Effects of pre-deformation on the martensitic transformation and magnetocaloric property in Ni-Mn-Co-Sn ribbons

This paper investigates the martensitic transformation and magnetocaloric effect in pre-deformed Ni-Mn-Co-Sn ribbons.The experimental results show that the reverse martensitic transformation temperature T M increases with the increasing pre-pressure,suggesting that pre-deformation is another effective way to adjust T M in ferromagnetic shape memory alloys.Large magnetic entropy changes and refrigerant capacities are obtained in these ribbons as well.It also discusses the origin of the enhanced martensitic transformation temperature and magnetocaloric property in pre-deformed Ni-Mn-Co-Sn ribbons.     

Conjecture on Avoidance of Big Crunch

By conjecturing the physics at the Planck scale, we modify the definition of the Hawking temperature and modify the Friedmann equation. It is found that we can avoid the singularity of the big crunch and obtain a bouncing cosmological model.     

Temperature-related performance of Yb^3＋：YAG disc lasers and optimum design for diamond cooling

In this paper the temperature-related performances of the Yb^3＋：YAG disc laser has been investigated based on quasi-three level rate equation model. A compact diamond window cooling scheme also has been demonstrated. In this cooling scheme, laser disc is placed between two thin discs of single crystal synthetic diamond, the heat transfer from Yb^3＋：YAG to the diamond, in the direction of the optical axis, and then rapidly conducted radically outward through the diamond to the cooling water at the circumference of the diamond/Yb^3＋ ：YAG assembly. Simulation results show that increasing the thickness of the diamond and the overlap-length （between diamond and water） decreases the disc temperature. Therefore a 0.3-0.5 mm thick diamond window with the overlap-length of 1.5 2.0 mm will provide acceptable cost effective cooling, e.g., with a pump intensity of 15 kW/cm^2 and repetitive rate of 10 Hz, to keep the maximum temperature of the lasing disc below a reasonable value （310K）, the heat exchange coefficient of water should be about 3000 W/m^2K.     

Super-Resolution Imaging on Microfluidic Super-Resolution Near-Field Structure

We present a new concept of the microfluidic super-resolution near-field structure (MSRENS) based on a microfluidic structure and a super-resolution near-field structure. The near-field distance control, “nano-probe” and scanning can be realized simultaneously using the MSRENS, which is similar to a near-field scanning optical microscope. The design and simulation results are presented. Numerical simulation has demonstrated that the MSRENS with spatial resolution beyond the diffraction limit could be applicable in chemistry, biologics, and many other fields.     

Enhanced Three-Photon Absorption by Symmetric Twisted Intramolecular Charge Transfer

We report on a novel organic chromophore with symmetric twisted intramolecular charge transfer (TICT) state on excitation. The properties of nonlinear transmission induced by three-photon absorption (3 PA) are demonstrated pumped with nanosecond laser pulse. Large 3PA cross sections as high as the order of 10^-74 cm^6s^2 have been obtained for nanosecond and picosecond laser pulses at 1064 nm from intensity-dependent transmission measurements. Similar two emissive behaviours from one-photon and three-photon excited fluorescence spectra indicate that the linear and nonlinear fluorescences share the same TICT relaxation process from the excited states. The intensity dependence of upconversion fluorescence on the incident intensity obeys the cubic law that characterizes the three-photon absorption.     

MgO-Al2O3-ZrO2复合粉的制备与表征

以Mg Cl2·6H2O,Al Cl3·6H2O和Zr OCl2·8H2O为原料,NH3·H2O为沉淀剂,采用溶胶-凝胶法制备了三种Mg O/Al2O3/Zr O2质量比分别为10.0/41.4/48.6、15.0/39.1/45.9、20.0/36.8/43的Mg O-Al2O3-Zr O2复合粉。借助X-ray荧光分析仪、同步热分析仪、X-ray衍射仪、激光粒度分析仪、扫描电子显微镜对Mg O-Al2O3-Zr O2复合粉进行了表征。研究结果表明:Mg O-Al2O3-Zr O2复合粉前驱体的分解在600℃之前完成,之后随着温度升高,复合粉体析晶程度逐渐提高,在800℃的热处理温度下四方相少量析出,Mg O和Al2O3仍处于非晶相,此状态下的复合粉应具有较高的反应活性;制得的Mg O-Al2O3-Zr O2复合粉体化学成分均匀性好,粒径较细,且与氧化锆原料尺寸相匹配,可作为氧化锆质定径水口改性的添加剂。     

并联结构微光纤双结谐振器中的慢光效应

为了研究基于微光纤的谐振器中的慢光效应,设计并制作了并联结构的微光纤双结谐振器.基于环形谐振器和方向耦合器理论,提出并联结构微光纤双结谐振器的理论模型,分析了该谐振器中光场传输和耦合的方向,推导了该谐振器中输出光场与输入光场之间的数学解析式和群延时表达式.通过数值模拟,给出了有关该谐振器的透射光谱和群延时,分析了群延时与透射光谱中谐振波长的对应关系.数值结果表明在该谐振器中,大的群延时能够在具有大消光比的谐振波长处产生.实验制作了一个并联结构的微光纤双结谐振器,测得的透射光谱与理论模拟相一致,验证了该谐振器理论分析的正确性.利用示波器上脉冲延时的方法,搭建了慢光延时测量系统,测得该谐振器中大约75 ps的群延时,远大于现有文献中的值.该谐振器可用于微纳光学的数据延时线、光学开关和光学存储等.     

CO诱导的FeO(111)/Ru(0001)负载Au原子吸附位和电荷的改变

采用密度泛函理论研究了CO气氛对FeO(111)/Ru(0001)负载Au原子吸附位、电荷及其稳定性的影响. 首先考察了FeO(111)单层薄膜在Ru(0001)表面上的界面结构. 研究发现,表面莫尔超晶胞内的HCP区域有最小的Fe-O层间距(rumpling),且Fe和O原子均与衬底Ru形成化学键. Au原子在FeO/Ru(0001)上最稳定的吸附在HCP区域的Fe-bridge位. 其中,Au原子诱导两个Fe原子从O原子层的下面翻转到其上面,形成两个Au-Fe键,且Au带负电. 当把体系暴露在CO气氛下后,CO能诱导Au原子从原来最稳定的Fe-bridge位转移到其邻近的O-top位,伴随着Au的电荷从负变到正,形成非常稳定的Au⁺-CO羰基物. 结果表明,反应气氛对负载金属催化剂的化学状态及其稳定性的影响很大; 同时也强调了反应条件下催化剂原位表征的重要性.     

测定核间距的不对称2DNOESY方法Ⅲ．从不对称2DNOESY重叠峰强度求取完整混合系数矩阵

建立了包括重叠峰在内的不对称２ＤＮＯＥＳＹ峰强度来求取完整混合系数矩阵的方法。并应用数值模拟方法验证了其正确性。该方法充分利用了不对称２ＤＮＯＥＳＹ重叠峰强度来求解完整混合系数矩阵，这对大分子体系中核间距的准确计算是有价值的。     

4×2片状放大器能源系统防电磁干扰研究

 对4×2片状放大器能源系统整个充放电过程中的几种电磁干扰进行了详细的分析比较，针对这些电磁干扰，采取储能电容器一端接地、整个能源模块单点接地、预电离屏蔽以及光纤隔离等防干扰措施，消除了4×2片状放大器能源系统的电磁干扰，使整个系统运行安全、稳定、可靠。