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1.
Linares-Barranco B. Serrano-Gotarredona T. Ramos-Martos J. Ceballos-Caceres J. Mora J.M. Linares-Barranco A. 《IEEE transactions on circuits and systems. I, Regular papers》2004,51(4):649-663
We present a very-large-scale integration continuous-time sinusoidal operational transconductance amplifiers quadrature oscillator fabricated in a standard double-poly 0.8-/spl mu/m CMOS process. The oscillator is tunable in the frequency range from 50 to 130 MHz. The two phases produced by the oscillator show a low-quadrature phase error. A novel current-mode amplitude control scheme is developed that allows for very small amplitudes. Stability of the amplitude control loop is studied as well as design considerations for its optimization. Experimental results are provided. 相似文献
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The effect of 4,6-O-benzylidene acetals, 4,6-O-phenylboronate esters, and 4,6-O-polystyrylboronate esters on the stereoselectivity of couplings to galacto-, gluco-, and mannopyranosyl thioglycosides, otherwise protected with benzyl ethers, has been investigated by the benzenesulfinyl piperidine/trifluoromethanesulfonic anhydride (BSP), diphenyl sulfoxide/trifluoromethanesulfonic anhydride (Ph(2)SO), and N-iodosuccinimide/trimethylsilyl trifluoromethanesulfonate (NIS/TMSOTf) methods. The BSP and Ph(2)SO methods give comparable results in all three systems whereas the NIS method affords significantly different stereoselectivities in both the gluco and manno, but not the galacto series. The benzylidene acetal and boronate esters influence the stereochemistry in a similar manner in the beta-selective manno series and the alpha-selective galacto series but show significant differences with the glucose donors. The differences between the glucose, galactose, and mannose series reflect the established differences in reactivity and, especially for mannose, those in the anomeric effect and are best interpreted in terms of changes in the relative energetics between the alpha- and beta-covalent triflate intermediates and the various contact ion pairs with which they are necessarily in equilibrium. 相似文献
5.
G. Marin S. M. Wasim G. Sánchez Pérez P. Bocaranda A. E. Mora 《Journal of Electronic Materials》1998,27(12):1351-1357
A new method to grow single crystals with stoichiometry close to 1:1:2 of CuInTe2, an important member of the Cu-III-VI2 family of semiconductors is described. This consists of tellurization in the liquid phase of stoichiometric Cu and In and
later solidification under directional freezing. It is found from energy dispersive spectroscopy that the ingots obtained
with the evaporation temperature (Tt) of Te at 590 and 635°C were very close to the ideal stoichiometry 1:1:2. Samples of all ingots obtained with Tt between 530 and 690°C, as studied by x-ray and differential thermal analysis, were of single phase having chalcopyrite structure
and p-type conductivity. Optical and electrical characterization of different ingots were made. The acceptor ionization energy
EA and the density of states effective mass m
p
*
of the holes are estimated from the temperature dependence of the hole concentration p in samples of different ingots. m
p
*
= (0.78 ± 0.02) me agrees quite well with the reported value. From a combined analysis of the variation of EA with p1/3 and the knowledge of molecularity and valence stoichiometry of each sample, it is established that the shallow acceptor level
observed in different samples with EA (0) ⋍ 30 meV is due to VIn. 相似文献
6.
R.?CombescotEmail author C.?Mora 《The European Physical Journal B - Condensed Matter and Complex Systems》2005,44(2):189-202
We explore the nature of the transition to the Fulde-Ferrell-Larkin-
Ovchinnikov superfluid phases
in the low temperature range in two dimensions, for the simplest
isotropic BCS model. This is done by applying the Larkin-Ovchinnikov
approach to this second order transition. We show that there is a
succession of transitions toward ever more complex order parameters
when the temperature goes to zero. This gives rise to a cascade with, in
principle, an infinite number of transitions. Except for one case, the
order parameter at the transition is a real superposition of cosines with
equal weights. The directions of these wavevectors are equally spaced
angularly, with a spacing which goes to zero when the temperature goes
to zero. This singular behaviour in this T = 0 limit is deeply linked to
the two-dimensional nature of the problem. 相似文献
7.
Adrián Serrano Mora Sean T. McBeath Clément A. Cid Michael R. Hoffmann Nigel J.D. Graham 《Current Opinion in Electrochemistry》2022
While diamond electrodes have been commonly used to generate ?OH to treat a variety of persistent water and wastewater micropollutants, mass transfer limitations and the non-selective, short-lived nature of the ?OH restrict the degradation to the solution at, or near, the electrode surface. However, diamond electrodes can generate oxidizing species that facilitate micropollutant degradation in the bulk water solution. These include persulfate, sulfate radicals, peroxodiphosphate, ferrate, permanganate, reactive chlorine species, hydrogen peroxide, and ozone, which have been reported during electrochemical treatment of water with diamond electrodes. Although still restricted to specialized applications, recent studies, summarized in this review, have proven the electrogeneration of these additional oxidant species to be effective. They have shown the adaptability and potential of diamond electrode-based water treatment to mitigate the presence of micropollutants in water. 相似文献
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Yu-Hui Huang Zhuo-Mei Li Herbert Mora Wetz 《Journal of polymer science. Part A, Polymer chemistry》1985,23(3):795-799
Poly(vinyl benzyl chloride) latex was reacted with ethanolamine and with amine terminated chain molecules containing up to 33 ethylene oxide residues. The kinetics of these reactions were essentially independent of the length of the chain carrying the amine group. An increasing length of the chains bound to the surface of the latex particles produced an increasing latex stabilization. 相似文献
10.
Elizabeth A. Jaramillo Mauro S. Ferreira Santos Aaron C. Noell Maria F. Mora 《Electrophoresis》2021,42(19):1956-1964
In situ missions of exploration require analytical methods that are capable of detecting a wide range of molecular targets in complex matrices without a priori assumptions of sample composition. Furthermore, these methods should minimize the number of reagents needed and any sample preparation steps. We have developed a method for the detection of metabolically relevant inorganic and organic anions that is suitable for implementation on in situ spaceflight missions. Using 55 mM acetic acid, 50 mM triethylamine, and 5% glycerol, more than 21 relevant anions are separated in less than 20 min. The method is robust to sample ionic strength, tolerating high concentrations of background salts (up to 900 mM NaCl and 300 mM MgSO4). This is an important feature for future missions to ocean worlds. The method was validated using a culture of Escherichia coli and with high salinity natural samples collected from Mono Lake, California. 相似文献