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61.
Güveli Şükriye Özdemir Namık Bal-Demirci Tülay Soylu Mustafa Serkan Ülküseven Bahri 《Transition Metal Chemistry》2019,44(2):115-123
Transition Metal Chemistry - Mixed ligand Ni(II) complexes were synthesized from triphenylphosphine and S-methyl- or S-ethyl-isothiosemicarbazone ligands derived from... 相似文献
62.
Structural Chemistry - Metal carbonyl complexes, which have been known as effective catalysts since early days, find use in many fields both directly and indirectly. Although the use of metal... 相似文献
63.
64.
A magnetic balance was used for measuring the susceptibility of metals and alloys, in an atmosphere of purified argon, up to 1800°c. Comparison of the susceptibilities of liquid Fe, Co and Ni gives information on the liquid state. The changes in the susceptibilities of Ge, Sn and Te on melting are typical of semi-metallic elements and semiconductors, but their behaviour differs according to the degree of symmetry in the solid state. 相似文献
65.
The beta dose response and Optically Stimulated Luminescence (OSL) signal stability characteristics of human tooth enamel deproteinated by hydrazine reagent under blue photon stimulation are reported. Removal of the protein organic component of tooth enamel resulted in a higher OSL sensitivity and slower fading of OSL signals. The effect of chemical sample preparation on the enamel sample sensitivity is discussed and further steps to make this deproteinization treatment suitable for in vitro dose reconstruction studies are suggested. 相似文献
66.
D. Kocheva G. Rainovski J. Jolie N. Pietralla A. Blazhev A. Astier R. Altenkirch S. Ansari Th. Braunroth M. L. Cortés A. Dewald F. Diel M. Djongolov C. Fransen K. Gladnishki A. Hennig V. Karayonchev J. M. Keatings E. Kluge J. Litzinger C. Müller-Gatermann P. Petkov M. Rudigier M. Scheck Ph. Scholz P. Spagnoletti M. Spieker C. Stahl R. Stegmann M. Stoyanova P. Thöle N. Warr V. Werner W. Witt D. Wölk K. O. Zell P. Van Isacker V. Yu. Ponomarev 《The European Physical Journal A - Hadrons and Nuclei》2017,53(9):175
67.
Michael Mehring Christian LÖW Ioannis Vrasidas Markus SchÜRmann Klaus Jurkschat 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1):311-318
Recent results are reported on the application of the novel O,C,O-coordinating pincer ligand {2,6-[P(O)(OEt)2]2-4-tert-Bu-C6H2} (A) for the synthesis of hypercoordinate organotin(IV) compounds ASnR3 (R = Ph, Cl), heteroleptic stannylenes ASnR (R = Cl, CH2SiMe3) and intramolecularly coordinated 1,2,5-oxaphosphastannolanes. 相似文献
68.
Four cone calix[4]arene-1,2-crown ethers each with two ionisable side arms containing dansyl groups are synthesised. The crown ether ring on the lower rim is varied from crown-4 to crown-5 with hydrogen or tert-butyl groups on the para position of the upper rim. Di(tetramethylammonium) salts of the di-ionised ligands are utilised for spectrofluorimetric titration experiments in MeCN. The influence of alkali metal, alkaline earth metal and selected transition and heavy metal (Co2+, Fe2+, Hg2+, Mn2+, Pb2+, Zn2+ and Fe3+) cations on the spectroscopic properties of the two dansyl groups linked to the lower rim of the conformationally locked, di-ionised calix[4]arene-1,2-crown ether frameworks is investigated by emission spectrophotometry. All of the metal cations induce red shifts in the emission spectra of the di-ionised ligands. The metal cations produce enhancement or quenching of the fluorescence emissions. Changes in the fluorescence emission as a function of the metal cation identity, the lower rim crown ether ring size and the absence or presence of upper rim tert-butyl groups are investigated. 相似文献
69.
Sonochemical synthesis and electrochemical characterization of α-nickel hydroxide: precursor effects
F. Sinem Ertaş Recep Kaş Uğur Ünal Özgür Birer 《Journal of Solid State Electrochemistry》2013,17(5):1455-1462
Sonochemical degradation of urea was employed to synthesize alpha-nickel hydroxide from different nickel salts. Utilization of ultrasound yielded products with properties significantly different than the products obtained by thermal degradation of urea. The effect of intercalating chloride, nitrate, acetate, and sulfate anions on morphology and electrochemical performance was studied. The sulfate-intercalated sample had the smallest interlayer spacing when obtained by the sonochemical method, contradicting all the previous thermal synthesis results. The specific capacitance trend also differed from the literature values, and the value for the sulfate-intercalated sample was larger than that of acetate- and nitrate-intercalated samples. Ultrasonic synthesis increased the specific capacitance of the sulfate-intercalated sample significantly. This sample was also the most reversible and had the highest charge efficiency. 相似文献
70.
采用MnCl2(或Mn(NO3)2)与teaH3和KSCN混合配体合成了1个七核锰配合物{K[MnⅡMnⅢ6(teaH)3(tea)3(NCS)6]}n(1)(teaH3=三乙醇胺),通过元素分析和红外光谱对其进行了表征,并通过X-单晶衍射确定了其晶体结构。1的阴离子由外围6个锰髥与1个中心Mn髤通过6个μ3-O键连接成1个类似车轮的环状结构。直流磁化率研究结果表明,该配合物具有较高的自旋基态(S=29/2),其磁性行为说明在高自旋的Mn髤和Mn髥之间存在铁磁性相互作用。 相似文献