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81.
A glassy carbon electrode was modified with electropolymerized film of diphenylamine sulfonic acid (DPASA). Electropolymerization was performed by cyclic voltammetry in 0.1 M KCl solution. The modified electrode showed an excellent
electrocatalytic effect towards oxidation of dopamine (DA) and ascorbic acid (AA). Electrostatic interaction between the negatively charged poly(DPASA) film and either cationic DA species or anionic AA
species favorably contributed to the redox response of DA and AA. Anodic peaks of DA and AA in their mixture were well separated
by ca 168 and −11.8 mV. The proposed modified electrode was utilized for selective determination of dopamine in the concentration
range of 5.0 × 10t7–2.0 × 10−5 M in the presence of high concentration of ascorbic acid. Detection limit was 6.5 × 10−9 M. 相似文献
82.
In this paper we introduce some Tauberian conditions for the (A)(C, α) summability method. These results extend and generalize some of the classical Tauberian theorems for the Abel summability method. 相似文献
83.
İsmail Aslan 《Mathematical Methods in the Applied Sciences》2011,34(8):990-995
In this paper, we present an application of some known generalizations of the Exp‐function method to the fifth‐order Burgers and to the seventh‐order Korteweg de Vries equations for the first time. The two examples show that the Exp‐function method can be an effective alternative tool for explicitly constructing rational and multi‐wave solutions with arbitrary parameters to higher order nonlinear evolution equations. Being straightforward and concise, as pointed out previously, this procedure does not require the bilinear representation of the equation considered. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
84.
Gökce H Bahçeli S 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,78(2):803-808
Molecular geometry, vibrational wavenumbers and gauge including atomic orbital (GIAO) 13C NMR and 1H NMR chemical shift values of 1,3-phenylenediacetic acid (C10H10O4), in the ground state have been calculated by using ab initio Hartree-Fock (HF) and density functional theory (DFT/B3LYP) methods with 6-311++G(d,p) basis set for the first time. Comparison of the observed fundamental vibrational modes of 1,3-phenylenediacetic acid and calculated results by density functional B3LYP and Hartree-Fock methods indicate that B3LYP is superior to the scaled Hartree-Fock approach for quantum chemical studies. Geometric parameters (bond lengths and bond angles) and vibrational wavenumbers obtained by the HF and DFT/B3LYP methods are in good agreement with the experimental data. Furthermore, this is the first time the results of the calculated JCH and JCC coupling constants of the C10H10O4 molecule are presented in this study. 相似文献
85.
It is shown that a Korovkin type theorem for a sequence of linear positive operators acting in weighted space L
p,w
(loc) does not hold in all this space and is satisfied only on some subspace. 相似文献
86.
Yılmaz Turgut Nadir Demirel Halil Hoşgören 《Journal of inclusion phenomena and macrocyclic chemistry》2006,54(1-2):29-33
New chiral diaza-18-crown-6 ether derivatives, 5 and 6 were synthesized from (R)-(-)-2-amino-1-bütanol. These chiral artificial receptors exhibit pronounced chiral recognition toward the enantiomers of
l- and d- amino acid derivatives. The highest enantioselectivity was observed in the case of Trp-OMe·HCl (KD/KL=12.5). 相似文献
87.
Robert Leon Jerrard Halil Mete Soner 《Archive for Rational Mechanics and Analysis》1998,142(2):99-125
(Accepted August 19, 1996) 相似文献
88.
Yangsheng Yuan Yangjian Cai Jun Qu Halil T. Eyyubo?lu Yahya Baykal 《Optics & Laser Technology》2010,42(8):1344-1348
Based on the extended Huygens–Fresnel integral and the second-order moments of the Wigner distribution function, an analytical formulae for the propagation factors (M2-factors) of coherent and partially coherent one-dimensional Hermite–Gaussian beams in a turbulent atmosphere are derived. Evolution properties of the M2-factor of the Hermite–Gaussian beam in a turbulent atmosphere are studied numerically in detail. Our results show that the M2-factor of the Hermite–Gaussian beam increases upon propagation in a turbulent atmosphere. The M2-factor of the Hermite–Gaussian beam with larger beam order (or lower coherence) increases slower that of the Hermite–Gaussian beam with smaller beam order (or higher coherence) in a turbulent atmosphere, which means that the Hermite–Gaussian beam with a larger beam order and lower coherence is less affected by a turbulent atmosphere. Our results will be useful in long-distance free-space optical communications. 相似文献
89.
90.
İdris Dağ Alper Korkmaz Bülent Saka 《Numerical Methods for Partial Differential Equations》2010,26(3):544-560
The differential quadrature method based on cosine expansion is applied to obtain numerical solutions of the RLW equation. The propagation of single solitary wave is studied to validate the efficiency of the algorithm. Then, test problems including interaction of two and three solitary waves, undulation, and evolution of solitary waves are implemented. Solutions are compared with earlier results. Discrete conservation quantities are computed for test experiments. © 2009 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2009 相似文献