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91.
V. Karpus A. Suchodolskis U.O. Karlsson L. Giovanelli S. Brühne 《Applied Surface Science》2006,252(15):5411-5414
We present a detailed analysis of the Mg 2p shallow core-levels measured on icosahedral single-grain ZnMgY, ZnMgHo, and ZnMgEr quasicrystals during a photoelectron microscopy study. The synchrotron radiation photoemission measurements were performed on in situ cleaved samples at a pressure of 10−10 mbar and at low temperature, typically 90-150 K. The Mg 2p photoemission lines are essentially broadened as compared to those of the Mg 2p spin-orbit doublet recorded on the Zn2Mg crystalline Laves phase. The broadening is associated to the coordination shifts of the Mg 2p level due to the inequivalent magnesium sites in the quasicrystalline lattice. The coordination shifts are calculated on the basis of i-ZnMg(Ho, Y) atomic structure data, recently determined from the pair distribution function analysis. The coordination shifts obtained are up to 0.2 eV. The Mg 2p experimental spectral intensity is nicely reproduced by a superposition of coordination-shifted Mg 2p spin-orbit doublets. 相似文献
92.
93.
Summary Flow injection analysis associated with a gradient mixing technique can be used for the determination of free acidity and total acidity (sum of free and bonded hydrogen ions) in a few microliters by reaction with suitable acid/base indicators and UV/VIS-detection. A rapid analysis of the two parameters in single raindrops in dependence on their size is possible [1]. 相似文献
94.
95.
F. Schümann S. Zavatarelli L. Gialanella U. Greife M. Junker D. Rogalla C. Rolfs F. Strieder H.P. Trautvetter 《The European Physical Journal A - Hadrons and Nuclei》1998,2(4):337-342
Abstact: The elastic scattering cross sections, σ (E,θ), for the systems He+Ta and He+W have been measured at θlab=165° and E
lab=76.1 keV to 3.988 MeV using targets with a thickness of a few atomic layers. The results are smaller than the results given
by the Rutherford scattering law, σR(E,θ), due to the effects of electron screening and can be described by σ(E,θ)/σR(E,θ)=(1+Ue/E)−1, where U
e is an atomic screening potential energy. The deduced average value, U
e=28 ± 3 keV, is consistent with the Moliére- and Lenz-Jensen-models as well as electron binding energies.
Received: 25 May 1998 相似文献
96.
H.O.U. Fynbo Y. Prezado J. Äystö U.C. Bergmann M.J.G. Borge P. Dendooven W. Huang J. Huikari H. Jeppesen P. Jones B. Jonson M. Meister G. Nyman M. Oinonen K. Riisager O. Tengblad I.S. Vogelius Y. Wang L. Weissman K.W. Rolander 《The European Physical Journal A - Hadrons and Nuclei》2002,15(1-2):135-138
97.
The general features of two series of sol-gel derived materials, designatedurethanesils (Ut), have been investigated by infrared and Raman spectroscopies with the goal of elucidating the chemical environment of
the Eu3+ cations.
The host frameworks of the two families of ormolytes studied have been represented by m-Ut(350) and d-Ut(300), where m stands
for mono, d stands for di, 350 and 300 are the average molecular weights of the organic precursors (poly(ethylene glycol)
methyl ether, PEGME, and poly(ethylene glycol), PEG, respectively).
The hybrid matrix of the mono-xerogels is composed by a siliceous backbone bonded by means of urethane linkages (-NHC (=O)O-)
to pendant methyl end capped oligopolymer chains with approximately 7 oxyethylene units, whereas that of the di-xerogels is
based on a siliceous network grafted through urethane groups to both ends of poly(oxyethylene) segments containing about 6
(OCH2CH2) repeat units.
Both classes of materials have been doped with europium triflate (Eu(CF3SO3)3). The doped samples have been identified by m-Ut(350)nEu(CF3SO3)3 and d-Ut(300)nEu(CF3SO3), where n is the molar ratio of (OCH2CH2) repeat units per Eu3+ ion. Materials with n ranging from ∞ to 5 have been analyzed. The spectral data obtained provide evidence that the cations
begin to coordinate to the ether oxygen atoms of the oligopolymer chains at n=40 in the mono-urethanesils and at n=10 in the
di-urethanesils. In mono-urethanesils samples with n>40 and in di-urethanesils materials with n>10, the Eu3+ coordinate exclusively to the carbonyl oxygen atoms of the urethane linkages.
Paper presented at the 8th EuroConference on Ionics, Carvoeiro, Algarve, Portugal, Sept. 16–22, 2001. 相似文献
98.
Summary A screening model (CISP) is presented for the calculation of maximum predicted concentrations from a single point source,
which is particularly useful in situations where on-site meteorological measurements are limited or unavailable. CISP utilizes
an analytical solution of the advection diffusion equation which is non-Gaussian in form. CISP performance in evaluating maximum
ground-level concentrations was compared with that of the Environmental Protection Agency (EPA) Regulatory PTPLU2 Gaussian
model. 相似文献
99.
100.
Sunto Generalizzando precedenti definizioni, si introduce il gruppo delle terne pitagoriche nell'anello di interi R di una fissata estensione finita K di Q. Sia S l'anello degli interi di K(i): si dà una descrizione esplicita di tali gruppi in termini delle unità di S, del suo gruppo di classi di ideali e di opportuni ideali primi di S.
Lavoro eseguito con il contribute del M.P.I. 相似文献
Lavoro eseguito con il contribute del M.P.I. 相似文献