全文获取类型
收费全文 | 699篇 |
免费 | 18篇 |
国内免费 | 2篇 |
专业分类
化学 | 403篇 |
晶体学 | 13篇 |
力学 | 24篇 |
数学 | 142篇 |
物理学 | 137篇 |
出版年
2023年 | 6篇 |
2022年 | 10篇 |
2021年 | 14篇 |
2020年 | 22篇 |
2019年 | 28篇 |
2018年 | 24篇 |
2017年 | 17篇 |
2016年 | 46篇 |
2015年 | 20篇 |
2014年 | 30篇 |
2013年 | 113篇 |
2012年 | 48篇 |
2011年 | 63篇 |
2010年 | 55篇 |
2009年 | 39篇 |
2008年 | 37篇 |
2007年 | 37篇 |
2006年 | 21篇 |
2005年 | 13篇 |
2004年 | 13篇 |
2003年 | 10篇 |
2002年 | 18篇 |
2001年 | 7篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1998年 | 4篇 |
1997年 | 5篇 |
1996年 | 1篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1981年 | 1篇 |
1978年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有719条查询结果,搜索用时 31 毫秒
111.
Using integer and noninteger n-Slater type orbitals in single- and double-zeta approximations, the Hartree-Fock-Roothaan calculations were performed for the ground states of first ten cationic members of the isoelectronic series of He atom. All the noninteger parameters and orbital exponents were fully optimized. In the case of noninteger n-Slater type orbitals in double zeta basis sets, the results of calculations obtained are more close to the numerical Hatree-Fock values and the average deviations of our ground state energies do not exceed 2×10-6 hartrees of their numerical results. 相似文献
112.
We consider a combination of Chlodowsky polynomials with generalized Szasz operators involving Charlier polynomials. We give the degree of approximation for these bivariate operators by means of the complete and partial modulus of continuity, and also by using weighted modulus of continuity. Furthermore, we construct a GBS (Generalized Boolean Sum) operator of bivariate Chlodowsky–Szasz–Charlier type and estimate the order of approximation in terms of mixed modulus of continuity. 相似文献
113.
114.
This paper is a continuation of our recent work on the localization of the eigenvalues of matrices. We give new bounds for the real and imaginary parts of the eigenvalues of matrices. Applications to the localization of the zeros of polynomials are also given. 相似文献
115.
Halil Aksoy Mesut Sancar Ali Sen Betul Okuyan Leyla Bitis Fikriye Uras 《Natural product research》2016,30(4):452-455
The aim of this study is to determine the cutaneous wound healing effects of the ethanol extract of Cotinus coggygria leaves in rats by excision wound model to provide scientific evidence for the traditional use of C. coggygria Scop. The levels of malondialdehyde, catalase, superoxide dismutase, glutathione and hydroxyproline were investigated in wound tissues. Histopathological examination was also performed. The hydroxyproline content of the granulation tissue and the glutathione levels were both significantly higher in the treatment group than in the control group (p < 0.05 for both); while the malondialdehyde levels were significantly lower in the treatment group (p < 0.05). These results were supported with histological results. The ethanol extract of C. coggygria Scop could be considered as an effective agent in wound healing in accordance with its traditional use. 相似文献
116.
In this paper, we study generalized Cartan null Bertrand curves in semi-Euclidean 4-space \({\mathbb{E}_{2}^{4}}\) with index 2. 相似文献
117.
Halil Turgut Şahin 《Central European Journal of Chemistry》2007,5(3):824-834
Attempts were made to plasma deposit an oriented π-conjugated polymer of pyrrole (Py) on paper surfaces in order to produce
electrically conductive layers. The N/C atomic ratio of 0.13–0.24 was observed for all treatment conditions. This implies
the nature of the deposition formed on the paper surface via pulsed plasma is different from that of pyrrole monomer. An increase
in conductivity of all pyrrole-plasma treated papers was observed. The 50 W RF-power with 5 min plasma exposed paper sample
shows 8.15 × 10−9 S·cm−1 conductivity. The conductivity measurements indicated a plasma-enhanced ring-opening reaction mechanism of pyrrole.
相似文献
118.
Sandanaraj BS Bayraktar H Krishnamoorthy K Knapp MJ Thayumanavan S 《Langmuir : the ACS journal of surfaces and colloids》2007,23(7):3891-3897
An amphiphilic homopolymer scaffold has been used to bind to the protein, cytochrome c. This interaction is analyzed using cyclic voltammetry, native gel electrophoresis, UV-visible absorption, and circular dichroism spectroscopy. The polymer binds to cytochrome c with micromolar affinity and the association of polymer with cytochrome c leads to a structural change of the protein. This conformational change exposes the heme unit of the protein, which affords an opportunity to reversibly modulate its electron-transfer properties. We have also shown that the electrostatic binding of polymer to cytochrome c can be used to disrupt its interaction with its natural partner, cytochrome c peroxidase. 相似文献
119.
Purpose
To prospectively evaluate diffusion-weighted (DW) magnetic resonance (MR) imaging for differentiation of postobstructive consolidation from centrally located lung carcinomas by using apparent diffusion coefficients (ADCs).Materials and Methods
An institutional review board approved this study; informed consent was obtained from patients. Forty-nine consecutive patients (3 women, 46 men; mean age, 63.6 years; age range, 42–85 years) with lung carcinoma underwent DW MR imaging. Forty patients had central and nine patients had peripheral lung carcinomas. ADC of each lung carcinoma was calculated from DW MR images obtained with two different b values (0, 1000 s/mm2).In the final study group including 27 patients with central lung carcinoma accompanying distal lung consolidation (mean age, 67.2 years; 3 women, 24 men), ADCs of lung carcinomas were statistically compared among cytologic/histologic types and accompanying postobstructive consolidations. Unpaired t test was used for measurable variables with normal distribution, and Kruskal–Wallis variance analysis and Mann–Whitney U tests were used for the measurable variables without normal distribution.Results
There was no significant difference between mean ADC values of all types of carcinomas (P=.302) and also between mean ADC values of central (1.91 ± 0.7×10−3 mm2/s) and peripheral carcinomas (1.58 ± 0. 6×10−3 mm2/s) (P=.224). The mean ADC value for the masses of central lung carcinoma with postobstructive consolidations was 1.83 ± 0.75×10−3 mm2/s, and for consolidation was 2.50 ± 0.76×10−3 mm2/s. ADC of central carcinoma masses was significantly lower than that of postobstructive consolidations (P=.003).Conclusions
ADC values of central lung carcinoma masses appear to be lower than accompanying postobstructive consolidations. ADC values could be considered useful as a differentiating parameter among central lung carcinomas and accompanying postobstructive consolidations. 相似文献120.
Ahmet Bulut brahim Uar Okan Zafer Yeilel Hasan budak Halis
lmez Orhan Büyükgüngr 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(10):m526-m528
The title mononuclear [Cu(sq)(phen)2]·3H2O complex [sq is squarate (C4O4) and phen is 1,10‐phenanthroline (C12H8N2)] has been synthesized and the structure consists of a neutral mononuclear [Cu(sq)(phen)2] unit and three solvate water molecules. The CuII ion has distorted square‐pyramidal coordination geometry, comprised of one carboxylate O atom from a monodentate squarate ligand and four N atoms from two chelating phen ligands. An extensive three‐dimensional network of OW—H⋯O/OW hydrogen bonds, face‐to‐face π–π interactions between the 1,10‐phenanthroline aromatic rings and a weak π–ring interaction are responsible for crystal stabilization. 相似文献