Thermodynamic and transport properties of spiro-(1,1')-bipyrrolidinium tetrafluoroborate and acetonitrile mixtures:A molecular dynamics study

Organic salts such as spiro-(1,1')-bipyrrolidinium tetrafluoroborate([SBP][BF4]) dissolved in liquid acetonitrile(ACN) are a new kind of organic salt solution,which is expected to be used as an electrolyte in electrical double layer capacitors(EDLCs).To explore the physicochemical properties of the solution,an all-atom force field is established on the basis of AMBER parameter values and quantum mechanical calculations.Molecular dynamics(MD) simulations are carried out to explore the liquid structure and physicochemical properties of [SBP][BF4] electrolyte at room temperature.The computed thermodynamic and transport properties match the available experimental results very well.The microscopic structures of [SBP][BF4] salt solution are also discussed in detail.The method used in this work provides an efficient way of predicting the properties of organic salt solvent as an electrolyte in EDLCs.     

Interplay of Rashba effect and spin Hall effect in perpendicular Pt/Co/MgO magnetic multilayers

The interplay of the Rashba effect and the spin Hall effect originating from current induced spin–orbit coupling was investigated in the as-deposited and annealed Pt/Co/MgO stacks with perpendicular magnetic anisotropy. The above two effects were analyzed based on Hall measurements under external magnetic fields longitudinal and vertical to dc current,respectively. The coercive field as a function of dc current in vertical mode with only the Rashba effect involved decreases due to thermal annealing. Meanwhile, spin orbit torques calculated from Hall resistance with only the spin Hall effect involved in the longitudinal mode decrease in the annealed sample. The experimental results prove that the bottom Pt/Co interface rather than the Co/MgO top one plays a more critical role in both Rashba effect and spin Hall effect.     

Damage effect and mechanism of the GaAs pseudomorphic high electron mobility transistor induced by the electromagnetic pulse

The damage effect and mechanism of the electromagnetic pulse(EMP) on the GaAs pseudomorphic high electron mobility transistor(PHEMT) are investigated in this paper. By using the device simulation software, the distributions and variations of the electric field, the current density and the temperature are analyzed. The simulation results show that there are three physical effects, i.e., the forward-biased effect of the gate Schottky junction, the avalanche breakdown, and the thermal breakdown of the barrier layer, which influence the device current in the damage process. It is found that the damage position of the device changes with the amplitude of the step voltage pulse. The damage appears under the gate near the drain when the amplitude of the pulse is low, and it also occurs under the gate near the source when the amplitude is sufficiently high, which is consistent with the experimental results.     

基于3D-EEMs和PARAFAC的土壤渗滤系统DOM垂直分布特征

利用三维荧光光谱(3D-EEMs)和平行因子分析(PARAFAC)的方法研究了土壤渗滤系统处理模拟高氨氮废水中溶解性有机物(DOM)的垂直分布特征。试验在一个中试规模的土壤渗滤系统中进行,反应器自上而下每隔30 cm设置一个采样口,采集的样品通过PARAFAC识别出系统不同点位的DOM具有四个荧光组分,包括两个类腐殖质物质(C1,C2)、2个类蛋白物质(C3,C4)。相关性分析显示,四种荧光组分与多数理化指标呈现极显著性正相关关系,可以用荧光组分浓度间接表征系统对氮、磷等营养元素的去除效果。对荧光组分浓度得分F_max分析得出,土壤渗滤系统中类酪氨酸最易降解,其次为类富里酸、类胡敏酸类物质,最难以降解的为类蛋白物质。     

Experimental demonstration of underwater optical wireless power transfer using a laser diode

We experimentally demonstrate an underwater optical wireless power transfer(OWPT) using a laser diode(LD)as a power transmitter. We investigate the characteristics of a solar cell and a photodiode(PD) as a power receiver. We optimize the LD, the PD, and the solar cell to achieve the maximum transfer efficiency. The maximum transfer efficiency of the back-to-back OWPT is measured as 4.3% with the PD receiver. Subsequently, we demonstrate the OWPT in tap and sea water. Our result shows an attenuation of 3 dB/m in sea water.     

Mean-square composite-rotating consensus of second-order systems with communication noises

We study the mean-square composite-rotating consensus problem of second-order multi-agent systems with communication noises, where all agents rotate around a common center and the center of rotation spins around a fixed point simultaneously. Firstly, a time-varying consensus gain is introduced to attenuate to the effect of communication noises. Secondly, sufficient conditions are obtained for achieving the mean-square composite-rotating consensus. Finally, simulations are provided to demonstrate the effectiveness of the proposed algorithm.     

大气湍流对空间目标偏振成像探测的影响

为研究大气湍流对空间目标偏振成像探测准确度的影响,构建了大气湍流影响下的偏振成像探测模型,并对大气湍流导致的空间目标偏振度探测偏差进行仿真分析.通过对分时和同时偏振成像方式进行仿真,发现大气湍流会对空间目标偏振成像探测准确度造成明显影响,且对分时偏振成像探测准确度的影响明显大于同时偏振成像方式.通过自适应系统校正部分低阶像差,能明显减小大气湍流对偏振成像探测准确度的影响.为了兼顾图像信噪比和大气湍流影响下的偏振成像探测准确度,给出了一种结合分时和同时成像方式的改进偏振成像探测方式,大气湍流对其的影响略大于同时偏振成像方式,但该方式图像信噪比明显优于同时偏振成像方法.另外仿真分析发现,采用多帧图像叠加能效减小大气湍流带来的空间目标偏振成像探测偏差,在使用分时偏振成像方式时效果尤为明显.     

构建物理模型 切忌随心所欲

以不可压缩流体通过流管各截面的流量都相等这一连续性原理和“ 游乐园入口旁有一喷泉”这一实际 条件为依据, 评析2 0 1 6年高考河北省教育考试院印发的“ 试题与参考答案”理科综合能力测试第3 5( 2) ( i i )题中把 水柱强行视为圆柱体模型的错误做法, 并给出了适切模型和正确解法     

高电荷态Ar^q＋与Ne碰撞中入射离子电荷交换截面的研究

报道Ar^q Ne(q=8，9，11，12)碰撞体系中多电子转移过程，得到了多组实验测量电荷交换截面数据，讨论入射离子电荷交换截面、反冲离子产生截面与入射离子电荷态、能量以及散射离子电荷态的关系，并且将实验结果与Ar^q Ar碰撞体系进行对比研究。在修正分子库仑过垒模型的基础上，对实验现象做了合理的解释。     

在杨氏双缝干涉实验中非单色光干涉图样的理论判断方法

本给出了杨氏双缝干涉实验中非单色光产生干涉图样的两种理论判断方法。