Diffusion behavior of helium in titanium and the effect of grain boundaries revealed by molecular dynamics simulation

The microstructures of titanium(Ti), an attractive tritium(T) storage material, will affect the evolution process of the retained helium(He). Understanding the diffusion behavior of He at the atomic scale is crucial for the mechanism of material degradation. The novel diffusion behavior of He has been reported by molecular dynamics(MD) simulation for the bulk hcp-Ti system and the system with grain boundary(GB). It is observed that the diffusion of He in the bulk hcp-Ti is significantly anisotropic(the diffusion coefficient of the [0001] direction is higher than that of the basal plane),as represented by the different migration energies. Different from convention, the GB accelerates the diffusion of He in one direction but not in the other. It is observed that a twin boundary(TB) can serve as an effective trapped region for He.The TB accelerates diffusion of He in the direction perpendicular to the twinning direction(TD), while it decelerates the diffusion in the TD. This finding is attributable to the change of diffusion path caused by the distortion of the local favorable site for He and the change of its number in the TB region.     

冲击波和高速破片联合作用下夹芯复合舱壁结构的毁伤特性

为探讨导弹战斗部近炸下舰船夹芯复合舱壁结构设计方法,采用TNT和预制破片近炸实验研究了典型夹芯复合舱壁结构在冲击波与高速破片联合作用下的破坏效应,分析了冲击波和破片联合毁伤载荷,指出了钢质面板和抗弹层的破坏模式,阐述了夹芯复合舱壁结构的防护机理。结果表明:预制破片装药近炸下,破片能远大于冲击波能,是防护结构的主要设计载荷;前面板主要是抵御冲击波,其变形破坏整体为挠曲大变形,局部为集团破片冲塞破口、破片穿孔和撞击凹坑;背板以挠曲大变形吸能为主;陶瓷材料碎裂严重,部分陶瓷碎片反向飞溅撞击前面板;纤维增强复合材料发生了纤维断裂、基体开裂、整体弯曲大变形及分层等破坏,抗弹层应避免产生穿透性破坏。     

液滴对爆炸冲击波的衰减作用

为分析液滴对舰船舱内爆炸冲击波的耗散与衰减作用,通过有限元分析方法,建立冲击波作用于不同尺寸单个液滴和多排液滴的模型,分析冲击波与单个及多个液滴的作用过程及液滴形态变化,对冲击波衰减规律进行分析总结。得到结论如下:单个液滴模型中,小液滴破碎更迅速,破碎的规律性强;大液滴抛撒现象发生较早,抛撒出的小液滴数目多,但整体变化规律性偏差;不同尺寸单个液滴对冲击波有一定的衰减作用,衰减率随液滴尺寸增大而增大,线性规律较明显;成排液滴对冲击波有明显的衰减作用,相同液滴密度下衰减率随着液滴数量的增多而增大,呈现明显的线性特性。     

水下舷侧多层防护隔舱接触爆炸毁伤载荷特性分析

为探讨水下多层防护隔舱结构设计,以典型三舱式结构为对象,利用Dytran软件分析了水下接触爆炸下舷侧多层防护隔舱中膨胀空舱内的毁伤载荷特性,得到了载荷的简化模型,并拟合出膨胀舱压力载荷脉动平稳阶段准静态气压值的计算公式。结果表明,膨胀空舱内的毁伤载荷特性在时间尺度上可分为气团膨胀扩散阶段和脉动平稳两个阶段;在空间分布上,主要分为正反射区和马赫反射区,正反射区作用载荷由初始瞬态脉冲载荷和后续逐渐衰减的准静态气压载荷叠加而成,马赫反射区作用载荷则以准静态气压为主。     

破片高速侵彻中厚背水钢板的剩余特性

为探讨破片高速侵彻中厚背水钢板的剩余特性,通过弹道实验,分析了弹体和靶板的破坏模式,比较了破片侵彻垂直和倾斜背水钢板后的瞬时余速和运动轨迹, 以及由此引起的初始冲击波的压力特性。结果表明,破片在高速侵彻下,头部产生了严重的镦粗变形,钢板背后水介质的动支撑作用不容忽视;背水钢板的破坏模式主要为剪切冲塞破坏,背弹面穿孔存在绝热剪切效应;破片穿透背水钢板初期,会产生空泡和射流,空泡大小和射流强度与破片入水初速有关,而空泡形状和射流方向则受背水钢板的倾斜角度影响;破片穿透背水钢板后,在水中的运动轨迹会发生偏转,偏转方向与破片入水初速有关;由于水介质的动支撑作用和动能耗散效应,破片穿透背水钢板后的动能损失要大于穿透背空钢板的情形;水中初始冲击波的压力特性应考虑稀疏波的影响;相同初速下,破片侵彻垂直背水钢板引起的初始冲击波的峰值压力较侵彻倾斜背水钢板要大。     

普朗克常数的测量

本文运用绝对黑体辐射炉，采用三种不同方法测量ｈ，获得较好的结果。     

Mg+注入对GaN晶体辐射损伤的研究

在蓝宝石衬底上通过金属有机物化学气相沉积(metal-organic chemical vapor deposition，MOCVD)方法外延生长的GaN薄膜具有良好的结晶品质，χ_min达到2.00%. 结合卢瑟福背散射/沟道(Rutherford backscattering/channeling，RBS/C)和高分辨X射线衍射(high-resolution X-ray diffraction，HXRD)的实验测量，研究了不同剂量和不同角度Mg⁺注入GaN所造成的辐射损伤. 实验结果表明，随注入剂量的增大，晶体的辐射损伤也增大，注入剂量在1×10¹⁵atom/cm²以下，χ_min小于4.78%，1×10¹⁶atom/cm²是Mg⁺注入GaN的剂量阈值，超过这个阈值，结晶品质急剧变差，χ_min达到29.5%；随机注入比沟道注入的辐射损伤大，且在一定范围内随注入角度的增大，损伤也增大，在4×10¹⁵atom/cm²剂量下偏离〈0001〉沟道0°，4°，6°，9°时的χ_min(%)分别为6.28，8.46，10.06，10.85；经过700℃/10min+1050℃/20s两步退火和1000℃/30s高温快速退火后，晶体的辐射损伤都有一定程度的恢复，而且1000℃/30s高温快速退火的效果更好，晶体的辐射损伤可以得到更好的恢复. 关键词： GaN 卢瑟福被散射/沟道 高分辨X射线衍射 辐射损伤     

二叉树期权定价方法的一种新推广

对目前普遍使用的期权定价二叉树模型进行了分析,利用随机误差校正方法推广出了一种新型的二叉树参数模型.     

SrTiO_3表面O_2,H_2_O吸附的UPS,XPS研究

观察到还原SrTiO_3_, 表面三价Ti 离子引起的表面态的存在.分析了它在太阳光分解水中所起作用, 以及光照在恢复活性中的作用. 关键词：     

Field emission patterns with atomic resolution of single-walled carbon nanotubes by field emission microscopy

Electron emission properties of single-walled carbon nanotubes (SWCNTs) assembled on a tungsten tip were investigated using field emission microscopy (FEM). The transmission electron microscopy (TEM) micrograph confirmed the existence of an SWCNT bundle on the W tip. Under appropriate experimental conditions,a series of FEM patterns with atomic resolution were obtained. These patterns arose possibly from the field emission of the open end of an individual (16,0) SWCNT protruding from the SWCNT bundle. The magnification factor and the resolution under our experimental conditions were calculated theoretically. If the value of the compression factor β was set at β= 1.76, the calculated value of the magnification factor was in agreement with the measured value. The resolving powerof FEM was determined by the resolution equation given by Gomer. The resolutionof 0.277 nm could be achieved under the typical electric field of 5.0×107 V/cm, which was close to the interatomic separation 0.246 nm between carbon atoms along the zigzag edge at the open end for the (16, 0) SWCNT. Consequently, our experimental results were further supported by our theoretical calculation.