全文获取类型
收费全文 | 2854篇 |
免费 | 148篇 |
国内免费 | 5篇 |
专业分类
化学 | 2343篇 |
晶体学 | 27篇 |
力学 | 23篇 |
数学 | 89篇 |
物理学 | 525篇 |
出版年
2023年 | 20篇 |
2022年 | 21篇 |
2021年 | 35篇 |
2020年 | 57篇 |
2019年 | 48篇 |
2018年 | 36篇 |
2017年 | 21篇 |
2016年 | 66篇 |
2015年 | 79篇 |
2014年 | 98篇 |
2013年 | 132篇 |
2012年 | 186篇 |
2011年 | 218篇 |
2010年 | 110篇 |
2009年 | 126篇 |
2008年 | 205篇 |
2007年 | 211篇 |
2006年 | 198篇 |
2005年 | 183篇 |
2004年 | 158篇 |
2003年 | 100篇 |
2002年 | 92篇 |
2001年 | 53篇 |
2000年 | 43篇 |
1999年 | 27篇 |
1998年 | 11篇 |
1997年 | 16篇 |
1996年 | 24篇 |
1995年 | 12篇 |
1994年 | 20篇 |
1993年 | 13篇 |
1992年 | 17篇 |
1991年 | 18篇 |
1990年 | 19篇 |
1989年 | 15篇 |
1988年 | 20篇 |
1987年 | 16篇 |
1985年 | 18篇 |
1984年 | 24篇 |
1983年 | 13篇 |
1982年 | 17篇 |
1981年 | 14篇 |
1980年 | 23篇 |
1979年 | 21篇 |
1978年 | 29篇 |
1977年 | 12篇 |
1976年 | 19篇 |
1975年 | 12篇 |
1974年 | 20篇 |
1973年 | 10篇 |
排序方式: 共有3007条查询结果,搜索用时 16 毫秒
1.
Takumi Watanabe Yuichiro Nishizawa Haruka Minato Dr. Chihong Song Prof. Dr. Kazuyoshi Murata Prof. Dr. Daisuke Suzuki 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(23):8934-8938
The three-dimensional structure of nanocomposite microgels was precisely determined by cryo-electron micrography. Several nanocomposite microgels that differ with respect to their nanocomposite structure, which were obtained from seeded emulsion polymerization in the presence of microgels, were used as model nanocomposite materials for cryo-electron micrography. The obtained three-dimensional segmentation images of these nanocomposite microgels provide important insights into the interactions between the hydrophobic monomers and the microgels, that is, hydrophobic styrene monomers recognize molecular-scale differences in polarity within the microgels during the emulsion polymerization. This result led to the formation of unprecedented multi-layered nanocomposite microgels, which promise substantial potential in colloidal applications. 相似文献
2.
Daisuke Matsuura 《Tetrahedron letters》2006,47(9):1371-1374
An efficient and stereodefined strategy is described for the asymmetric synthesis of a new styryllactone from the stem bark of Goniothalamus cardiopetalus, cardiobutanolide. The synthetic process is based on requisite manipulation of the functionalized bicyclic lactol-lactone intermediate incorporating the glucuronolactone-derived skeleton in a complete stereoselective manner. 相似文献
3.
4.
The turbulent flow in a compound meandering channel with a rectangular cross section is one of the most complicated turbulent flows, because the flow behaviour is influenced by several kinds of forces, including centrifugal forces, pressure‐driven forces and shear stresses generated by momentum transfer between the main channel and the flood plain. Numerical analysis has been performed for the fully developed turbulent flow in a compound meandering open‐channel flow using an algebraic Reynolds stress model. The boundary‐fitted coordinate system is introduced as a method for coordinate transformation in order to set the boundary conditions along the complicated shape of the meandering open channel. The turbulence model consists of transport equations for turbulent energy and dissipation, in conjunction with an algebraic stress model based on the Reynolds stress transport equations. With reference to the pressure–strain term, we have made use of a modified pressure–strain term. The boundary condition of the fluctuating vertical velocity is set to zero not only for the free surface, but also for computational grid points next to the free surface, because experimental results have shown that the fluctuating vertical velocity approaches zero near the free surface. In order to examine the validity of the present numerical method and the turbulent model, the calculated results are compared with experimental data measured by laser Doppler anemometer. In addition, the compound meandering open channel is clarified somewhat based on the calculated results. As a result of the analysis, the present algebraic Reynolds stress model is shown to be able to reasonably predict the turbulent flow in a compound meandering open channel. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
5.
Hiroto Kudo Nobuhito Ito Keiji Nakajima Masami Ochiai Tadatomi Nishikubo 《Journal of polymer science. Part A, Polymer chemistry》2007,45(19):4421-4429
The polyaddition of fluorine‐containing bis(epoxide)s and fluorine‐containing triazine di(aryl ether)s were examined to give the corresponding fluorine‐containing poly(cyanurate)s. It was observed that the synthesized fluoropolymers had good thermal stabilities and good film‐forming properties. The glass transition temperatures (Tg's) and refractive‐indices (nD's) of synthesized polymers were determined by differential scanning calorimetry and ellipsometry, respectively, and it was found that the values of Tg's and nD's were supported by their fluorine containing ratios and skeletons. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4421–4429, 2007 相似文献
6.
The running coupling and the Kugo-Ojima parameter of unquenched lattice Landau gauge are simulated and compared with the continuum
theory. Although the running coupling measured by the ghost and gluon dressing function is infrared suppressed, the running
coupling has a maximum of α0 ∼ 2 − 2.5 at around q = 0.5 GeV irrespective of the fermion actions (Wilson fermions and Kogut-Susskind (KS) fermions). The Kugo-Ojima parameter
c which saturated to about 0.8 in quenched simulations becomes consistent with 1 in the MILC configurations produced with the
use of the Asqtad action, after averaging the dependence on polarization directions caused by the asymmetry of the lattice.
The presence of the correction factor 1 + c
1/q
2 in the running coupling depends on the lattice size and the sea quark mass. In the large lattice size and small sea quark
mass, c
1 is confirmed of the order of a few GeV. The MILC configuration of a = 0.09 fm suggests also the presence of dimension-4 condensates with a sign opposite to the dimension-2 condensates. The
gluon propagator, the ghost propagator, and the running coupling are compared with recent pQCD results including an anomalous
dimension of fields up to the four-loop level. 相似文献
7.
Trifluoromethylation onto the tetrafluorophthalonitrile and tetrafluoroisophthalonitrile has been carried out using CF3TMS-CuI-KF system, and it was demonstrated that these trifluoromethylation enabled us to successfully construct di- and/or tri-trifluoromethylated benzonitriles via the decyanotrifluoromethylation. 相似文献
8.
A simple method to label oligosaccharides with a multifunctional fluorescent group was developed. Oligosaccharides were quantitatively labeled at their reducing termini with pyrene butanoic acid hydrazide. The pyrene-labeled oligosaccharides were successfully applied to fluorescence polarization measurements and ELISA at picomole quantity, which was not previously reached by other procedures. This labeling method should prove to be useful in a variety of aspects in glycobiology. 相似文献
9.
We have investigated the photoluminescence (PL) properties of trace amounts of Pr and Tb in single-crystal samples of yttria-stabilized zironia (YSZ), and found that Pr of the order of 10−6 mass% and Tb of the order of 10−5 mass% in YSZ can be detected by the PL spectroscopy. The PL spectra of the YSZ samples for the 280 nm excitation were comprised of several peaks and a broad emission. The peaks were attributed to transitions of Pr3+ and Tb3+ in the YSZ samples, whereas the broad emission seemed to be attributed to the yttria-associated oxygen vacancies. The peak intensities corresponded to the amounts of Pr and Tb in the YSZ samples, the amounts of which were analyzed by glow discharge mass spectrometry. In the PL excitation spectra, but not in the photoabsorption spectra, small peaks at 376 and 381 nm were observed, and were attributed to the transitions of Tb3+ in the YSZ samples. The results of the PL excitation spectra corresponding to the Pr3+ line emissions suggest that the charge transfer occurs between the YSZ and Pr ion in it. The trace amounts of these lanthanoids in YSZ would disturb the decay process of the photoinduced electrons to the yttria-associated oxygen vacancies. 相似文献
10.
Strained layer quantum well semiconductor optical amplifiers: Polarization insensitive amplification
M. Joma H. Hofukawa M. Nakajima M. Kawahara T. Kamijoh 《Fiber and Integrated Optics》1991,10(4):361-364
Polarization insensitive optical amplification was demonstrated in newly developed semiconductor optical amplifiers that have strained GalnAsP quantum well structures. We tailored the active region of the quaternary strained layer quantum well structure with a small biaxially tensile strain of 0.2% in the well layers for polarization insensitive operation. 相似文献