Modification of Poly(Ethylene Terephthalate) Track Membranes by Sorption of Poly(Ethylene Glycol)

Sorption of poly(ethylene glycol) on poly(ethylene terephthalate) track membranes was studied at different pH. The hydrophilic-hydrophobic properties of the intact membranes and those modified with poly(ethylene glycol) are compared. The membrane-aqueous human serum albumin and membrane-aqueous insulin adhesive tensions were determined for modified membranes. The competitive sorption of human serum albumin and poly(ethylene glycol) from aqueous solution on the track membranes is analyzed.     

A membrane bioreactor with immobilized proteinase

A procedure was developed for layer-by-layer immobilization of terrilytin proteolytic enzyme on track membranes and flat-membrane blocks. The hydrolysis of fibrinogen and casein was studied, and the possibility of using such a structure as an enzymatic bioreactor was demonstrated.     

Binuclear Triphenylantimony(V) Catecholates through N-Donor Linkers: Structural Features and Redox Properties

A series of binuclear triphenylantimony(V) bis-catecholato complexes 1–11 of the type (Cat)Ph₃Sb-linker-SbPh₃(Cat) was prepared by a reaction of the corresponding mononuclear catecholates (Cat)SbPh₃ with a neutral bidentate donor linker ligands pyrazine (Pyr), 4,4′-dipyridyl (Bipy), bis-(pyridine-4-yl)-disulfide (PySSPy), and diazobicyclo[2,2,2]octane (DABCO) in a dry toluene: Cat = 3,6-di-tert-butyl-catecholate (3,6-DBCat), linker = Pyr (1); PySSPy (2); Bipy (3); DABCO (4); Cat = 3,5-di-tert-butyl-catecholate (3,5-DBCat), linker = Bipy (5); DABCO (9); Cat = 4,5-(piperazine-1,4-diyl)-3,6-di-tert-butylcatecholate (pip-3,6-DBCat), linker = Bipy (6); DABCO (10); Cat = 4,5-dichloro-3,6-di-tert-butylcatecholate (4,5-Cl₂-3,6-DBCat), linker = Bipy (7); DABCO (11); and Cat = 4,5-dimethoxy-3,6-di-tert-butylcatecholate (4,5-(MeO)₂-3,6-DBCat), linker = Bipy (8). The same reaction of (4,5-Cl₂-3,6-DBCat)SbPh₃ with DABCO in an open atmosphere results in a formation of 1D coordination polymer {[(4,5-Cl₂-3,6-DBCat)SbPh₃·H₂O]·DABCO}_n (12). Bis-catecholate complex Ph₃Sb(Cat-Spiro-Cat)SbPh₃ reacts with Bipy as 1:1 yielding a rare macrocyclic tetranuclear compound {Ph₃Sb(Cat-Spiro-Cat)SbPh₃∙(Bipy)}₂ (13). The molecular structures of 1, 3, 4, 5, 8, 10, 12, and 13 in crystal state were established by single-crystal X-ray analysis. Complexes demonstrate different types of relative spatial positions of mononuclear moieties. The nature of chemical bonds, charges distribution, and the energy of Sb...N interaction were investigated in the example of complex 5. The electrochemical behavior of the complexes depends on the coordinated N-donor ligand. The coordination of pyrazine, Bipy, and PySSPy at the antimony atom changes their mechanism of electrooxidation: instead of two successive redox stages Cat/SQ and SQ/Cat, one multielectron stage was observed. The coordination of the DABCO ligand is accompanied by a significant shift in the oxidation potentials of the catecholate ligand to the cathodic region (by 0.4 V), compared to the initial complex.