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排序方式: 共有127条查询结果,搜索用时 15 毫秒
1.
Morgane Rosendale Jonathan Daniel Frdric Castet Paolo Pagano Jean-Baptiste Verlhac Mireille Blanchard-Desce 《Molecules (Basel, Switzerland)》2022,27(7)
Molecular-based Fluorescent Organic Nanoparticles (FONs) are versatile light-emitting nano-tools whose properties can be rationally addressed by bottom-up molecular engineering. A challenging property to gain control over is the interaction of the FONs’ surface with biological systems. Indeed, most types of nanoparticles tend to interact with biological membranes. To address this limitation, we recently reported on two-photon (2P) absorbing, red to near infrared (NIR) emitting quadrupolar extended dyes built from a benzothiadiazole core and diphenylamino endgroups that yield spontaneously stealth FONs. In this paper, we expand our understanding of the structure-property relationship between the dye structure and the FONs 2P absorption response, fluorescence and stealthiness by characterizing a dye-related series of FONs. We observe that increasing the strength of the donor end-groups or of the core acceptor in the quadrupolar (D-π-A-π-D) dye structure allows for the tuning of optical properties, notably red-shifting both the emission (from red to NIR) and 2P absorption spectra while inducing a decrease in their fluorescence quantum yield. Thanks to their strong 1P and 2P absorption, all FONs whose median size varies between 11 and 28 nm exhibit giant 1P (106 M−1.cm−1) and 2P (104 GM) brightness values. Interestingly, all FONs were found to be non-toxic, exhibit stealth behaviour, and show vanishing non-specific interactions with cell membranes. We postulate that the strong hydrophobic character and the rigidity of the FONs building blocks are crucial to controlling the stealth nano-bio interface. 相似文献
2.
A. Casaburi M. Ejrnaes F. Mattioli A. Gaggero R. Leoni N. Martucciello S. Pagano M. Ohkubo R. Cristiano 《Journal of nanoparticle research》2011,13(11):6121-6131
The recent progress in the nanofabrication of superconducting films opens the road toward detectors with highly improved performances.
This is the case for superconducting nano-striplines where the thickness and the width are pushed down to the extreme limits
to realize detectors with unprecedented sensitivity and ultra fast response time. In this way quantum detectors for single
photons at telecommunication wavelengths and for macromolecules such as proteins can be realized. As is often the case in
applied nanotechnology, it is a challenge to make devices with the necessary macroscopic dimensions that are needed to interface
present technologies, while maintaining the performance improvements. For nano-stripline detectors, both the fast temporal
response and the device sensitivity is generally degraded when the area is increased. Here, we present how such detectors
can be scaled up to macroscopic dimensions without losing the performance of the nano-structured active elements by using
an innovative configuration. In order to realize ultrathin superconducting film the nano-layer is growth with a careful setup
of the deposition technique which guarantees high quality and thickness uniformity at the nano-scale size. The active nano-strips
are defined with the state-of-the-art electron beam nanolithography to achieve a highly uniform linewidth. We present working
detectors based on nano-strips with thicknesses 9–40 nm and widths of 100–1000 nm which exhibit unprecedented speed and area
coverage (40 × 40 μm2 for single photon detectors and 1 × 1 mm2 for single molecule detectors) based on niobium nitride thus enabling practical use of this nanotechnology. 相似文献
3.
E.?De?FilippoEmail author G.?Lanzanó H.?Rothard C.?Volant S.?Aiello A.?Anzalone N.?Arena M.?Geraci F.?Giustolisi A.?Pagano 《The European Physical Journal A - Hadrons and Nuclei》2004,21(1):169-174
Doubly differential electron velocity spectra induced by 36Ar18 + (95 MeV/u) from thin target foils (C, Ni, Ag, Au) were measured at GANIL (Caen, France) by means of the ARGOS multidetector and the time-of-flight technique. The main features observed in the forward spectra are convoy electrons, binary-encounter electrons, and (for the Au target only) a high-velocity tail which we attribute to a Fermi shuttle acceleration mechanism. Backward spectra do not show distinct structures. The spectra allow us to determine absolute singly differential cross-sections as a function of the target material and the emission angle. The convoy electron yield increases with the target atomic number, but for C their yield is so small that our experiment is not able to detect them. Absolute doubly differential cross-sections for binary-encounter electron ejection from C targets are well described by a transport theory which is based on the relativistic electron impact approximation (EIA) for electron production and which accounts for angular deflection, energy loss and energy straggling of the transmitted electrons.Received: 1 July 2003, Revised: 15 December 2003, Published online: 13 July 2004PACS:
34.50.Fa Electronic excitation and ionization of atoms (including beam-foil excitation and ionization) - 79.20.Rf Atomic, molecular, and ion beam impact and interactions with surfaces - 25.70.-z Low and intermediate energy heavy-ion reactions 相似文献
4.
Russian Physics Journal - The paper describes the problem of finding the likelihood ratio for specific problem of stochastic system recognition in continuous time to member functions within... 相似文献
5.
Meccanica - Magneto-rheological elastomers (MRE), consisting of elastomeric matrix containing ferromagnetic particles, are a kind of smart material, whose mechanical properties are controllable via... 相似文献
6.
Let P be a bounded analytic polyhedron in ℂ2 whose boundary is smooth except for normal crossing singularities. We show that P is a holomorphic quotient of the bidisc,
if its automorphism group is noncompact. 相似文献
7.
L. Fernandes C. Pagano Gonçalves da Silva 《Journal of Radioanalytical and Nuclear Chemistry》1993,172(2):313-318
The radiopharmaceutical201TlCl(thallium-201 chloride) is used in nuclear medicine for myocardial visualization. The solution of201TlCl was prepared using201Tl obtained by irradiating a natural mercury target with protons from the CV-28 cyclotron installed at IPEN-CNEN/SP. This solution was subjected to different quality control processes required for its use in medicine. Some of these controls concerned the determination of the radionuclidic impurities:200Tl,202Tl and203Hg; the chemical identification of201Tl+; the hydrazine concentration, mercury contamination and the presence of phosphate. Furthermore. the biological distribution in Wistar rats and tests for sterility, pyrogenicity and toxicity were carried out. It was verified that the solution obtained was in the form of thallous chloride. This radiopharmaceutical gave good heart images in animals but due to the high levels of200Tl and202Tl its use in humans is not possible unless enriched202Hg is used as target in the irradiation. 相似文献
8.
I Berceanu A Andronic M Duma D MoisĂ M Petrovici A Pop V Simion A del Zoppo G D’Erasmo G Imme G Lanzano A Pagano A Pantaleo G Raciti 《Pramana》1999,53(3):419-424
The excitation function (EF) data for dissipative processes in 19F + 27Al system in the incident energy interval from 113.5 to 130 MeV are used to obtain the dependence of the charge variance and
of the interaction time as a function of the incident energy. Fluctuations are observed in the EFs of both these secondary
observables. Their correlation is supported by a mechanism based on stochastic exchange of nucleons. 相似文献
9.
10.
R. T. de Souza N. Le Neindre A. Pagano K. -H. Schmidt 《The European Physical Journal A - Hadrons and Nuclei》2006,30(1):275-291
This review on second- and third-generation multidetectors devoted to heavy-ion collisions aims to cover the last twenty years.
The presented list of devices is not exhaustive but regroups most of the techniques used during this period for nuclear reactions
at intermediate energy (≃ 10A MeV to 1A GeV), both for charged-particle and neutron detection. The main part will be devoted
to 4π multidetectors, projectile decay fragmentation, high-resolution magnetic spectrometers, auxiliary detectors and neutron
detection. The last part will present the progress in electronics and detection in view of the construction of future-generation
detectors. 相似文献