Hydrogenated chalcogenide glasses As2−xSe3+x and As2−xS3+x prepared by plasma decomposition

Amorphous semiconductors As_2?xSe_3+x and As_2?xS_3+x have been prepared by glow discharge decomposition of a gas mixture of AsH₃  H₂Se and AsH₃  H₂S respectively. The films contain about 3–8 at. percent hydrogen according to infrared transmission measurements. Both S-H and Se-H vibrational modes were observed. Results of the D.C. electrical conductivity, X-ray structural analyses and optical absorption are presented. The films composition was found to be close to $\text{As:Se = As:S}\text{=}\text{2}\text{3}$.     

Block copolymer adsorption from a homopolymer melt to an amine-terminated surface

Using neutron reflectometry, the adsorption of diblock copolymers from a neutral polystyrene (PS) matrix is studied as a function of substrate type and non-adsorbing block degree of polymerization. The block copolymer is poly(deutero styrene)-block-poly(methyl methacrylate) and the substrates are silicon oxide, SiO_x, and SiO_x functionalized with (3-aminopropyl)triethoxysilane (APTES). We have determined the equilibrium volume fraction-depth profiles for such films, and compared them with volume fraction profiles generated by self-consistent mean-field (SCMF) theory and find good agreement between the experimental and theoretical data. SCMF calculations show that the segmental interaction energy between PS matrix chains and APTES is two orders of magnitude stronger than that between PS and SiO_x.     

The standard model on non-commutative space-time: strong interactions included

This paper is a direct extension of our earlier work on electroweak currents and the Higgs sector in the standard model on non-commutative space-time, now with strong interactions included. Apart from the non-commutative corrections to standard model strong interactions, several new interactions appear. The most interesting ones are gluonic interactions with the electroweak sector. They are elaborated here in detail and the Feynman rules for interactions up to are provided.Received: 18 March 2005, Revised: 13 May 2005, Published online: 19 July 2005     

Potential formation in a bounded two-electron temperature plasma system with floating collector that emits electrons

Formation of the plasma potential in a plasma that contains energetic electrons and is bounded by a floating collector that emits electrons is studied theoretically. The problem is treated by a static. kinetic plasma-sheath model of Schwager and Birdsall [Phys. Fluids B2 (1990) 1057], which we have extended in order to include additional energetic electron population. The distribution of these electrons is assumed to be a high-temperature Maxwellian. They are called hot electrons. In the paper we study effects of the density and temperature of the hot electrons on the formation of the plasma potential. The model shows that for certain densities and temperatures of the hot electron population plasmas with two different plasma potentials can coexist in the system. These two plasmas are separated spatially by a double layer. For the case when there is no emission of electrons from the collector, results of the model are compared with computer simulation and very good agreement between the model and the simulation is found. The simulation also confirms existence of two plasmas with two different potentials separated by a double layer.     

Unital Groups and General Comparability Property

Pseudo-effect algebras are partial algebras (E;+,0,1) with a partially defined addition + which is not necessarily commutative and therefore with two complements, left and right. If they satisfy a special kind of the Riesz decomposition property, they are intervals in unital po-groups. The general comparability property in unital po-groups with strong unit (G,u), allows to compare elements of G in some intervals with Boolean ends. Such a po-group is always an -group admitting a state. We prove that every such (G,u) is a subdirect product of linearly ordered unital po-groups.     

Measures on the Splitting Subspaces of an Inner Product Space

Let S be an inner product space and let E(S) (resp. F(S)) be the orthocomplemented poset of all splitting (resp. orthogonally closed) subspaces of S. In this article we study the possible states/charges that E(S) can admit. We first prove that when S is an incomplete inner product space such that dim S/S < , then E(S) admits at least one state with a finite range. This is very much in contrast to states on F(S). We then go on showing that two-valued states can exist on E(S) not only in the case when E(S) consists of the complete/cocomplete subspaces of S. Finally we show that the well known result which states that every regular state on L(H) is necessarily -additive cannot be directly generalized for charges and we conclude by giving a sufficient condition for a regular charge on L(H) to be -additive.     

Modeling deoxyribose radicals by neutralization-reionization mass spectrometry. Part 2. Preparation,dissociations, and energetics of 3-hydroxyoxolan-3-yl radical and cation

The title radical (1) is generated in the gas-phase by collisional neutralization of carbonyl-protonated oxolan-3-one. A 1.5% fraction of 1 does not dissociate and is detected following reionization as survivor ions. The major dissociation of 1 (approximately 56%) occurs as loss of the hydroxyl H atom forming oxolan-3-one (2). The competing ring cleavages by O[bond]C-2 and C-4[bond]C-5 bond dissociations combined account for approximately 42% of dissociation and result in the formation of formaldehyde and 2-hydroxyallyl radical. Additional ring-cleavage dissociations of 1 resulting in the formation of C(2)H(3)O and C(2)H(4)O cannot be explained as occurring competitively on the doublet ground (X) electronic state of 1, but are energetically accessible from the A and higher electronic states accessed by vertical electron transfer. Exothermic protonation of 2 also produces 3-oxo-(1H)-oxolanium cation (3(+)) which upon collisional neutralization gives hypervalent 3-oxo-(1H)-oxolanium radical (3). The latter dissociates spontaneously by ring opening and expulsion of hydroxy radical. Experiment and calculations suggest that carbohydrate radicals incorporating the 3-hydroxyoxolan-3-yl motif will prefer ring-cleavage dissociations at low internal energies or upon photoexcitation by absorbing light at approximately 590 and approximately 400 nm.     

Study of nanocrystalline diamond film growth in rf hybrid laser deposition systems in O2, H2 and H2+Ar ambients

Pulsed laser deposition (PLD) and hybrid pulsed laser deposition (HPLD) systems were used for nanocrystalline diamond (NCD) film growth on Si(100) and sapphire(0001) substrates. The PLD system was based on a KrF excimer laser (=248 nm,20 ns), which ablated a graphite target in pure oxygen or hydrogen ambient. The HPLD system was based on a combination of PLD and additional capacitively coupled radio-frequency discharges (13.56 MHz) in argon–hydrogen ambient. Radio-frequency power was applied to two plane parallel electrodes or directly to the substrate holder. The working atmosphere pressure was varied from 1 Pa to 220 Pa and the substrate temperature was varied from 20 °C to 660 °C. X-ray diffraction analysis, Raman spectroscopy and a profilometer were used to study the deposited film properties. A band around 1180 cm^-1, which can be attributed to NCD, occurred in the Raman spectra. A characteristic diamond peak at 1332 cm^-1 was not observed. Films prepared by HPLD showed better compositional homogeneity (from Raman analysis) than films created by PLD. PACS 52.80.Pi; 81.07.Bc; 81.15.Fg     

Second experiment at VASSILISSA separator on the synthesis of the element 112

The upgraded separator VASSILISSA was used to confirm results of previous experiments on the synthesis of the heavy isotopes of the element 112 obtained in complete-fusion reactions of ⁴⁸Ca and ²³⁸U. An additional reason was the non-observation of any events in the same reaction studied with the BGS separator at Berkeley. Limits of for the atomic mass number of the observed spontaneously fissioning isotope were measured. The obtained results on the decay mode, half-life and production cross-section are in agreement with those obtained in our first experiment.Received: 10 June 2003, Revised: 29 July 2003, Published online: 2 December 2003PACS: 23.60. + e decay - 25.70.-z Low and intermediate energy heavy-ion reactions - 25.85.Ca Spontaneous fission - 27.90. + b      

Total and differential cross-sections for the pp\rightarrow pp\eta^\prime reaction near threshold

The -meson production in the reaction has been studied at excess energies of Q = 26.5, 32.5 and 46.6 MeV using the internal beam facility COSY-11 at the cooler synchrotron COSY. The total cross-sections as well as one angular distribution for the highest Q-value are presented. The excitation function of the near-threshold data can be described by a pure s-wave phase space distribution with the inclusion of the proton-proton final-state interaction and Coulomb effects. The obtained angular distribution of the -mesons is also consistent with pure s-wave production.Received: 11 August 2003, Revised: 14 November 2003, Published online: 6 April 2004PACS: 13.60.Le Meson production - 13.75.-n Hadron-induced low- and intermediate-energy reactions and scattering (energy GeV) - 13.85.Lg Total cross-sections - 25.40.-h Nucleon-induced reactions