全文获取类型
收费全文 | 856篇 |
免费 | 41篇 |
国内免费 | 2篇 |
专业分类
化学 | 586篇 |
晶体学 | 6篇 |
力学 | 29篇 |
数学 | 80篇 |
物理学 | 198篇 |
出版年
2023年 | 5篇 |
2022年 | 16篇 |
2021年 | 34篇 |
2020年 | 26篇 |
2019年 | 24篇 |
2018年 | 24篇 |
2017年 | 31篇 |
2016年 | 59篇 |
2015年 | 26篇 |
2014年 | 45篇 |
2013年 | 109篇 |
2012年 | 53篇 |
2011年 | 70篇 |
2010年 | 30篇 |
2009年 | 26篇 |
2008年 | 54篇 |
2007年 | 39篇 |
2006年 | 30篇 |
2005年 | 39篇 |
2004年 | 25篇 |
2003年 | 27篇 |
2002年 | 14篇 |
2001年 | 8篇 |
2000年 | 4篇 |
1999年 | 3篇 |
1998年 | 3篇 |
1997年 | 7篇 |
1996年 | 11篇 |
1995年 | 7篇 |
1994年 | 1篇 |
1993年 | 3篇 |
1992年 | 4篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 5篇 |
1986年 | 2篇 |
1985年 | 4篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1974年 | 1篇 |
1973年 | 3篇 |
1972年 | 2篇 |
1963年 | 1篇 |
排序方式: 共有899条查询结果,搜索用时 15 毫秒
1.
Saleh Z. M. Nasser H. Özkol E. Günöven M. Abak K. Canli S. Bek A. Turan R. 《Journal of nanoparticle research》2015,17(10):1-12
Journal of Nanoparticle Research - Plasmonic interfaces consisting of silver nanoparticles of different sizes (50–100&;nbsp;nm) have been processed by the self-assembled dewetting... 相似文献
2.
Manuel Fernández-López Eduardo García-Río Demir N. Kupeli 《Annals of Global Analysis and Geometry》2002,21(1):1-13
A characterization of time functions on a spacetime is made by using theMöbius equation. It is shown that a time function characterized in this wayyields past timelike geodesic incompleteness and local Lorentzian warpedproduct decomposition of spacetime, provided that the stress-energy tensoris a fluid. Also, by imposing additional assumptions on the stress-energytensor and global analytic structure of the spacetime, more restrictivedecompositions closer to Robertson–Walker spacetimes are obtained. 相似文献
3.
D-3-Hydroxybutyrate dehydrogenase (BDH) is an NAD(+)-dependent dehydrogenase of the mitochondrial inner membrane involved in the energetic balance between the liver and peripheral organs in mammals. It allows the conversion of ketone bodies (acetoacetate and D-3-hydroxybutyrate) and it is one of the best documented lipid-requiring enzymes with a dependence on lecithins. After release of proteins from the membrane by phospholipase A2 treatment of salt-treated mitochondria, the rat liver enzyme is absorbed on controlled-pore glass beads. After batch washing, the enzyme, devoid of lipids (apoBDH), is specifically eluted at pH 8.05-8.15 with a 0.1 M Tris-1 M LiBr buffer under reducing conditions (5 mM dithiothreitol). It appears that during BDH absorption, the glass beads mimic the phospholipid surface of biomembranes. 相似文献
4.
Nicolas Meyer Mohamad Nasser Eddine Christelle Delaite Guy Hurtrez Philippe Dumas 《Journal of polymer science. Part A, Polymer chemistry》2003,41(21):3329-3335
The reactions of polystyryllithium and potassium on dimethoxymethyl 1,1‐diphenylethylene derivatives were studied in different solvents. In a polar medium, A3 and A6 star types were formed according to the stoichiometry, whereas in a nonpolar medium, hyperbranched structures were synthesized. Extensions of an already proposed mechanism in polar and nonpolar media were examined. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3329–3335, 2003 相似文献
5.
Ti(IV) as TiCl3(O3SCF3) and TiO(O2CCF3)2 are used as efficient catalysts for oxidative coupling of aliphatic, aromatic and heteroaromatic thiols to their disulfides in the presence of NaI under air atmosphere. 相似文献
6.
We discuss role of partially gravitating scalar fields, scalar fields whose energy–momentum tensors vanish for a subset of dimensions, in dynamical compactification of a given set of dimensions. We show that the resulting spacetime exhibits a factorizable geometry consisting of usual four-dimensional spacetime with full Poincaré invariance times a manifold of extra dimensions whose size and shape are determined by the scalar field dynamics. Depending on the strength of its coupling to the curvature scalar, the vacuum expectation value (VEV) of the scalar field may or may not vanish. When its VEV is zero the higher-dimensional spacetime is completely flat and there is no compactification effect at all. On the other hand, when its VEV is nonzero the extra dimensions get spontaneously compactified. The compactification process is such that a bulk cosmological constant is utilized for curving the extra dimensions. 相似文献
7.
M. I. Nasser M. A. Moharram 《International Journal of Infrared and Millimeter Waves》1989,10(1):73-82
In this work, the temperature dependence of the intensities of the IR absorption bands corresponding to the fundamental vibrations, overtones and combination frequencies of diphenyl is presented. A thorough discussion of the interpretation of the fundamental modes of vibration has been made on the basis of the temperature dependence of the intensities of these absorption bands.The structure of the diphenyl molecule has been the subject of numerous investigations. Despite a considerable amount of work on the Raman(1), IR(3,4,5) and ultraviolet (2) spectra, the assignment of the fundamental frequencies has not yet been established with certainty, Some assistance can be obtained from the temperature dependence of the IR spectrum of this material. 相似文献
8.
A new enantioselective synthesis of furan‐2‐yl amines and amino acids is described, in which the key step is the oxazaborolidine‐catalyzed enantioselective reduction of O‐benzyl (E)‐ and (Z)‐furan‐2‐yl ketone oximes to the corresponding chiral amines. The chirality of the furan‐2‐yl amines is fully controlled by the appropriate choice of the geometrical isomer of the O‐benzyl oxime. Oxidation of the furan ring furnished amino acids in high yields. 相似文献
9.
New, sterically demanding 1,3-dialkyl-3,4,5,6-tetrahydropyrimidinium salts (2) as NHC precursors have been synthesized and characterized. These salts, in combination with palladium acetate, provided active catalysts for the cross-coupling of aryl chlorides and bromides under mild conditions. The catalytic system was applied to the Heck, Suzuki and benzaldehyde (Kumada) coupling reactions. Catalyst activity was found to be influenced by the presence of a methoxy group on the ring of the p-position of benzyl substituent of the ligand precursor. 相似文献
10.
Nasser R. El-Brollosy Claus Nielsen Erik B. Pedersen 《Monatshefte für Chemie / Chemical Monthly》2005,12(2):1247-1254
A series of Emivirine and GCA-186 analogues substituted at N-1 with indan-1-yloxymethyl (6a–6c) and indan-2-yloxymethyl (6d–6f) were synthesized by reaction of the corresponding bis(indanyloxy)methans with uracils having 5-ethyl or 5-isopropyl and 6-benzyl or 6-(3,5-dimethylbenzyl) substituents. A route to the corresponding N-1 substituted 4-hydroxybut-2-enyloxymethyl analogue was also devised. All newly synthesized compounds showed potent activity against wild-type HIV-1, the most active compound being 5-ethyl-1-(indan-1-yloxymethyl)-6-(3,5-dimethylbenzyl)uracil (6b), which was 50-fold more active than Emivirine. 相似文献