Performance of modern oxide-confined (OC) vertical-cavity surface-emitting diode lasers (VCSEL s) is more sensitive to the construction details than in the case of other VCSEL s. In particular, a stable single-fundamental-mode operation is difficult to be achieved in these VCSEL s especially in higher-output large-size continuous-wave (cw) operating devices at higher temperatures. In the present paper, an operation of OC VCSEL s has been investigated with the aid of the comprehensive fully self-consistent model using the (GaIn)(NAs)/GaAs quantum-well VCSEL with two oxide apertures as a typical example. A new approach is proposed to enhance cw RT single-fundamental-mode low-threshold operation in higher-output OC VCSEL s. One of their oxide apertures should be shifted to the node position of the resonator standing wave where it is working as the electrical aperture only. Then diameters of both apertures may be changed independently giving an additional degree of freedom for VCSEL designing, which enables their optimisation. While the larger-diameter optical aperture placed in the anti-node position creates an efficient radial waveguiding effect, the smaller-diameter electrical aperture enhances a more uniform current injection into the VCSEL active region. Due to combining influence of both the apertures, the single-fundamental-mode operation is predicted in a large device with the 10-m-diameter active region even for 80 K active-region temperature increase over RT of the ambient. An impact of intentional detuning at room-temperature (RT) of VCSEL active-region gain spectrum towards shorter wavelengths with respect to the resonator mode improves mode selectivity is also analysed. PACS 42.55.Px; 02.60.Cb; 85.60.Bt 相似文献
We study ergodic averages for a class of pseudodifferential operators on the flatN-dimensional torus with respect to the Schrödinger evolution. The later can be consider a quantization of the geodesic flow on
. We prove that, up to semi-classically negligible corrections, such ergodic averages are translationally invariant operators.Mathematics Subject Classifications (2000) 58J50, 58J40, 81S10. 相似文献
This work compares the solid-state structures of films made from a polystyrene-poly(Z-L-lysine) (1) and a polystyrene-poly(-benzyl-L-glutamate) (2) block copolymer, both having virtually the same numbers of repeating units and block length ratios. Small-angle X-ray scattering (SAXS) revealed a hexagonal-in-undulated lamellar morphology for both films. The long-period and the thickness of layers obtained for 2 were by a factor of three smaller as compared to 1, indicating that PBLGlu helices were folded twice, whereas PZLLys helices were fully stretched. Another difference shows up in the packing of helices, the level of ordering being considerably lower in 2. This might be due to spatial restrictions in the proper alignment of back-folded helical segments. 相似文献
We deal with the Hermitian Hurwitz pairs of signature (, s), + s = 5 + 4, | + 1 – s| = 2 + 4m;, m = 0, 1,.... We introduce the Hurwitz twistors for signature (3, 2) and its dual (1, 4) and we indicate the relationship between Hurwitz and Penrose twistors. The signatures (1, 8) and (7, 6) give rise to pseudotwistors and bitwistors, respectively. For pseudotwistors, we prove a counterpart of the Penrose theorem in the local version, on real analytic solutions of the related spinor equations versus harmonic forms, and in the semiglobal version, on holomorphic solutions of those equations versus Dolbeault cohomology groups. We prove an atomization theorem: There exist complex structures on isometric embeddings for the Hermitian Hurwitz pairs so that the embeddings are real parts of holomorphic mappings. 相似文献
The Michael addition of selected sulfur and nitrogen nucleophiles to a chiral non-racemic 2-phosphono-2,3-didehydrothiolane S-oxide is fully diastereoselective. The enantiomeric excesses of the adducts obtained could be determined by 31P NMR spectroscopy using (R)-(+)-tert-butyl(phenyl)phosphinothioic acid as a chiral solvating agent. The addition of thiophenol was monitored by 31P NMR spectroscopy which made it possible to observe the formation and evolution of the kinetic and thermodynamic adducts in the reaction mixture. The structures of both enantiomeric thiophenol adducts have been determined by X-ray analysis. 相似文献
The lipophilicity of the novel 12 products of the reaction of N3-substituted amidrazones with cis-1,2-cyclohexanedicarboxylic anhydride (4 linear, 4 triazole-like and 4 isoindole ones) with potential pharmacologic activity was evaluated by thin layer and liquid chromatography. Using organic-aqueous eluent systems (with methanol or acetonitrile) on RP18 plates and C18 column, a linear relationship between the volume fraction of modifiers and the retention indices was obtained. The retention values, log k or RM were extrapolated to zero organic modifier content to obtain the log kw or RMW values. 12 compounds with known literature lipophilicity were used as a calibration dataset. The results were compared in a multivariate way with in silico methods (ALOGPs, AC_logP, AB/LogP, COSMOFrag, miLogP, ALOGP, MLOGP, KOWWIN, XLOGP3).
Azide ions (5–120 μg) are oxidized by cerium(IV) in an acidic medium. The nitrogen evolved is displaced by helium carrier and quantified by gas chromatography with a thermal conductivity detector. The relative standard deviation is <5%. Many sulphur anions, cyanide and some metal ions which form azide complexes do not interfere. 相似文献
Explicit results of the van der Pauw method for a sample containing an isolated hole are presented together with experimental confirmation. Results of measurements and numerical analysis strongly suggest that four probe resistivities obey inequality similar in the form to the famous van der Pauw equation. The inequality seems to be valid for any sample with an isolated hole and contacts located on the same edge, however rigorous proof is not given. The inequality can be used for experimental detection of the sample quality. 相似文献
We consider a deterministic process described by a discrete one-dimensional chaotic map and study its diffusive-like properties. Starting with the corresponding Frobenius-Perron equation we derive an approximate evolution equation for the probability distribution which is a partial differential equation of a hyperbolic type. Consequently, the process is correlated, non-Markovian, non-Gaussian and the information propagates with a finite velocity. This is in clear contrast to conventional diffusion processes described by a standard parabolic diffusion equation with an infinite velocity of information propagation. Our approach allows for a more complete characterisation of diffusion dynamics of deterministic systems. 相似文献