考虑人类流动行为的动态复杂网络研究

现实的复杂网络往往具有动态的结构特征.考虑人类流动行为的特点,提出一种随机行走网络模型对人类流动网络进行模拟研究.从度分布、聚类系数、最短路径距离以及位移分布等方面对该模型进行模拟分析,结果表明,该动态复杂网络度分布服从泊松分布,呈现随机网络特征;当通信半径大于某一较小数值时,具有高的聚类系数和短的平均路径长度,呈现小世界网络特征;而位移分布则满足幂律分布,这一结论与近年来人们对人类流动行为的实证研究结果相符合.     

Enhancement of upconversion luminescence of YAlO3:Er3+ by Gd3+ doping

The upconversion luminescences of YAlO3:Er3+ phosphor co-doping with different Gd3+ concentrations are investigated under the excitation of 980- and 532-nm diode lasers. A near ultraviolet upconversion emission at 410 nm is observed in YAlO3 under 532-nm excitation. Moreover, the inactive Gd3+ ions can improve the upconversion intensity efficiently in a certain range of concentration. Under 980-nm excitation, the visible upconversion emissions at 546 and 646 nm are enhanced by about 10 and 8 times at the Gd3+ concentration of 40%, respectively. The upconversion emission at 410 nm under 532-nm excitation is also enhanced by 7 times. The substitution of Gd3+ ions for Y3+ sites changes the local symmetry of Er3+, leading to the improvement of upconversion efficiency.     

聚乙撑二氧噻吩导电聚合物上吗啡的电化学检测

在水相中电沉积制备得到了聚乙撑二氧噻吩（PEDOT）导电聚合物膜,研究了沉积电量、沉积电位等因素对聚合物膜的电化学活性及其在水溶液中检测吗啡的电化学响应的影-向．结果表明．沉积电量为20～40mC,沉积电位为1．2V（相对于Ag／AgCl电极）时所得的聚合物膜对吗啡具有最高的电化学响应．在此基础上,研究了PEDOT膜修饰电极在不同浓度的吗啡水溶液中的电化学检测,发现在0．05～6mmol·L^-1浓度范围内具有很好的线性响应．最低检测限为0．05mmol·L^-1,相关系数达0．995．     

Lamb＇s integral formulas of two-phase saturated medium for soil dynamic with drainage

When dynamic force is applied to a saturated porous soil, drainage is common. In this paper, the saturated porous soil with a two-phase saturated medium is simulated, and Lamb＇s integral formulas with drainage and stress formulas for a two-phase saturated medium are given based on Biot＇s equation and Betti＇s theorem （the reciprocal theorem）. According to the basic solution to Biot＇s equation, Green＇s function Gij and three terms of Green＇s function G4i, Gi4, and G44 of a two-phase saturated medium subject to a concentrated force on a spherical coordinate are presented. The displacement field with drainage, the magnitude of drainage, and the pore pressure of the center explosion source are obtained in computation. The results of the classical Sharpe＇s solutions and the solutions of the two-phase saturated medium that decays to a single-phase medium are compared. Good agreement is observed.     

半苞紫菊的化学成分

从光苞紫菊(NotoserispsilolepisShih)全草中分离到三个新化合物,通过波谱分析和化学降解将它们的结构分别鉴定为4,6-二对羟基苯乙酰基-D-葡萄糖、3,6-二对羟基苯乙酰基-D-葡萄糖和6-对羟基苯乙酰基-D-葡萄糖。此外,还分离出7个倍半萜内酯和2个香豆素化合物,其结构分别为scorzoside,austricin,lactusideB,jacquilenin,crepidiasideA,crepidiasideB,notoserolideA,6,7-二羟基香豆素和野莴苣甙。     

小波变换-偏最小二乘算法及其在复方甲硝唑注射液分析中的应用

提出了结合小波变换的偏最小二乘法（ＷＰＬＳ）,即先对光谱信号进行小波变换,去除噪声,再用偏最小二乘法对多组分同时测定。将该法用于模拟体系及复方甲硝唑注射液体系,结果表明,该法优于偏最小二乘法。     

三维有限体积TVD方法与冲击波的多级扩散研究

将TVD方法应用到三维,给出三维有限体积TVD方法,并对三维冲击波的多级坑道扩散问题进行了数值模拟,取得了令人满意的结果。     

Controlling the motion of solitons in BEC by a weakly periodic potential

By developing multiple-scale method combined with Wentzel--Kramer--Brillouin expansion, this paper analytically studies the modulating effect of weakly periodic potential on the dynamical properties of the Bose--Einstein condensates (BEC) trapped in harmonic magnetic traps. A black--grey soliton transition is observed in the BEC trapped in harmonic magnetic potential, due to the weakly periodic potential modulating effect. Meanwhile, it finds that with the slight increase of the weakly periodic potential strength, the velocity of the soliton decreases, while its width firstly decreases then increases, a minimum exists there. These results show that the amplitude, velocity, and width of matter solitons can be effectively managed by means of a weakly periodic potential.     

宽叶秦岭藤根部的化学成分

通过正相和反相硅胶柱层析从宽叶秦岭藤根部乙醇提取物中分离纯化得到19个化合物,经波谱分析并结合化学方法鉴定了其结构,其中4个为新化合物,它们分别是3,5-二羟基二十烷酸羽扇豆醇酯(3),2-羟甲基-5-甲氧基苯基-O-β-D-吡喃葡萄糖甙(11),Δ5-孕甾烯-3β,20(S)-二醇-20-O-β-D-吡喃葡萄糖基(1→6)-β-D-吡喃葡萄糖甙(18,秦岭藤甙C)和Δ5-孕甾烯-3β,20(S)-二醇-3-O-β-D-吡喃葡萄糖基-20-O-β-D-吡喃葡萄糖基(1→6)-β-D-吡喃葡萄糖甙(19,秦岭藤甙D).     

9-羟基苯嵌萘酮的基态能级劈裂的理论研究

当γ,μ满足一定条件时,六次函数V(R,γ)=C[R⁶+2γR⁴+(γ²+μ)R²]的图像是双势阱,可用来描述质子转移,且其相应的Schrodinger方程有解析解.用此势函数结合一维双势阱模型及变分法,并用B3P86密度泛函方法在6-311G水平下计算了该分子的平衡态和过渡态的构型及能量,研究了9-羟基苯嵌萘酮的基态能级劈裂,与其它理论值相比,所得计算结果[Δ_H(0)=86.13cm^-1]与实验值符合得较好.