全文获取类型
收费全文 | 2559篇 |
免费 | 31篇 |
专业分类
化学 | 1754篇 |
晶体学 | 48篇 |
力学 | 88篇 |
数学 | 170篇 |
物理学 | 530篇 |
出版年
2022年 | 54篇 |
2021年 | 46篇 |
2020年 | 49篇 |
2019年 | 71篇 |
2018年 | 90篇 |
2017年 | 71篇 |
2016年 | 71篇 |
2015年 | 46篇 |
2014年 | 77篇 |
2013年 | 116篇 |
2012年 | 93篇 |
2011年 | 135篇 |
2010年 | 82篇 |
2009年 | 117篇 |
2008年 | 120篇 |
2007年 | 124篇 |
2006年 | 89篇 |
2005年 | 86篇 |
2004年 | 81篇 |
2003年 | 88篇 |
2002年 | 91篇 |
2001年 | 53篇 |
2000年 | 40篇 |
1999年 | 24篇 |
1998年 | 27篇 |
1997年 | 19篇 |
1996年 | 22篇 |
1995年 | 24篇 |
1994年 | 22篇 |
1993年 | 18篇 |
1992年 | 21篇 |
1991年 | 23篇 |
1990年 | 26篇 |
1989年 | 16篇 |
1987年 | 22篇 |
1986年 | 22篇 |
1985年 | 21篇 |
1984年 | 25篇 |
1982年 | 15篇 |
1978年 | 26篇 |
1977年 | 25篇 |
1976年 | 16篇 |
1975年 | 22篇 |
1974年 | 20篇 |
1973年 | 21篇 |
1972年 | 17篇 |
1971年 | 20篇 |
1970年 | 17篇 |
1968年 | 22篇 |
1967年 | 20篇 |
排序方式: 共有2590条查询结果,搜索用时 31 毫秒
1.
Valiullina Z. R. Ivanova N. A. Shitikova O. V. Miftakhov M. S. 《Russian Journal of Organic Chemistry》2019,55(8):1131-1135
Russian Journal of Organic Chemistry - Methyl (Z)-3-[(2R,3R,4S,5S)-5-(2-methoxy-2-oxoethyl)-3,4-(isopropylidenedioxy)tetrahydrofuran-2-yl]-prop-2-enoate was synthesized, and its intramolecular... 相似文献
2.
When dealing with simple phenols such as caffeic acid (CA) and ferulic acid (FA), found in a variety of plants, it is very important to have control over the most important factors that accelerate their degradation reactions. This is the first report in which the stabilities of these two compounds have been systematically tested by exposure to various different factors. Forced degradation studies were performed on pure standards (trans-CA and trans-FA), dissolved in different solvents and exposed to different oxidative, photolytic and thermal stress conditions. Additionally, a rapid, sensitive, and selective stability-indicating gas chromatographic-mass spectrometric method was developed and validated for determination of trans-CA and trans-FA in the presence of their degradation products. Cis-CA and cis-FA were confirmed as the only degradation products in all the experiments performed. All the compounds were perfectly separated by gas chromatography (GC) and identified using mass spectrometry (MS), a method that additionally elucidated their structures. In general, more protic solvents, higher temperatures, UV radiation and longer storage times led to more significant degradation (isomerization) of both trans-isomers. The most progressive isomerization of both compounds (up to 43%) was observed when the polar solutions were exposed to daylight at room temperature for 1 month. The method was validated for linearity, precision as repeatability, limit of detection (LOD) and limit of quantitation (LOQ). The method was confirmed as linear over tested concentration ranges from 1−100 mg L−1 (r2s were above 0.999). The LOD and LOQ for trans-FA were 0.15 mg L−1 and 0.50 mg L−1, respectively. The LOD and LOQ for trans-CA were 0.23 mg L−1 and 0.77 mg L−1, respectively. 相似文献
3.
The influence of interatomic distances on magnetic ordering in RMnSi compounds (R=La, Y, Sm, and Gd)
S. A. Nikitin T. I. Ivanova Yu. A. Ovchenkova M. V. Maslennikova G. S. Burkhanov O. D. Chistyakov 《Physics of the Solid State》2002,44(2):308-311
Magnetic ordering in the RMnSi (R=La, Y, Sm, and Gd) compounds is investigated. It is found that the type of magnetic ordering depends on the d Mn-Mn distance between manganese atoms inside the magnetic layers located in the planes perpendicular to the c axis. This inference is based on the results of studies performed with SmMnSi and GdMnSi compounds in which the distances between manganese atoms are close to the critical value d Mn-Mn that corresponds to the crossover between ferromagnetic and antiferromagnetic ordering in RMnSi compounds. The introduction of lanthanum and yttrium atoms into the rare-earth sublattice leads to an increase and a decrease in the unit cell size, respectively, and brings about magnetic phase transitions in the compounds under investigation. 相似文献
4.
Relying on reliability growth testing to improve system designis neither usually effective nor efficient. Instead it is importantto design in reliability. This requires models to estimate reliabilitygrowth in the design that can be used to assess whether goalreliability will be achieved within the target timescale forthe design process. Many models have been developed for analysisof reliability growth on test, but there has been much lessattention given to reliability growth in design. This paperdescribes and compares two models: one motivated by the practicalengineering process; the other by extending the reasoning ofstatistical reliability growth modelling. Both models are referencedin the recently revised edition of international standard IEC61164. However, there has been no reported evaluation of theirproperties. Therefore, this paper explores the commonalitiesand differences between these models through an assessment oftheir logic and their application to an industrial example.Recommendations are given for the use of reliability growthmodels to aid management of the design process and to informproduct development. 相似文献
5.
The numerical prediction of the fields of inelastic strains (the linear invariant of the tensor of inelastic strains) in thermoset polyester/marble filler composite plates is discussed. A uniformly distributed load is applied to the plates, which lie on a steel base. The strain fields are predicted by means of the boundary element method by using creep test data for the composites and the polyester matrix itself. Identical creep tests were performed for two ages of the materials (1 month and 13 years), which allowed evaluating the aging effect. The study is carried out in two stages. At the first stage, the application of the generalized Maxwell-Gurevich equation to the thermoset matrix/mineral filler composite is demonstrated. The model parameters determined from the experimental creep data is used for the second stage, where the state of inelastic strains in the plates is predicted by applying the boundary element method. The influence of composite formulation (filler content) and physical aging of the polyester matrix on the state of inelastic strains in the plates is shown.__________Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 41, No. 2, pp. 145–156, March–April, 2005. 相似文献
6.
Results of measuring the monochromatic sound field with a dipping probe in the deep ocean are presented. The sound speed profile in the region of measurements had a minimum at a depth of 1600 m. The experiment was carried out in the Atlantic Ocean with the use of two vessels separated by a distance of approximately four ray cycles (~240 km). The experimental data are compared with the calculations based on a new concept of the Brillouin waves for describing the vertical structure of the sound field produced by rays. It is shown that a satisfactory agreement between experiment and calculation can be achieved by fitting the parameters of the experiment. Such a procedure allows one to refine or even to determine the experimental conditions, which not are always known. The proposed method of calculation offers an opportunity for solving inverse problems of ocean acoustics. 相似文献
7.
The results of experimental investigation into the mechanical properties of blends of low-density polyethylene (LDPE) with chlorinated polyethylene (CPE) in tension are presented. The specimens of pure LDPE, CPE, and nine types of LDPE/CPE blends, with different content of components at 10 wt.% intervals, were examined. Data on the influence of blend composition on the tensile stress-strain diagram, elastic modulus, yield stress, breaking stress, and ultimate elongation are obtained. The results of investigations of creep are also reported. It is found that the creep compliance (the total current compliance minus the elastic compliance) obeys the power law of creep.__________Translated from Mekhanika Kompozitnykh Materialov, Vol. 41, No. 3, pp. 391–404, May–June, 2005. 相似文献
8.
T. M. Shneidman G. G. Adamian N. V. Antonenko S. P. Ivanova R. V. Jolos W. Scheid 《Physics of Atomic Nuclei》2003,66(2):206-217
Based on the dinuclear system concept, the role of bending vibrations in creation of the angular momentum of primary fission fragments is investigated. For 252Cf spontaneous fission, the angular momenta of the fragments are calculated as a function of the neutron multiplicity and compared with available experimental data. Different cluster compositions of the 252Cf fission modes at the scission point are considered. 相似文献
9.
O. Yu. Ivanova 《Journal of Mathematical Sciences》2007,147(5):7088-7097
A complete two-dimensional local field K of mixed characteristic with finite second residue field is considered. The existence
of a completely ramified extension L of K such that L is a standard field is assumed. It is proved that the rank of the quotient
U(1)K
2
top
K/TK, where TK is the closure of the torsion subgroup, is equal to the degree of the constant subfield of K over ℚp. I. B. Zhukov constructed a set of generators of this quotient in the case where K is a standard field. In this paper, two
natural generalizations of this set are considered, and it is proved that one of them generates the entire group and the other
generates its subgroup of finite index. Bibliography: 5 titles.
__________
Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 343, 2007, pp. 206–221. 相似文献
10.
E. L. Belokoneva A. G. Ivanova S. Yu. Stefanovich O. V. Dimitrova V. S. Kurazhkovskaya 《Crystallography Reports》2004,49(4):603-613
Crystals of new rare earth borates of the composition Ln[B6O9 (OH)3] (Ln = Sm-Lu), sp. gr. R3c are synthesized under hydrothermal conditions. Their crystal structures are determined on single crystals with Ln = Ho, Gd without preliminary determination of their chemical formulas. The polar anionic framework of the crystals consists
of BO3 triangles and BO4 tetrahedra and has wide channels along the threefold axis of the structure, which are similar to the channels along the a, b, and c axes in cubic Li4[B7O12]Cl boracite with Li conductivity. Rare earth atoms are arranged in the structure over the cubic F pseudolattice, whereas
the analogous positions in Li boracites are filled with Cl anions. The squared optical nonlinearity of the new crystals is
comparable with the nonlinearity of quartz, whereas the electrical conductivity in borates at 300°C exceeds 10−6 S/cm.
__________
Translated from Kristallografiya, Vol. 49, No. 4, 2004, pp. 681–691.
Original Russian Text Copyright ? 2004 by Belokoneva, Ivanova, Stefanovich, Dimitrova, Kurazhkovskaya. 相似文献