全文获取类型
收费全文 | 254篇 |
免费 | 5篇 |
国内免费 | 1篇 |
专业分类
化学 | 202篇 |
晶体学 | 2篇 |
力学 | 1篇 |
数学 | 5篇 |
物理学 | 50篇 |
出版年
2023年 | 3篇 |
2022年 | 1篇 |
2021年 | 1篇 |
2019年 | 1篇 |
2018年 | 4篇 |
2016年 | 7篇 |
2015年 | 4篇 |
2014年 | 10篇 |
2013年 | 24篇 |
2012年 | 11篇 |
2011年 | 10篇 |
2010年 | 6篇 |
2009年 | 5篇 |
2008年 | 15篇 |
2007年 | 14篇 |
2006年 | 12篇 |
2005年 | 15篇 |
2004年 | 11篇 |
2003年 | 11篇 |
2002年 | 13篇 |
2001年 | 3篇 |
2000年 | 5篇 |
1999年 | 3篇 |
1998年 | 4篇 |
1997年 | 6篇 |
1994年 | 1篇 |
1993年 | 6篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1988年 | 2篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1974年 | 16篇 |
1973年 | 2篇 |
1972年 | 3篇 |
1971年 | 2篇 |
1970年 | 1篇 |
1968年 | 1篇 |
1967年 | 2篇 |
排序方式: 共有260条查询结果,搜索用时 0 毫秒
1.
2.
3-Acetyl-2-oxazolone readily undergoes free-radical homopolymerization as well as telomerization with polyhalomethanes, in which low telomer formation is highly stereo- and regio-selective. 相似文献
3.
When aqueous solution of aluminium salt involving nitrate, chloride or sulfate was added into sodium fluoride solution, an immediate reaction occured to form cryolite-like precipitate. Examination into the resultant solution and analysis for the precipitate were carried out, leading to the fact that fluorine ion can substitute for bound water molecules around central Al+++ ion, but hardly for bound hydroxide and sulfate ion which should go or be “frozen”, as it is, into cryolite-like precipitate. These ligand substitution reaction seems to contribute to identification of ion species of aluminium in aqueous solution. 相似文献
4.
Oguchi T Tozuka Y Hanawa T Mizutani M Sasaki N Limmatvapirat S Yamamoto K 《Chemical & pharmaceutical bulletin》2002,50(7):887-891
The solid-state complexation between cholic acid (CA) and either methyl p-hydroxybenzoate (MPB) or ibuprofen (IBP) was investigated. Powder X-ray diffractometry, IR spectroscopy and thermal analysis suggested the complex formation between CA and MPB as well as between CA and IBP by co-grinding method. The stoichiometry of CA-MPB was 1 : 1 while that of CA-IBP was 2 : 1, reflecting the effect of guest size on complex formation. The guest compounds were assumed to be included in the channel of complexes formed by hydrogen bonds among CA molecules. 相似文献
5.
Sano S Takehisa T Ogawa S Yokoyama K Nagao Y 《Chemical & pharmaceutical bulletin》2002,50(9):1300-1302
Tetrasubstituted (Z)-alkenes were readily prepared through the Horner-Wadsworth-Emmons reactions of methyl 2-[bis(2,2,2-trifluoroethyl)phosphono]propionate with aryl alkyl ketones by employing Sn(OSO(2)CF(3))(2) and N-ethylpiperidine. 相似文献
6.
Yoshiyasu Ichikawa Yohei Matsukawa Mari Tamura Fumiyo Ohara Minoru Isobe Hiyoshizo Kotsuki 《化学:亚洲杂志》2006,1(5):717-723
A new method for the synthesis of urea‐linked disaccharides in aqueous media has been developed. The key feature of our approach is two strained Steyermark‐type gluco‐ and galactopyranosyl oxazolidinones. Each oxazolidinone is attached to a pyranose ring in a di‐equatorial trans‐annulation framework. Reaction of these oxazolidinones with 4‐aminohexopyranose in water proceeded smoothly to afford the urea‐tethered cellobiose and lactose analogues. The galactose‐type oxazolidinone proved to be more reactive than the glucose‐type, which is explained by the presence of an axial hydroxy group at C4 in the former. 相似文献
7.
8.
Tsutomu Kagiya Masatsugu Izu Masakazu Hatta Takehisa Matsuda Kenichi Fukui 《Journal of polymer science. Part A, Polymer chemistry》1967,5(5):1129-1135
N,N′-Dipropionylethylenediamine was synthesized by the ring-opening addition reaction of 2-ethyl-2-imidazoline with propionic acid at 220°C. By applying this reaction to polymerization, polyamides were synthesized by the ring-opening polyaddition reaction at 220°C. of 1,4-bis(imidazoline-2-yl)butane with adipic acid, succinic acid, sebacic acid, and terephthalic acid. The reaction product of 1,4-bis(imidazoline-2-yl)butane with adipic acid, which was proposed to be nylon 26, was compared with an authentic sample of nylon 26 and shown to possess a very similar infrared spectrum and melting point. 相似文献
9.
Terutaka Watanabe Takeshi Wada Masaaki Takehisa Sueo Machi 《Journal of polymer science. Part A, Polymer chemistry》1974,12(8):1619-1628
The heterogeneous polymerization of ethylene initiated by radiation in tert-butyl alcohol was studied. The polymerization was carried out in a 100-ml reactor at 25–100°C and pressures of 200–300 kg/cm2 in the presence of 50 ml of tert-butyl alcohol containing 7 wt-% water. The amounts of polymerized monomer, the average molecular weight of polymer formed, and the molecular weight distribution of polymer were measured at various stages of reaction and at various temperatures. The molecular weight distribution was found to be very much dependent on the reaction time and temperature. For the polymer formed at 50–60°C in the very early stages of reaction, the molecular weight distribution is unimodal, and in the intermediate stage a shoulder appears at a molecular weight higher than the first peak which increases as the polymerization proceeds; eventually a bimodal curve is formed. The bimodal distribution curves were analyzed to determine the fractions and average molecular weights of the each peak. On the basis of these data for the molecular weight distribution and kinetic behavior, a new scheme for the heterogeneous polymerization is proposed which indicates that the polymerization proceeds via propagating radicals in two different physical states, namely, loose and rigid states. 相似文献
10.
Takeshi Wada Terutaka Watanabe Masaaki Takehisa 《Journal of polymer science. Part A, Polymer chemistry》1971,9(9):2659-2672
The dependence of the dose rate on the rate of radiation-induced polymerization of ethylene in tert-butyl alcohol containing 5 vol-% water was studied. The reaction was carried out by use of a reactor with a capacity of 100 ml under the following conditions: pressure, 200 kg/cm2; temperature, 24 ± 3°C; dose rate, 3.7 × 104?1.6 × 105 rad/hr; amount of medium, 70 ml. The dose rate exponents for rate of the polymerization, the molecular weight, and the number of polymer chain were found to be about 0.8, ?0.1, and 0.9, respectively. These results were well explained with kinetic results (obtained by a novel analytical method) for the polymerization which contain both first-order and second-order terminations for the concentrations of propagating radical. The individual values of the rate constants in each elementary reaction were also obtained. 相似文献