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91.
Ya. P. Stradyn' G. Ya. Dubur Yu. I. Beilis Ya. R. Uldrikis A. É. Sausin' B. S. Chekavichus 《Chemistry of Heterocyclic Compounds》1975,11(11):1299-1303
Thirty-nine -substituted 1,4-dihydropyridine derivatives were subjected to electrochemical oxidation on a rotating platinum microelectrode in acetonitrile, and the Ep (E1/2) values were measured. A satisfactory linear correlation between the Ep and Taft. * constants of the substituents in the position was observed. A linear correlation of the Ep values with the 0, - and – constants also exists.See [1] for communication I.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1525–1529, November. 1975. 相似文献
92.
Institute of Catalysis, Academy of Sciences of the USSR. Central Institute of Physical Chemistry, Academy of Sciences of the German Democratic Republic. Translated from Zhurnal Strukturnoi Khimii, Vol. 30, No. 1, pp. 29–33, January–February, 1989. 相似文献
93.
94.
É. I. Ivanov G. D. Kalayanov I. M. Yaroshchenko 《Chemistry of Heterocyclic Compounds》1992,28(7):795-797
Possible routes for synthesis of 2-haloimidazo[4,5-e][1,4]diazepines are discussed. Conditions for chlorination differ for homologs of caffeine, theophylline, and theobromine. For the caffeine homolog, both the 2-chloroand 2,6,6-trichloro products are obtained depending on the synthetic conditionsTranslated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 955–958, July, 1992. 相似文献
95.
Kicha A. A. Kalinovskii A. I. Levina É. V. Rashkes Ya. B. Stonik V. A. Elyakov G. B. 《Chemistry of Natural Compounds》1985,21(3):332-337
From the glycoside fraction of the starfishPatiria pectinifera, after its desulfation, an artefactural glycoside has been obtained: 29(-L-arabinofuranosyloxy)-5-stigmastane-3,6,8,15,16-pentaol (I). The structure of (I) was shown by1H and13C NMR spectra and mass spectra and by acetylation and high-temperature hydrogenation.Pacific Ocean Institute of Bioorganic Chemistry, Far Eastern Scientific Center, Academy of Sciences of the USSR, Vladivostok. Institute of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 356–361, May–June, 1985. 相似文献
96.
N. K. Kochetkov B. A. Dmitriev A. V. Nikolaev N. É. Bairamova 《Russian Chemical Bulletin》1977,26(7):1480-1483
Conclusions Trisaccharide-D-glucopyranosyl-(14)--L-rhamnopyranosyl-(1 3)-D-galactose was synthesized by using, 2-O-isopropylidene-4,6-O-ethylidene--D-galactopyranose for producing 1 3-rhamnosylgalactose, linkage.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1609–1613, July, 1977. 相似文献
97.
Köhnlein H Purath A Klemp C Baum E Krossing I Stösser G Schnöckel H 《Inorganic chemistry》2001,40(19):4830-4838
A disproportionation process of a metastable AlCl solution with a simultaneous ligand exchange-Cl is substituted by N(SiMe(3))(2)-leads to a [Al(69)[N(SiMe(3))(2)](18)](3-) cluster compound that can be regarded as an intermediate on the way to bulk metal formation. The cluster was characterized by an X-ray crystal structural analysis. Regarding its structure and the packing within the crystal, this metalloid cluster with 4 times more Al atoms than ligands is compared to the [Al(77)N(SiMe(3))(2)](20)](2-) cluster that has been published four years ago. Although there is a similar packing density of the Al atoms in both clusters as well as in Al metal, the X-ray structural analysis shows significant differences in topology and distance proportions. The differences between these-at a first glance almost identical-Al clusters demonstrate that results of physical measuring, e.g., of nanostructured surfaces which carry supposedly identical cluster species, have to be interpreted with great caution. 相似文献
98.
99.
B. S. Chekavichus A. É. Sausin'sh G. Ya. Dubur 《Chemistry of Heterocyclic Compounds》1975,11(9):1077-1081
A number of new aryl esters of acetoacetic acid were obtained in the reaction of phenols with diketene in the presence of triethylamine. Reaction of the esters thus obtained with hexamethylenetetramine gave, for the first time, aryl esters of 1,4-dihydropyridine-3,5-dicarboxylic acid, the oxidation of which with chloranil gave the corresponding pyridines. 相似文献
100.
By means of Hartree—Fock energy variance calculations it has been shown that the specific electroncorrelation energy in extended cumulene molecules is approximately 0.3 eV/electron and the specific energy of interaction between -electron shells is 0.1 eV/electron.Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 29, No. 6, pp. 514–517, November–December, 1993. 相似文献