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1.

The catalytic activity of the systems based on titanium(iv) alkoxides (Ti(OPri)4, Ti(OPri)2(OCH(CF3)2)2, and Ti(OCH(CF3)2)4) and mixtures of alkylaluminum chlorides (Et2AlCl or Et3Al2Cl3) with dibutylmagnesium in ethylene polymerization and ethylene copolymerization with propylene and 5-ethylidene-2-norbornene was studied. Ultrahigh-molecular-weight polyethylene with the molecular weight reaching 4.9 · 106 Da was found to be formed in the homopolymerization reaction, whereas copolymerization gives ter-copolymers containing propylene (up to 35 mol.%) and 5-ethylidene-2-norbornene (4.3 mol.%) units.

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Yorioka introduced a class of ideals (parametrized by reals) on the Cantor space to prove that the relation between the size of the continuum and the cofinality of the strong measure zero ideal on the real line cannot be decided in . We construct a matrix iteration of c.c.c. posets to force that, for many ideals in that class, their associated cardinal invariants (i.e., additivity, covering, uniformity and cofinality) are pairwise different. In addition, we show that, consistently, the additivity and cofinality of Yorioka ideals does not coincide with the additivity and cofinality (respectively) of the ideal of Lebesgue measure zero subsets of the real line.  相似文献   
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A. Bande 《Molecular physics》2019,117(15-16):2014-2028
ABSTRACT

Recently, highly accurate multi-configuration time-dependent Hartree electron dynamics calculations demonstrated the efficient long-range energy transfer inter-Coulombic decay (ICD) process to happen in charged semiconductor quantum dot (QD) pairs. ICD is initiated by intraband photoexcitation of one of the QDs and leads to electron emission from the other within a duration of about 150 ps. On the same time scale electronically excited states are reported to relax due to the coupling of electrons to acoustic phonons. Likewise, phonons promote ionisation. Here, the QDs' acoustic breathing mode is implemented in a frozen-phonon approach. A detailed comparison of the phonon effects on electron relaxation and emission as well as on the full ICD process is presented, which supports the previous empirical finding of ICD being the dominant decay channel in paired QDs. In addition the relative importance of phonon–phonon, phonon–electron and electron–electron interaction is analysed.  相似文献   
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Intricate behaviour of one-electron potentials from the Euler equation for electron density and corresponding gradient force fields in crystals was studied. Channels of locally enhanced kinetic potential and corresponding saddle Lagrange points were found between chemically bonded atoms. Superposition of electrostatic and kinetic potentials and electron density allowed partitioning any molecules and crystals into atomic - and potential-based -basins; -basins explicitly account for the electron exchange effect, which is missed for -ones. Phenomena of interatomic charge transfer and related electron exchange were explained in terms of space gaps between zero-flux surfaces of - and -basins. The gap between - and -basins represents the charge transfer, while the gap between - and -basins is a real-space manifestation of sharing the transferred electrons caused by the static exchange and kinetic effects as a response against the electron transfer. The regularity describing relative positions of -, -, and - basin boundaries between interacting atoms was proposed. The position of -boundary between - and -ones within an electron occupier atom determines the extent of transferred electron sharing. The stronger an H⋅⋅⋅O hydrogen bond is, the deeper hydrogen atom's -basin penetrates oxygen atom's -basin, while for covalent bonds a -boundary closely approaches a -one indicating almost complete sharing of the transferred electrons. In the case of ionic bonds, the same region corresponds to electron pairing within the -basin of an electron occupier atom.  相似文献   
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