Fast Li+ Transport via Silica Network-Driven Nanochannels in Ionomer-in-Framework for Lithium Metal Batteries

For the development of all-solid-state lithium metal batteries (LMBs), a high-porous silica aerogel (SA)-reinforced single-Li⁺ conducting nanocomposite polymer electrolyte (NPE) is prepared via two-step selective functionalization. The mesoporous SA is introduced as a mechanical framework for NPE as well as a channel for fast lithium cation migration. Two types of monomers containing weak-binding imide anions and Li⁺ cations are synthesized and used to prepare NPEs, where these monomers are grafted in SA to produce SA-based NPEs (SANPEs) as ionomer-in-framework. This hybrid SANPE exhibits high ionic conductivities (≈10⁻³ S cm⁻¹), high modulus (≈10⁵ Pa), high lithium transference number (0.84), and wide electrochemical window (>4.8 V). The resultant SANPE in the lithium symmetric cell possesses long-term cyclic stability without short-circuiting over 800 h under 0.2 mA cm⁻². Furthermore, the LiFePO₄|SANPE|Li solid-state batteries present a high discharge capacity of 167 mAh g⁻¹ at 0.1 C, good rate capability up to 1 C, wide operating temperatures (from −10 to 40 °C), and a stable cycling performance with 97% capacity retention and 100% coulombic efficiency after 75 cycles at 1 C and 25 °C. The SANPE demonstrates a new design principle for solid-state electrolytes, allowing for a perfect complex between inorganic silica and organic polymer, for high-energy-density LMBs.     

The role of inorganic nanoparticle on ion conduction of epoxy-based solid polymer electrolytes for lithium-ion batteries

Abstract

Recently, extensive efforts have focused on the development of solid polymer electrolytes (SPEs) requiring high mechanical performance without sacrificing ion conductivity. To develop such a SPE, we incorporate robust silica mesoporous particles (SMP) into the epoxy-based SPEs, and increasing the SMP content raises the glass transition temperature of the SPEs. This enables to increase the mechanical properties of the SPEs, supported by the microstructural investigation showing a highly compact structure. Ionic conductivities of these SPEs follow Vogel temperature dependence, and increasing the silica nanoparticle content leads to a slight decrease in the conductivity, consistent with the dielectric response investigation.     

Screening, Gene Sequencing and Characterising of Lipase for Methanolysis of Crude Palm Oil

Staphylococcus sp. WL1 lipase (LipFWS) was investigated for methanolysis of crude palm oil (CPO) at moderate temperatures. Experiments were conducted in the following order: searching for the suitable bacterium for producing lipase from activated sludge, sequencing lipase gene, identifying lipase activity, then synthesising CPO biodiesel using the enzyme. From bacterial screening, one isolated specimen which consistently showed the highest extracellular lipase activity was identified as Staphylococcus sp. WL1 possessing lipFWS (lipase gene of 2,244 bp). The LipFWS deduced was a protein of 747 amino acid residues containing an α/β hydrolase core domain with predicted triad catalytic residues to be Ser474, His704 and Asp665. Optimal conditions for the LipFWS activity were found to be at 55 °C and pH 7.0 (in phosphate buffer but not in Tris buffer). The lipase had a K _M of 0.75 mM and a V _max of 0.33 mM?min^?1 on p-nitrophenyl palmitate substrate. The lyophilised crude LipFWS performed as good as the commonly used catalyst potassium hydroxide for methanolysis of CPO. ESI-IT-MS spectra indicated that the CPO was converted into biodiesel, suggesting that free LipFWS is a worthy alternative for CPO biodiesel synthesis.     

Adaptive wire bow-tie antenna for GPR applications

In this paper, the basic design of an adaptive ground penetrating radar antenna is introduced. The antenna is able to adapt its input impedance to a variation in the antenna elevation and soil type to keep reflections at the antenna's terminal minimum. As a result, energy transfer from the generator to the antenna is maximized, which in turn maximizes the energy radiated by the antenna into the ground for different antenna elevations and soil types. The antenna is based on a wire bow-tie structure with variable flare angle for adjusting the antenna's input impedance. The flare angle variation is realized by short-circuiting the gaps separating the wires from the feed point of the antenna, for which electronic switching devices such as PIN diodes could be used to allow fast and convenient control of the antenna's flare angle.     

Phytochemical Profile of Antibacterial Agents from Red Betel Leaf (Piper crocatum Ruiz and Pav) against Bacteria in Dental Caries

Based on data from The Global Burden of Disease Study in 2016, dental and oral health problems, especially dental caries, are a disease experienced by almost half of the world’s population (3.58 billion people). One of the main causes of dental caries is the pathogenesis of Streptococcus mutans. Prevention can be achieved by controlling S. mutans using an antibacterial agent. The most commonly used antibacterial for the treatment of dental caries is chlorhexidine. However, long-term use of chlorhexidine has been reported to cause resistance and some side effects. Therefore, the discovery of a natural antibacterial agent is an urgent need. A natural antibacterial agent that can be used are herbal medicines derived from medicinal plants. Piper crocatum Ruiz and Pav has the potential to be used as a natural antibacterial agent for treating dental and oral health problems. Several studies reported that the leaves of P. crocatum Ruiz and Pav contain secondary metabolites such as essential oils, flavonoids, alkaloids, terpenoids, tannins, and phenolic compounds that are active against S. mutans. This review summarizes some information about P. crocatum Ruiz and Pav, various isolation methods, bioactivity, S. mutans bacteria that cause dental caries, biofilm formation mechanism, antibacterial properties, and the antibacterial mechanism of secondary metabolites in P. crocatum Ruiz and Pav.     

RC-loaded bow-tie antenna for improved pulse radiation

In this paper, a loading technique for improving pulse radiation from bow-tie antennas is introduced. This technique allows transmission of short transient pulses with very small late-time ringing and relatively high radiation efficiency. It makes use of a combination of a constant resistive loading along the antenna and a capacitive loading with linearly increasing reactance toward the antenna ends. The constant resistive loading is applied using volumetric microwave absorbers to cover one side of the antenna and the linear capacitive loading is realized by constructing narrow slots on the antenna surface. Relatively high radiation efficiency is achieved by choosing the location of the slot nearest to the feed point in such a way that radiation from it combines constructively with radiation from the feed point. Using a 0.8-ns monocycle for excitation, the technique results in a level of late-time ringing of lower than -40 dB and at the same time the peak value of the transmitted pulse is 54% higher than that of the same antenna without loading.     

Cisplatin-modified isonicotinic acid as a potential linker in bio-MOFs: synthesis and characterization

Research on Chemical Intermediates - The platinum derivative cisplatin is widely used against many types of cancers effectively. However, cisplatin has limitations such as toxicity, resistances,...     

Characterization of Key Intermediates in a Complex Organocatalytic Cascade Reaction Using Mass Spectrometry

Chemical scrabble : Mechanistic studies of complex organocatalytic cascade reactions are challenging owing to the presence of many species involved. Electrospray ionization mass spectrometry provides details about a one‐pot quadruple organocatalytic cascade reaction, and allows detailed characterization of the reaction and its key intermediates.

     

Numerical and experimental analysis of circular-end wire bow-tie antennas over a lossy ground

This paper presents a numerical and experimental analysis of a wire bow-tie antenna situated horizontally near a lossy ground. The antenna is basically an array of identical wire dipoles having a common feed point and equal angular separation between two neighboring wires. This antenna is particularly suitable for ultrawide-band applications as it possesses a wideband property and allows a simple realization of resistive loading. It also provides a possibility to easily vary the antenna flare angle for the purpose of antenna matching or to adjust its footprint. In this work a theoretical model of the antenna is developed and verified experimentally. The wires are modeled as a tape-like structure by triangular patches and the antenna is analyzed using a mixed-potential integral equation formulation. Moreover, time-domain solutions are computed using the Fourier transformation, and a time-window technique is employed to calculate the antenna characteristic impedance. Using the model a comprehensive analysis of the antenna performance is carried out.     

Fluorescent Flippers: Small-Molecule Probes to Image Membrane Tension in Living Systems

Flipper probes have been introduced as small molecule fluorophores to image physical forces, that is, membrane tension in living systems. Their emergence over one decade is described, from evolution in design and synthesis to spectroscopic properties. Responsiveness to physical compression in equilibrium at the ground state is identified as the ideal origin of mechanosensitivity to image membrane tension in living cells. A rich collection of flippers is described to deliver and release in any subcellular membrane of interest in a leaflet-specific manner. Chalcogen-bonding cascade switching and dynamic covalent flippers are developed for super-resolution imaging and dual-sensing of membrane compression and hydration. Availability and broad use in the community validate flipper probes as a fine example of the power of translational supramolecular chemistry, moving from fundamental principles to success on the market.