全文获取类型
收费全文 | 1512篇 |
免费 | 132篇 |
国内免费 | 4篇 |
专业分类
化学 | 1022篇 |
晶体学 | 13篇 |
力学 | 22篇 |
数学 | 377篇 |
物理学 | 214篇 |
出版年
2024年 | 5篇 |
2023年 | 20篇 |
2022年 | 25篇 |
2021年 | 39篇 |
2020年 | 47篇 |
2019年 | 65篇 |
2018年 | 52篇 |
2017年 | 40篇 |
2016年 | 95篇 |
2015年 | 106篇 |
2014年 | 90篇 |
2013年 | 248篇 |
2012年 | 149篇 |
2011年 | 139篇 |
2010年 | 79篇 |
2009年 | 57篇 |
2008年 | 52篇 |
2007年 | 29篇 |
2006年 | 44篇 |
2005年 | 27篇 |
2004年 | 12篇 |
2003年 | 16篇 |
2002年 | 22篇 |
2001年 | 13篇 |
2000年 | 16篇 |
1999年 | 11篇 |
1998年 | 8篇 |
1997年 | 11篇 |
1996年 | 12篇 |
1995年 | 8篇 |
1994年 | 7篇 |
1993年 | 5篇 |
1992年 | 10篇 |
1991年 | 6篇 |
1990年 | 3篇 |
1989年 | 7篇 |
1988年 | 3篇 |
1986年 | 3篇 |
1985年 | 9篇 |
1984年 | 10篇 |
1983年 | 4篇 |
1982年 | 4篇 |
1981年 | 8篇 |
1980年 | 4篇 |
1977年 | 4篇 |
1976年 | 3篇 |
1974年 | 2篇 |
1970年 | 2篇 |
1958年 | 2篇 |
1955年 | 2篇 |
排序方式: 共有1648条查询结果,搜索用时 15 毫秒
21.
22.
M. C. Villa-lojo E. Beceiro-GonzÁlez E. Alonso-Rodríguez D. Prada-Rodríguez 《International journal of environmental analytical chemistry》2013,93(3):377-389
Abstract The speciation of arsenic in the environment is among others controlled by reduction, methylation and oxidation processes and therefore influenced by the prevailing redox conditions. In this study we have analyzed sediments taken from La Coruña estuary in the north west of Spain. Inorganic (trivalent and pentavalent) and the organic (MMA and DMA) arsenic speciation is related to Eh, Fe and Mn load. The various of the arsenic species concentration and other parameters was analyzed at different depths in some of the sampling points. Low arsenic concentrations (1–10 μg·g–1) were found. In spite of oxidising conditions (Eh values between 31–96 mV), most of the samples showed a higher As(V) percentage than As (III). Principal component analysis was made to see a sample groups and the results showed that speciation depends on reducing conditions (Eh and Mn). 相似文献
23.
János B. Czirok Ákos Tarcsay Pál D. Mezei András Simon László Balázs 《Supramolecular chemistry》2013,25(10-12):722-728
The size limit of substituents allowing O-through-the-annulus rotation of substituted calix[4]arenes was further extended to the propargyloxy group in 24-propargyloxy-25,26,27-tris(N,N-dimethylcarbamoylmethoxy)-p-tert-butylcalix[4]arene by demonstrating its free but slow motion affording equilibrium between the partial cone and 1,2-alternate conformers. The effect of solvent and upper rim substituents R1 on the conformational inversion was investigated by means of 1H NMR. The rotational isomerisation of the parent (R1 = H) analogue could not unambiguously be detected. The experimental results were supported by comprehensive density functional theory studies. 相似文献
24.
Isidro Morales Juan E. Álvaro Miguel Urrestarazu 《Journal of Thermal Analysis and Calorimetry》2014,116(2):1033-1039
Thermography is a tool used in many scientific disciplines, including agriculture. This paper describes the application of thermography as a rapid diagnostic method of adequate watering. Two experiments were conducted. In experiment 1, Philodendron erubescens and Anthurium andraeum were transplanted to pots in a greenhouse in Almeria (Spain). The vegetative growth parameters of these plants were measured. In experiment 2, two areas of vegetative cover were established on green walls: one with a combination of aromatic plants and another with ornamental indoor plants. The thermographic images were recorded using a compact infrared camera, which had a spectral infrared range of 7.3–13 μm, microbolometer of 320 × 240 pixels, and the resolution was 0.01 °C at 30 °C. Three irrigation treatments were applied in both experiments, consisting of a control treatment (CT), a deficit irrigation [1/3 less volume, deficient irrigation (DI)] treatment, and an excess irrigation [1/3 greater volume, excess irrigation (EI)] treatment. In both experiments, the sample temperatures were recorded by thermography for each irrigation treatment. In experiment 1, the vegetative growth parameters were greater under CT than under DI or EI. The data of the reference thermographs over the leaves of the potted plants were significantly correlated with the superior growth parameters under the optimal irrigation treatment. A continuous vegetative canopy was formed on both of the green walls in experiment 2, and the average temperatures were correlated with the irrigation treatments in this experiment. The temperatures reflected in the reference thermographs allowed for the determination of the most appropriate irrigation treatment. These results suggest that thermography can be a useful method to provide an early diagnosis of water stress in potted plants and green walls. 相似文献
25.
26.
27.
28.
29.
Dr. Steffen Bähring Dr. Luis Martín‐Gomis Gunnar Olsen Prof. Dr. Kent A. Nielsen Dr. Dong Sub Kim Dr. Troels Duedal Prof. Dr. Ángela Sastre‐Santos Prof. Dr. Jan O. Jeppesen Prof. Dr. Jonathan L. Sessler 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(6):1958-1967
Supramolecular polymers are a class of macromolecules stabilized by weak non‐covalent interactions. These self‐assembled aggregates typically undergo stimuli‐induced reversible assembly and disassembly. They thus hold great promise as so‐called functional materials. In this work, we present the design, synthesis, and responsive behavior of a short supramolecular oligomeric system based on two hetero‐complementary subunits. These “monomers” consist of a tetrathiafulvalene‐functionalized calix[4]pyrrole (TTF‐C[4]P) and a glycol diester‐linked bis‐2,5,7‐trinitrodicyanomethylenefluorene‐4‐carboxylate (TNDCF), respectively. We show that when mixed in organic solvents, such as CHCl3, CH2ClCH2Cl, and methylcyclohexane, supramolecular aggregation takes place to produce short oligomers stabilized by hydrogen bonding and donor–acceptor charge‐transfer (CT) interactions. The self‐associated materials were characterized by 1H NMR and UV/Vis/NIR absorption spectroscopy, as well as by concentration‐ and temperature‐dependent absorption spectroscopy and dynamic light scattering (DLS) analyses of both the monomeric and oligomerized species. The self‐associated system produced from TTF‐C[4]P and TNDCF exhibits a concentration‐dependent aggregation behavior typical of supramolecular polymers. Further support for the proposed self‐assembly came from theoretical calculations. The fluorescence emitting properties of TNDCF are quenched under conditions that promote the formation of supramolecular aggregates containing TTF‐C[4]P and TNDCF. This quenching effect has been utilized as a probe for the detection of substrates in the form of anions (i.e., chloride) and nitroaromatic explosives (i.e., 1,3,5‐trinitrobenzene). Specifically, the addition of these substrates to mixtures of TTF‐C[4]P and TNDCF produced a fluorescence “turn‐on” response. 相似文献
30.
The lipase catalyzed resolution of trans-3,4-tetrahydrofuran and pyrrolidine bromohydrins by acylation or hydrolysis of their acylated derivatives has been studied. For both heterocycles, the best enantioselectivity was obtained using Candida antarctica lipase B as the catalyst in the hydrolytic processes. The enantiomerically pure bromohydrins are useful intermediates for the preparation of 3,4-fuctionalized cis-heterocycles. 相似文献