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201.
Precipitate-forming chemical reactions have been studied in chemically cross-linked poly(vinyl alcohol) gel medium. One of the reactive components was incorporated into the gel, the other was allowed to diffuse into it. Depending on the experimental conditions the reaction-diffusion process often results in patterns of different type. Experiments performed in tubes and in thin layers were carried out in order to investigate the effects of various factors (cross-linking density, swelling degree as well as the concentrations of the outer and inner electrolytes) on the morphologies of the precipitate patterns. It was found that precipitation occurs not only in the Liesegang bands, but also between bands. Beside Liesegang-type structures, tree-like patterns have been observed, showing a characteristic periodicity in the density profile obtained by digitalized image analyses. 相似文献
202.
B. F. Matzanke U. Möllmann R. Reissbrodt V. Schünemann A. X. Trautwein 《Hyperfine Interactions》1998,112(1-4):123-128
Iron uptake of the 57Fe-siderophores ferricrocin, rhizoferrin and citrate in M. smegmatis was analyzed by in situ Mössbauer spectroscopy. Siderophore dependent uptake and metabolic utilization patterns of 57Fe were found. Rhizoferrin is accumulated in the organism and, therefore, represents a suitable candidate for the synthesis of novel siderophore-antibiotics conjugates. 相似文献
203.
Rüdiger Schultz Leen Stougie Maarten H. van der Vlerk 《Mathematical Programming》1998,83(1-3):229-252
In this paper we present a framework for solving stochastic programs with complete integer recourse and discretely distributed right-hand side vector, using Gröbner basis methods from computational algebra to solve the numerous second-stage integer programs. Using structural properties of the expected integer recourse function, we prove that under mild conditions an optimal solution is contained in a finite set. Furthermore, we present a basic scheme to enumerate this set and suggest improvements to reduce the number of function evaluations needed. 相似文献
204.
This paper deals with the inversive congruential method with power of two modulusm for generating uniform pseudorandom numbers. Statistical independence properties of the generated sequences are studied based on the distribution of triples of successive pseudorandom numbers. It is shown that there exist parameters in the inversive congruential method such that the discrepancy of the corresponding point sets in the unit cube is of an order of magnitude at leastm
–1/3. The method of proof relies on a detailed analysis of certain rational exponential sums. 相似文献
205.
206.
207.
An efficient algorithm for solving nonlinear programs with noisy equality constraints is introduced and analyzed. The unknown exact constraints are replaced by surrogates based on the bundle idea, a well-known strategy from nonsmooth optimization. This concept allows us to perform a fast computation of the surrogates by solving simple quadratic optimization problems, control the memory needed by the algorithm, and prove the differentiability properties of the surrogate functions. The latter aspect allows us to invoke a sequential quadratic programming method. The overall algorithm is of the quasi-Newton type. Besides convergence theorems, qualification results are given and numerical test runs are discussed. 相似文献
208.
R. Klein R. Grieser L. Hoog G. Huber I. Klaft P. Merz T. Kühl S. Schröder M. Grieser D. Habs W. Petrich D. Schwalm 《Zeitschrift für Physik A Hadrons and Nuclei》1992,342(4):455-461
We have performed for the first time precision spectroscopy on a coasting fast7Li+ ion beam in a storage ring. The ion beam moving with 6.4% speed of light was first electron cooled and then merged with two counterpropagating laser beams acting on two different hyperfine transitions sharing a common upper level (λ-system). One laser was frequency locked to thea 3 127J2 hfs frequency component established as a secondary frequency standard at 514 nm. The second laser was tuned over theλ-resonance, which was recorded relative to127J2 hfs components. This experiment is sensitive to the time dilation in fast moving frames and will lead to new limits for the verification of special relatively. The present status of the experiment and perspectives in accuracy are discussed. 相似文献
209.
210.
Fe2O3--V2O5 catalysts doped with Cs2SO4 (molar ratio: V:Fe:Cs=1:0.74:0.06) were found to be a rather inhomogeneous mixture of various crystalline and amorphous iron
vanadate phases. After calcination in air the catalyst was divided into three different parts which were analyzed separately
revealing the formation of FeVO4 in the top and bottom fraction of the crucible and Fe2V4O13 in the middle fraction. As compared to the well crystallized FeVO4 reference sample, the quadrupole splittings of FeVO4 in the Cs-doped catalysts were larger pointing to more distorted iron sites which were assumed to be responsible for high
catalytic selectivities. In contrast, the quadrupole splittings of FeVO4 in the less selective K- and Rb-doped Fe2O3--V2O5 catalysts were smaller. Additional components in the bottom fraction were also α-Fe2O3 and Fe1-xS. As indicated by the CEMS spectra the latter is located preferentially on the surface of the catalyst particles.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献