Thermal behavior of metallodendrimers possessing bis(terpyridinyl)Ru(II) connectivity and different surface functionality

A series of metallodendrimers, assembled by means of bis(terpyridinyl)Ru^(II) connectivity on poly(propylene imine) dendrimer scaffolds, with homogeneous or heterogeneous surfaces, were prepared. Differential scanning calorimetry and thermogravimetric analysis were used to determine their thermal behavior, glass‐transition temperatures, and the decomposition kinetics and temperatures; no synergy effects for these properties were observed for the heterogeneously surfaced constructs in contrast to the corresponding homogeneously coated materials, which exhibited different values depending on their surface functionalities. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1487–1495, 2004     

Background-free,fast protein staining in sodium dodecyl sulfate polyacrylamide gel using counterion dyes,zincon and ethyl violet

A background-free, fast protein staining method in polyacrylamide gel electrophoresis using an acidic dye, zincon (ZC) and a basic dye, ethyl violet (EV) is described. It is based on the counterion dye staining technique that employs two oppositely charged dyes to form an ion-pair complex in staining solution. The selective binding of free dye molecules to proteins in acidic solution produces bluish violet-colored bands. It is a rapid and end-point staining procedure, involving only fixing and staining steps that are completed in 1-1.5 h. The detection limit of this method is 8-15 ng of protein that is comparable to the sensitivity of the colloidal Coomassie Brilliant Blue G (CBBG) stain. Due to its sensitivity and speed, this stain may be more practical than any other dye-based stains for routine laboratory purposes.     

The Tolman length: is it positive or negative?

By means of a large-scale molecular dynamics simulation, we show that the Tolman length, although positive, is much smaller in magnitude than previously reported. We found that the range of interparticle interaction can significantly affect the magnitude of the Tolman length. When the range of interaction is longer than five molecular diameters, the Tolman length is on the order of a few hundredths of the molecular diameter, rather than a few tenths known previously.     

High-order numerical simulation and modelling of the interaction of energetic and inert materials

We present an integrated algorithm on a Eulerian grid, for multimaterial simulations of energetic and inert materials modelled by non-ideal equations of state. We employ high-resolution shock capturing numerical algorithms for each material inside its domain and use an overlap domain method across the interface, maintained by a recently developed, hybrid, level-set algorithm. For applications to condensed explosives we implement a non-ideal, wide-ranging equation of state and reaction rate law. For inert materials, like plastic, metal, water, etc., we implement a (linear in the pressure) Mie–Grüneisen, (U _p ?U _s ), equation of state. We present a series of verifications of the integrated multimaterial code and show validations against experiment. We show examples of simulations of various experiments associated with real or planned experiments, some of which contain energetic materials (specifically the condensed explosives PBX-9502 and PBX-9501).     

Angular and NiFe thickness dependence of exchange bias in IrMn/NiFe/IrMn thin film

Exchange biased IrMn/NiFe/IrMn thin films were studied as a function of NiFe thickness. In plane angular dependence of a resonance field distribution which is measured by FMR was analyzed as a combined effect of an unidirectional anisotropy and an uniaxial anisotropy. The unidirectional anisotropic field and the uniaxial anisotropic field were linearly varied with NiFe thickness while the films with a thicker NiFe layer do not follow the linear variation. Resonance field and linewidth variations were also analysed with NiFe thickness.     

Sound modes in holographic hydrodynamics for charged AdS black hole

In the previous paper we studied the transport coefficients of quark–gluon plasma in finite temperature and finite density in vector and tensor modes. In this paper, we extend it to the scalar modes. We work out the decoupling problem and hydrodynamic analysis for the sound mode in charged AdS black hole and calculate the sound velocity, the charge susceptibility and the electrical conductivity. We find that Einstein relation among the conductivity, the diffusion constant and the susceptibility holds exactly.     

Q-switched neodymium-doped Y3Al5O12-based silica fiber laser

We present pulsed laser operation in a Nd-doped, Y3Al5O12-based silica fiber. The fiber was fabricated using the rod-in-tube technique with a Nd:YAG crystal rod as the core material and a silica tube for the cladding material. A spectroscopy study revealed that the core region had become amorphous in the process of fiber drawing. Q-switched pulsed laser operation was realized at a wavelength of 1058 nm when the fiber was cladding pumped at a wavelength of 808 nm. The laser delivered 38 μJ of energy in 65 ns pulses. The extracted energy was limited due to the multimodal operation of the fiber. Laser slope efficiency in continuous wave operation reached 52%. The spectroscopic properties of the fabricated fiber are discussed and compared to a Nd:YAG crystal and a Nd:Al-doped silica fiber.     

The nonlinear optical properties of a magneto-exciton in a strained Ga0.2In0.sAs/GaAs quantum dot

The magnetic field-dependent heavy hole excitonic states in a strained Gao.2Ino.sAs/GaAs quantum dot are investi- gated by taking into account the anisotropy, non-parabolicity of the conduction band, and the geometrical confinement. The strained quantum dot is considered as a parabolic dot of InAs embedded in a GaAs barrier material. The dependence of the effective excitonic g-factor as a function of dot radius and the magnetic field strength is numerically measured. The interband optical transition energy as a function of geometrical confinement is computed in the presence of a mag- netic field. The magnetic field-dependent oscillator strength of interband transition under the geometrical confinement is studied. The exchange enhancements as a function of dot radius are observed for various magnetic field strengths in a strained Gao.2Ino.sAs/GaAs quantum dot. Heavy hole excitonic absorption spectra, the changes in refractive index, and the third-order susceptibility of third-order harmonic generation are investigated in the Gao.2Ino.8As/GaAs quantum dot. The result shows that the effect of magnetic field strength is more strongly dependent on the nonlinear optical property in a low-dimensional semiconductor system.