的发射光谱分别在４３０ｎｍ附近及６３０ｎｍ附近，它们是由Ｃｕ，Ｃａ－Ｖｓ２＋中心的离子发射和Ｅｕ２＋的５ｄ－４ｆ跃迁发射产生的．实验结果表明，Ｃｕ＋对Ｅｕ２＋荧光发射有较强的敏化作用，Ｅｕ２＋对Ｃｕ＋发射峰值波长和强度也有显著影响；单掺Ｅｕ２＋或Ｃｕ＋的荧光粉是良好的农用薄膜红，蓝光转换剂，共掺Ｅｕ２＋和Ｃｕ＋的ＣａＳ荧光粉作光转换农膜添加剂可望人工模拟叶绿素的吸收光谱，使作物在植物最佳生长作用光谱环境中生长，促使作物早熟或提高作物产量     

Polarographic catalytic wave of hydrogen——Parallel catalytic hydrogen wave of bovine serum albumin in the presence of oxidants

A polarographic catalytic hydrogen wave of bovine serum albumin (BSA) at about -1.80 V (vs. SCE) in NH4CI-NH3 · H2O buffer is further catalyzed by such oxidants as iodate, per-sulfate and hydrogen peroxide, producing a kinetic wave. Studies show that the kinetic wave is a parallel catalytic wave of hydrogen, which resulted from that hydrogen ion is electrochemically reduced and chemically regenerated through oxidation of its reduction product, atomic hydrogen, by oxidants mentioned above. It is a new type of poralographic catalytic wave of protein, which is suggested to be named as a parallel catalytic hydrogen wave.