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51.
We predict ultraslow collapse of “tubular image states” (TIS) on material surfaces. TIS are bound Rydberg-like electronic states formed at large distances (∼30 nm) from the surfaces of suspended circularly-symmetric nanowires, such as metallic C nanotubes. The states are formed in potential wells, resulting from a combination of the TIS-electron attraction to image charges in the nanotube and its centrifugal repulsion, caused by spinning around the tube. We demonstrate that TIS can collapse on the tube surface by passing their angular momentum l to circularly polarized flexural phonons excited in the tube. Our analysis shows that for highly detached TIS with l ? 6 the relaxation lifetimes are of the order of 10 ns-1 μs, while for l < 6 these lifetimes are reduced by several orders of magnitude. 相似文献
52.
Autler-Townes splitting (ATS) and electromagnetically induced transparency (EIT) both yield transparency in an absorption profile, but only EIT yields strong transparency for a weak pump field due to Fano interference. Empirically discriminating EIT from ATS is important but so far has been subjective. We introduce an objective method, based on Akaike's information criterion, to test ATS vs EIT from experimental data for three-level atomic systems and determine which pertains. We apply our method to a recently reported induced-transparency experiment in superconducting-circuit quantum electrodynamics. 相似文献
53.
N. Aissaoui F. Haas R. M. Freeman C. Beck A. Morsad B. Djerroud R. Čaplar G. A. Monnehan A. Hachem M. Youlal 《Zeitschrift für Physik A Hadrons and Nuclei》1994,348(3):237-238
The 16 O+ 15 N reaction products have been studied by the γ-ray detection method in the CM energy range 15.5 to 36.1 MeV and by the kinematical coincidence method at energies ranging from E CM =20.6 to 33.5MeV. The γ-ray yield excitation function of the 16O 3? inelastic channel shows the existence of resonant structures. Two structures with ~ 1.6 MeV width are observed in the large angle elastic scattering excitation function, they are correlated with the resonances seen in the inelastic channel. Angular momentum assignments were made from the elastic backward angular distributions. 相似文献
54.
M. Rotter B. Sedlák J. Englich P. Čížek M. Finger P. Malinský V. N. Pavlov 《Hyperfine Interactions》1987,34(1-4):303-306
The results of NMR/ON measurements on56'57'60Co isotopes in iron are presented. To avoid the uncertainties caused by local demagnetizing field inhomogenities the measurements on two cobalt isotopes in one sample have been carried out. The values of nuclear-factor ratios
57/
60 = 1.805 (20),
60/
56 = 0.761 (20),
56/
57 = 0.726 (20) and hyperfine anomalies5660 = -0.036 (10),60
57 = 0.017 (10) and5756 = 0.018 (10) have been calculated from the experimental results. 相似文献
55.
56.
57.
Petr P. Sharin Sofia P. Yakovleva Susanna N. Makharova Maria I. Vasilieva Vasilii I. Popov 《Composite Interfaces》2019,26(1):53-65
The structural-phase state of the contact zone and the factors that influence on the strength of diamond retention in the diamond carbide composites were determined. Composites were obtained by the new hybrid technology that eliminates the reheating of the metalized coating. The elaborated technology combines the thermal diffusion metallization of a diamond and the sintering by the scheme of self-dosed impregnation in a one-stage technological cycle. By the methods of electron microscopy, X-ray diffraction analysis, and Raman spectroscopy the structural and phase characteristics of the interphase boundary were investigated. The improvement of chemical and mechanical adhesion between the diamond and carbide matrix was obtained. It was shown that the specific productivity of the samples with a metalized diamond component is 39% higher than those without metallization. 相似文献
58.
Tomáš Čarný Dr. Ronan Rocaboy Dr. Antonin Clemenceau Prof. Dr. Olivier Baudoin 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(43):19142-19146
The 1,4-palladium shift strategy allows the functionalization of remote C−H bonds that are difficult to reach directly. Reported here is a domino reaction proceeding by C(sp3)−H activation, 1,4-palladium shift, and amino- or alkoxycarbonylation, which generates a variety of amides and esters bearing a quaternary β-carbon atom. Mechanistic studies showed that the aminocarbonylation of the σ-alkylpalladium intermediate arising from the palladium shift is fast using PPh3 as the ligand, and leads to the amide rather than the previously reported indanone product. 相似文献
59.
Dr. Lenka Štacková Marina Russo Dr. Lucie Muchová Vojtěch Orel Prof. Libor Vítek Dr. Peter Štacko Prof. Petr Klán 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(58):13184-13190
Carbon monoxide (CO) is an endogenous signaling molecule that controls a number of physiological processes. To circumvent the inherent toxicity of CO, light-activated CO-releasing molecules (photoCORMs) have emerged as an alternative for its administration. However, their wider application requires photoactivation using biologically benign visible and near-infrared (NIR) light. In this work, a strategy to access such photoCORMs by fusing two CO-releasing flavonol moieties with a NIR-absorbing cyanine dye is presented. These hybrids liberate two molecules of CO in high chemical yields upon activation with NIR light up to 820 nm and exhibit excellent uncaging cross-sections, which surpass the state-of-the-art by two orders of magnitude. Furthermore, the biocompatibility and applicability of the system in vitro and in vivo are demonstrated, and a mechanism of CO release is proposed. It is hoped that this strategy will stimulate the discovery of new classes of photoCORMs and accelerate the translation of CO-based phototherapy into practice. 相似文献
60.