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R. K. Yanbaev V. V. Shereshovets V. D. Komissarov 《Reaction Kinetics and Catalysis Letters》1992,48(1):255-257
Medium effect on the decomposition rate of C6H5CH3.O3 in solvents: n-C6H14, CHCl3, CH2Cl2, (CH3)2CO, CH3OH and CH3CN has been studied. Consumption rate of this complex increases in polar solvents.
C6H5CH3.O3 n-C6H14, CHCl3, CH2Cl2, (CH3)2CO, CH3OH, CH3CN. .相似文献
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, p. 2879, December, 1988. 相似文献
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V. V. Shereshovets N. M. Korotaeva R. K. Yanbaev V. D. Komissarov G. A. Tolstikov 《Reaction Kinetics and Catalysis Letters》1989,38(2):243-247
Kinetic regularities of triphenylphosphite ozonide reaction with triphenylphosphite have been studied at T=–75°C to –40°C. The rate of ozonide consumption is estimated as W=k1[(C6H5O)3P·O3]+k2[(C6H5O)3P·O3][(C6H5O)3P], where k1=(2.03±0.39)×10–5s–1(–50°C), 1gk2=(3.82±0.33)–(6.61±0.32)/gq dm3/mol s and =2.303RT kcal/mol.
–75°C –40°C . : W=k1[(C6H5O)3P·O3]+k2[(C6H5O)3P·O3][(C6H5O)3P], k1=(2,03±0,39)·10–5–1(–50°C); 1g k2=(3,82±0,33)–(6,61±0,32)/ /·, =2,303·RT /相似文献
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Bashurin V. P. Budnikov I. N. Klevtsov V. A. Ktitorov L. V. Lazareva A. S. Meshkov E. E. Novikova I. A. Pletenev F. A. Fedorenko Ya. V. Yanbaev G. M. 《Technical Physics》2015,60(7):1093-1095
Technical Physics - Methods of laboratory modeling of 2D water flows in a rectangular channel are developed. The flow is produced in a vertical tube of a rectangular cross section when water flows... 相似文献
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V. V. Shereshovets R. K. Yanbaev V. D. Komissarov 《Reaction Kinetics and Catalysis Letters》1992,46(1):7-10
Decomposition rate of O3 complexes with aromatic hydrocarbons (ArX·O3) in ArXO3-ArX-CH2Cl2 system (ArX=C6H5CH3, C6H5CD3 and C6D5CD3) is described by the equation:
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