全文获取类型
收费全文 | 127篇 |
免费 | 9篇 |
专业分类
化学 | 70篇 |
晶体学 | 1篇 |
数学 | 54篇 |
物理学 | 11篇 |
出版年
2023年 | 1篇 |
2022年 | 6篇 |
2021年 | 4篇 |
2020年 | 7篇 |
2019年 | 5篇 |
2018年 | 6篇 |
2017年 | 8篇 |
2016年 | 7篇 |
2015年 | 4篇 |
2014年 | 9篇 |
2013年 | 5篇 |
2012年 | 8篇 |
2011年 | 8篇 |
2010年 | 3篇 |
2009年 | 8篇 |
2008年 | 5篇 |
2007年 | 1篇 |
2006年 | 2篇 |
2005年 | 4篇 |
2003年 | 3篇 |
2001年 | 1篇 |
2000年 | 3篇 |
1999年 | 3篇 |
1998年 | 4篇 |
1997年 | 3篇 |
1996年 | 6篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1992年 | 2篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1937年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有136条查询结果,搜索用时 15 毫秒
1.
M. Samet G. Boiteux G. Seytre A. Kallel A. Serghei 《Colloid and polymer science》2014,292(8):1977-1988
The dielectric properties of composite materials consisting of a host matrix filled with spherical particles are investigated as a function of frequency by means of numerical calculations. Two different cases are analyzed: (a) composites with a conductive matrix and insulating fillers and (b) composites with an insulating matrix and conductive fillers. In both situations, dielectric dispersions due to interfacial polarization effects are observed in the dielectric spectra. In the present contribution, the characteristic frequencies of interfacial polarization effects are systematically analyzed in dependence on the volume fraction of the spherical fillers and on the conductivity values of the composite phases. The resulting scaling laws are discussed in detail. 相似文献
2.
Chirkova Zh. V. Kabanova M. V. Filimonov S. I. Samet A. V. Stashina G. A. Sudzilovskaya T. N. 《Russian Chemical Bulletin》2018,67(6):1083-1087
Russian Chemical Bulletin - Chlorination of 1-hydroxyindole-5,6-dicarbonitriles and 1-hydroxypyrrolo[3,4-f]indole-5,7(1H,6H)-diones with N-chlorosuccinimide afforded previously unknown... 相似文献
3.
Samet Solak Mehmet Karakuş 《Phosphorus, sulfur, and silicon and the related elements》2013,188(11):1054-1061
Abstract2,4-Bis(4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide (Lawesson’s reagent: LR) was reacted with 1,2:5,6-di-O-cyclohexylidene-α-D-glucofuranose and 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose in toluene and gave rise to crude dithiophosphonic acids. The crude dithiophosphonic acids were treated with excess triethylamine and the triethylammonium salts of dithiophosphonic acids (1) and (2) were isolated by crystallization method. Compounds 1 and 2 were characterized by elemental analysis, IR, and NMR (1H-, 13C- and 31P-) spectroscopies and mass spectrometry. In addition, NMR spectra, the electronic properties (the electronic chemical potential, electronegativity, chemical hardness and the global electrophilicity index) and NBO analysis of compound 2 have been calculated by using the Gaussian 16?W program. The electronic properties were calculated using Highest Occupied Molecular Orbital (HOMO) and Lowest Unoccupied Molecular Orbital (LUMO) energies by density functional method (DFT/B3LYP) at 6-31G(d,p) level. The HOMO and LUMO energies are ?5.9 and ?0.72?eV, respectively. The HOMO–LUMO energy difference is 5.18?eV and this value shows that compound 2 has a high stability and low reactivity. 相似文献
4.
5.
Bayrakdar Alpaslan Mert Samet Kasımoğulları Rahmi Bangaru Sathya Manivannan Prasath 《Research on Chemical Intermediates》2022,48(5):2087-2109
Research on Chemical Intermediates - Trifluoromethyl group containing pyrazole-3-carboxamide derivative is synthesized and the structure of the molecule (E3N5PC) has been verified by using FT-IR,... 相似文献
6.
Levoglucosenone reacts with α-aminoazoles to yield azolo[1,5-a]pyrimidine systems fused with a carbohydrate fragment. The reaction oocurs much more smoothly than in the case of other α,β-unsaturated
ketones. The reactions of levoglucosenone with β-dicarbonyl compounds (dimedone, barbituric acid) in the presence of a base
results in the pyran ring closure, which has never been observed earlier in reactions of β-dicarbonyl compounds with α,β-unsaturated
ketones under the conditions of basic catalysis. The structures of products were established by IR and NMR spectroscopy.
For Part 3, see Ref. 1.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 553–558, March, 1997. 相似文献
7.
8.
In this paper, we consider self-mappings defined on a metric space endowed with a finite number of graphs. Under certain conditions imposed on the graphs, we establish a new fixed point theorem for such mappings. The obtained result extends, generalizes and improves many existing contributions in the literature including standard fixed point theorems, fixed point theorems on a metric space endowed with a partial order and fixed point theorems for cyclic mappings. 相似文献
9.
We establish some results on coincidence and common fixed points for a twopair of multi-valued and single-valued maps in complete metric spaces.Presented theorems generalize recent results of Gordji et... 相似文献
10.
In this paper, we consider the solution to Wente's problem with the fractional Laplace operator (?Δ)α/2, where 0 < α < 2. We derive a Wente‐type inequality for this problem. Next, we compute the optimal constant in such inequality. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献