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(TbBi)3GaxFe5-xO12薄膜/(TbYbBi)3Fe5O12晶体复合结构的生长和在光通信波段的磁光性能 总被引:1,自引:1,他引:0
用助熔剂法生长出掺Bi复合稀土铁石榴石晶体((TbYbBi)3Fe5O12),用(TbYbBi)3Fe5O12替代传统的无磁性Gd3Ga5O12晶体作基底液相外延掺Bi稀土铁鎵石榴石薄膜((TbBi)3GaXFe5-XO12).测量了Tb0.87Yb1.62Bi0.51Fe5O12晶体和Tb2.43Bi0.57Ga0.12Fe4.88O12薄膜/Tb0.87Yb1.62Bi0.51Fe5O12晶体复合结构材料在光通信波段(波长λ=1500-1620nm)处的光透射谱(T)、饱和磁化强度(Ms,0.5×106A/m)、法拉第旋转温度系数(FTC,5×10-5/K)和法拉第旋转波长系数(FWC,0.05%/nm).所得结果表明:Tb2.43Bi0.57Ga0.1Fe4.9O12薄膜/Tb0.87Yb1.62Bi0.51Fe5O12晶体复合结构材料的综合性能适用于宽带和温度稳定的光隔离器及其他光通讯器件. 相似文献
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以B i2O3/B2O3为主助熔剂和加速坩埚旋转技术改进的高温助熔剂法生长出掺B i复合稀土铁石榴石TbxYbyB i3-x-yFe5O12单晶.研究了该系列晶体材料在近红外通信波段(波长λ=1500~1620nm)处的磁光性能,其中Tb0.91Yb1.38B i0.71Fe5O12单晶有大的比法拉第旋转角-1671.2°/cm(λ=1550nm,25℃),小的饱和磁化强度(4πM s=0.6×106A/m),小的法拉第旋转温度系数(FTC=3.92×10-5/K,λ=1550nm),在λ=1500~1620nm波长范围的法拉第旋转波长系数FWC(25℃)为0.009%/nm,在λ=1500~1620nm波长和25~95℃温度范围内反向隔离度>40dB.综合性能表明TbxYbyB i3-x-yFe5O12适合用作光通讯系统中宽带和温度稳定的高性能光隔离器的法拉第转子材料. 相似文献
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57Fe Mössbauer spectrometry: A powerful technique to analyze the magnetic and phase characteristics in RE–Fe–B permanent magnets 下载免费PDF全文
This review summarizes the recent advances on the application of 57Fe M?ssbauer spectrometry to study the magnetic and phase characteristics of Nd–Fe–B-based permanent magnets. First of all, the hyperfine structures of the Ce2Fe14B,(Ce,Nd)2Fe14B and MM2Fe14B phases are well-defined by using the model based on the Wigner-Seitz analysis of the crystal structure. The results show that the isomer shift δ and the quadrupole splitting ?EQ of those 2:14:1 phases show minor changes with the Nd content, while the hyperfine field Bhfincreases monotonically with increasing Nd content and its value is influenced by the element segregation and phase separation in the 2:14:1 phase. Then, the hyperfine structures of the low fraction secondary phases are determined by the 57Fe M?ssbauer spectrometry due to its high sensitivity. On this basis,the content, magnetic behavior, and magnetization of the REFe2 phase, the amorphous grain boundary(GB) phase, and the amorphous worm-like phase, as well as their effects on the magnetic properties, are systematically studied. 相似文献
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用INDO系列方法研究C60(OH)88种异构体的结构和光谱,探讨羟基不同加成位置对异构体稳定性的影响,表明8个羟基以1,2-加成方式加在C60的五元环与六元环相邻棱上所得的异构体最稳定, 生成热比次稳定异构体低25eV,故实验室合成的C60(OH)8主要以这种构型存在。以优化构型为基础,计算了8种异构体的UV谱,对电子跃迁进行理论指认,讨论产物UV谱带红移的原因,对反应机理进行探讨,并对C60R8(R=F,OH,Cl)的某些性质进行了对比。 相似文献
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用 INDO系列方法研究 C60 (OH) 88种异构体的结构和光谱 ,探讨羟基不同加成位置对异构体稳定性的影响 ,表明 8个羟基以 1,2 -加成方式加在 C60 的五元环与六元环相邻棱上所得的异构体最稳定 ,其生成热比次稳定异构体低 2 5 e V,故实验室合成的 C60 (OH) 8主要以这种构型存在。以优化构型为基础 ,计算了 8种异构体的 UV谱 ,对电子跃迁进行理论指认 ,讨论产物 UV谱带红移的原因 ,对反应机理进行探讨 ,并对 C60 R8(R=F,OH,Cl)的某些性质进行了对比。 相似文献
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TiC—Fe3C对铸铁激光熔敷层耐磨性的影响 总被引:4,自引:0,他引:4
采用铁基熔敷材料 ,在铸铁激光熔敷层内得到内生 Ti C.研究了内生 Ti C和 Fe3 C对熔敷层耐磨性的影响 ,分析了内生 Ti C数量及体积分数对熔敷层磨损表面形貌及磨损质量损失的影响规律 .结果表明 ,通过引入内生 Ti C可以显著改善铸铁表面激光熔敷层的抗磨性能 ,这主要是由于 Ti C硬度很高 ,且具有弥散强化及细晶强化作用所致 相似文献
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Magnetic transitions and magnetoresistance effect of the HfFe_6Ge_6-type Y_{0.9}La_{0.1}Mn_6Sn_6 compound have been investigated in the temperature range of 5-380K. The sample displays antiferromagnetic behaviour in the whole temperature range below Néel temperature T_N=309K. The metamagnetic transition from antiferromagnetism to ferromagnetism can be induced by an applied field. The metamagnetic transition field decreases monotonically from 2T at 5K to 0.4T at 300K. The giant magnetoresistance effect is observed with the metamagnetic behaviour, such as -10.4% at 245K under a field of 5T. 相似文献