Inversion and inversion-rotation spectrum of 14NH3 in the ν2 excited state

Using the vibration-inversion-rotation Hamiltonian for ammonia [V. ?pirko, J. M. R. Stone, and D. Papou?ek, J. Mol. Spectrosc.60, 159–178 (1976)], a modified theory is worked out for the Δk = ±3n interactions between the inversion-rotation energy levels of NH₃ which takes into account the large amplitude inversion motion. Eighty frequencies of inversion and inversion-rotation transitions and two perturbation-allowed transitions in the ν₂ state of ¹⁴NH₃ are measured in the far-infrared region around 1 THz (≈33 cm^?1), mostly with the microwave accuracy, by the radiofrequency spectrometer with acoustic detector. By a least-squares fit of these data and the data of the infrared-microwave two-photon and infrared heterodyne measurements of the ν₂ band, a set of molecular constants for the ν₂ state of ¹⁴NH₃ is obtained which reproduces the submillimeterwave data with the accuracy of the experiment.     

Extremal Values of L-Functions Associated with Newforms in the Half-Plane of Absolute Convergence

We prove estimates for extremal values of L-functions associated with newforms f in the half-plane of absolute convergence of their Dirichlet series expansion. The proof is based on an effective version of Kronecker's approximation theorem and estimates for the Fourier coefficients of the newform f.     

A complex impedance study of Pt∣NaCl and C∣NaCl interfaces

The a.c. impedance of Pt∣NaCl∣Pt and C∣NaCl∣C cells was measured in the frequency range from 10^?3 to 10³ Hz. Two contributions to the interface impedance could be distinguished, hindered charge transfer and an adsorption/desorption or slow reaction contribution, the latter being the rate determining step in the frequency range studied. An approximately symmetric nonlinear dependence of both the capacitance and the conductance on overvoltage was found at the lowest frequencies, indicating that the crystal/electrode interface is in a state which can be characterized as close to equilibrium. It should be ensured by two electrochemical reactions of approximately equal rates. The concept of a temporarily reversible electrode is introduced. It is a result of the ability of ions to discharge at the interface and to produce a finite reservoir of adsorbed or absorbed reaction products. An external voltage increases or reduces this reservoir, and therefore only a transient electric current may be carried by a backward reaction.     

Measurement of the electron distribution function in flowing afterglow plasma by means of Langmuir probe

Conclusion In the present report an attempt has been made to use the second derivative method for measurements of the electron distribution function in flowing afterglow plasma. It has been shown that using the cross-correlation technique, this method seems to be a useful tool for flowing afterglow plasma investigation.     

Density of states for intermediate valence and Kondo systems

We calculate the density of states for the nondegenerate Anderson model for various values ofu=U/ andn _f using the perturbation theory withu as the expansion parameter. Summing all the -independent self-energy diagrams, we use the Friedel sum rule and Ward identities to express the physical quantities in terms of the remaining -dependent part of the self-energy, which we evaluate to the 2nd order. The results for the spin and charge susceptibilities obtained in such a way compare rather well with the Bethe-ansatz results. The density of states exhibits different features in different parts of the parameter space. In Kondo region (u>1,n _f 1, i.e., – _f ~U/2), we obtain a many-body resonance (half-width T _K ) around the Fermi level and two broad peaks () at about _f +n _f U and _f +U. In the VF region (u>1, and | _f |) we obtain only two peaks (), one at about _f and one between _f +n _f U and _f +U. The consequences regarding the shape of the photoemission and inverse photoemission spectra of Ce intermetallics are discussed.     

Excitation functions for some output channels following the p +55Mn interaction atE p=1·3–2·0 MeV

Excitation functions for the⁵⁵Mn(p, p )⁵⁵Mn,⁵⁵Mn(p, n )⁵⁵Fe and⁵⁵Mn(p, )⁵⁶Fe reactions are studied for proton beam energyE _p=1·3–2 MeV. The excitation functions are established from yield functions for -rays emitted from the first excited states of final nuclei. Many resonances are observed and competition of their decay into all three output channels is analysed. Spin-parity assignment for some resonant states in the⁵⁶Fe compound nucleus is deduced.Participated partly in the course of his work on a Thesis.The authors wish to thank the staff of the Van de Graaff accelerator at Charles University in Prague for the efficient operation of the machine and dr. I. Wilhelm for the valuable technical help in the early period of the experimental work. One of us (N. A. N.) acknowledges the staff of the Dept. of Nuclear Physics of Charles University in Prague for the excellent working conditions.     

Two-body forces and amplitudes in the three-body model for the4He(\vec d,pα)n reaction withE d =12 and 17 MeV

The⁴He( ,p)n cross section, vector and tensor analyzing-power data with 12 and 17 MeV deuterons at kinematic conditions including proton-alpha quasifree scattering, neutron-alpha and proton-alpha final-state interactions, as well as collinearity, are compared with the predictions of the three-body model using different nucleon-alpha and neutron-proton forces. In general, better two-body potentials give a better fit to the data, except for the vector analyzing-power data. The roles of the impulse and multiple-scattering amplitudes are studied to understand the sensitivity to two-body potentials and to understand the reason for the successes and the failures of the model.     

Restoration of universality for the rod-to-coil transition scaling in the infinite-dimensionality limit: Exact results for directed walks

We derive scaling forms for the thermodynamic and correlation quantities for the turn-weighted fully and partially directed self-avoiding walks on the hypercubic lattices ind2. In the grand canonical (fixed fugacity per step) ensemble, the conformational rod-to-coil transition sets up in the regimew¯N=O(1), wherew is the weight of each 90° turn and¯N is the (fugacity-dependent) average number of steps. Contrary to the conventional critical phenomena wisdom, the scaling functions for the two different walk models, directed and partially directed, become universal only in the limitd.