N-苯基-α-氨基酸的微波合成及表征

以溴苯，α-氨基酸为原料，碘化亚铜为催化剂，DMF为溶剂，在碱性介质中微波辐射合成了目标化合物，并以颉氨酸与溴苯的偶联为模型反应进行条件优化，产物结构经IR，1H NMR表征。     

离子注入对MoN_x薄膜超导转变温度的影响

本文研究了离子注入参数、离子注入方式对MoN_x薄膜T_c的影响。实验结果表明:通过提高离子注入剂量、能量使MoN_x薄膜的T_c值提高将受到限制。而改变离子注入方式对提高MoN_x薄膜的T_c值效果显著。     

Structure and phase transition of a two—dimensional dusty plasma

The structure and phase transition of a two-dimensional (2D) dusty plasma have been investigated in detail bymolecular dynamics simulation. Pair correlation function, static structure factor, mean square displacement, and bondangle correlation function have been calculated to characterize the structural properties. The variation of internalenergy, shear modulus, particle trajectories and structural properties with temperature has been monitored to studythe phase transition of the 2D dusty plasma system. The simulation results are in favour of a two-step continuoustransition for this kind of plasma.     

阿司匹林半微量合成实验的改进

从反应机理入手,对传统文献中的阿司匹林半微量合成装置的进行合理改进,从而达到有效控温、严格防潮、充分搅拌、提高反应产率的效果。     

大气条件等离子体针处理Enterococcus faecalis菌

自行研制的等离子体针在大气压下通过介质阻挡放电产生的等离子体,再由喷嘴处安装的漏斗形装置聚焦形成针状等离子体. 然后对针状等离子体的基本特性和杀Enterococcus faecalis(E. faecalis)菌进行了研究,E. faecalis菌是一种引起完善充填根管再感染的主要微生物. 当等离子体针功率为5-28W时,对等离子体的温度进行了测量,表明它不同于其他热杀菌方式. 通过改变等离子体针内电极末端注入的氧气量,发现适当的氧气量,不仅增加等离子体内含氧粒子的浓度而且对等离子体的长度影响也不明显. 实验表明最佳参数为功率15W,0.1m3·h-1氦和2.5%氧气,间距12mm,处理时间30 s. 为了找出杀菌的关键粒子,进一步比较了大气压下的等离子体针的发射光谱与agar(琼脂)2mm下的光谱并找出关键粒子.     

Bi系高温氧化物超导体CuO2面内Cu-O键伸缩振动的分析

测试了一系列Ｂｉ系高温氧化物超导体的红外吸收谱，分析了Ｂｉ系超导样品ＣｕＯ２面内Ｃｕ－Ｏ键的伸缩振动与样品超电性的联系。结果表明，ＣｕＯ２面内Ｃｕ－Ｏ伸缩振动吸收峰强度的变化与样品零电阻的变化一致，其原因与微观结构内部声子与载流子的相互作用密切相关。其次，根据分子振动理论，采用简化模型计算了Ｂｉ系超导体ＣｕＯ２面内Ｃｕ－Ｏ振支频率     

Removal of NO Molecules by a Novel Atmospheric Pressure Plasma Apparatus

A novel atmospheric pressure plasma apparatus （APPA） is designed with a liquid electrode, and its discharging characteristics are studied. Relatively uniform and intense discharge can be realized in the APPA system. An experimental study on removal of NO molecules is carried out by using the APPA, and more than 95.5% of NO is decomposed when the NO initial concentration is lower than 400ppm. Removal of NO efficiency increases rapidly with the increasing discharge power. Compared with the absence of O2, more NO2 is generated with the increase of O2 concentration. However, most of the NO molecules are decomposed to N2 and O2 directly, when O2 concentration changes from 0 to 1.1 vol%.     

小波分析在寄生参数提取中的应用

将小波分析方法应用于求解三维（３－Ｄ）边界元素法形成的线性方程组。通过数据压缩将稠密矩阵化为稀疏矩阵，当求解具有相同系数矩阵和多个不同右端向量的方程组时，可以节省计算量。     

Impact of microsecond-pulsed plasma-activated water on papaya seed germination and seedling growth

The seed of Carica papaya consists of a hard shell-like testa with inhibitors in vivo causing slow, erratic and asynchronous germination. In this work, plasma-activated water prepared by microsecond-pulsed plasma jets (μPAW) was applied to treat papaya seeds. The μPAW after plasma activation of 30 min was about 40 ℃. The reactive species such as NO₂, NO₃, and H₂O₂ in the μPAW activated from deionized water were measured and correlated to the seed germination rate and the seedling growth performance. The μPAW-treated papaya seed achieved a higher germination rate of 90%, which is 26% higher than the control group using deionized water. Comparing the results with a hot water (40 ℃) reference group showed that the reactive species in μPAW played primary roles in germination improvement, with little effect caused by the heat shock. The μPAW also sterilized the treated seeds, reducing the germination stress. The morphological change in the seeds was observed by SEM, showing an effect of physical etching after treatment promoting seed imbibition. The biochemical mechanism of the seed germination was deduced with reference to the evolution of surface chemistry, functional groups, and ABA content. The accelerated seed metabolism observed was corresponded to the chemical modification pathway. Besides, early seedlings developed from treated seeds were observed to be healthy, grow more leaves, and have better root structures. The content of MDA in the treated papaya seedlings decreased along with increased SOD and higher ion concentration. The μPAW that can be prepared at atmospheric pressure for bulk production offers a low-risk and cost-effective seed priming technology that may significantly increase the production of agricultural crops.     

Increasing the ·OH radical concentration synergistically with plasma electrolysis and ultrasound in aqueous DMSO solution

In recent years, significant increases in waste processing and material engineering have been seen by using advanced oxidation processes. The treatment results and energy yields of these processes are largely determined by the generation and retention of reactive oxygen species (ROS). However, increasing the amount of ROS remains a key challenge because of the unavailability of performance- and energy-efficient techniques. In this study, plasma electrolysis, ultrasound, and plasma electrolysis combined with ultrasound were used to treat dimethyl sulfoxide (DMSO) solutions, and the results showed that the two methods can synergistically convert filament discharge into spark discharge, and the conversion of the discharge mode can significantly increase the concentration of OH radicals and effectively improve the efficiency of DMSO degradation. We verified the rationality of the results by analyzing the mass transfer path of ROS based on the reaction coefficients and found that the ·OH radicals in aqueous solution were mainly derived from the decomposition of hydrogen peroxide. These findings indicated that the synergistic action of plasma electrolysis and ultrasound can enhance the production of chemically reactive species, and provide new insights and guiding principles for the future translation of this combined strategy into real-life applications. Our results demonstrated that the synergistic strategy of ultrasound and plasma electrolysis is feasible in the switching mode and increasing the ROS, and may open new routes for materials engineering and pollutant degradation.